Gen Chem Flashcards

1
Q

Energy of an electron

A

E = -Rh/ n^2

depends on principal quantum # (n)

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2
Q

E-mag energy of photons

A
E = hc/lambda
E = h(f) 

h = planks constant = 6.626 x 10 ^-34

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3
Q

Hydrogen emission lines

A

n >2 –> n=2 Balmer
n >1 –> n=1 Lyman
paschen?

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4
Q

Heisenberg uncertainty principle

A

impossible to determine with perfect accuracy the position and momentum of e- simultaneously

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5
Q

Exceptions to octet

A

H(2), He(2), Li(2), Be(4), B(6)

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6
Q

Hunds rule

A

Electrons fill in order to maximize half-filled orbitals

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7
Q

Exceptions to e- configuration

A

Chromium: 3d5 and 4s1

Copper: 3d 10 and 4s1

more favorable to fill the 3d and deal with incomplete 4s

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8
Q

How many e- in shell/subshell/orbital

A

shell: 2n^2
sub shell: 4l +2
orbital: always 2?

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9
Q

VESPR

e = 2

A

linear
180
non polar?

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10
Q

e =3

A

trigonal planar

120

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11
Q

e = 4

A

tetrahedral

109.5

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12
Q

e = 5

A

trigonal bipyramidal

90, 120, 180

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13
Q

e = 6

A

octahedral
90, 180
SN

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14
Q

quantum number n

A

= shell

value = n

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15
Q

quantum number p

A

= subshell (l)

l values = from (0 to n-1)

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16
Q

quantum number ml

A

= orbital

ml values = from (-l to +l)

17
Q

quantum number ms

A

= spin

+/- 1/2