Gen Chem Flashcards
Energy of an electron
E = -Rh/ n^2
depends on principal quantum # (n)
E-mag energy of photons
E = hc/lambda E = h(f)
h = planks constant = 6.626 x 10 ^-34
Hydrogen emission lines
n >2 –> n=2 Balmer
n >1 –> n=1 Lyman
paschen?
Heisenberg uncertainty principle
impossible to determine with perfect accuracy the position and momentum of e- simultaneously
Exceptions to octet
H(2), He(2), Li(2), Be(4), B(6)
Hunds rule
Electrons fill in order to maximize half-filled orbitals
Exceptions to e- configuration
Chromium: 3d5 and 4s1
Copper: 3d 10 and 4s1
more favorable to fill the 3d and deal with incomplete 4s
How many e- in shell/subshell/orbital
shell: 2n^2
sub shell: 4l +2
orbital: always 2?
VESPR
e = 2
linear
180
non polar?
e =3
trigonal planar
120
e = 4
tetrahedral
109.5
e = 5
trigonal bipyramidal
90, 120, 180
e = 6
octahedral
90, 180
SN
quantum number n
= shell
value = n
quantum number p
= subshell (l)
l values = from (0 to n-1)