Gases and Kinetic Theory COPY Flashcards

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1
Q

What was used to see Brownian motion?

A

Smoke particles with a microscope

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2
Q

What is Brownian motion?

A

Where particles seem to be wriggling unpredictably.

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3
Q

How did Brownian motion show the existanceof molecules and atoms?

A

The unpredictable wriggling is due to being bombarded unevenly and experiences forces due to these impacts, which changes its magnitude and direction.

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4
Q

What is pressure caused by?

A

The molecules in a gas bombarding the walls of the container

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5
Q

What does the graph of pressure against temperature look like?

A
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6
Q

Define absolute zero

A

The temperature where the pressure of an ideal gas becomes 0

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7
Q

Draw the graph of pressure against volume

A
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8
Q

Draw the graph of pressure against 1/volume

A
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9
Q

How would you use an experiment showing Boyle’s Law to show that P is directly proportional to 1/V

A
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10
Q

What is Boyle’s Law?

A

P is directly proportional to 1/V

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11
Q

How would you use an experiment showing Charles’s Law to that volume is proportional to temperature

A
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12
Q

What is Charles’s Law?

A

V is directly proportional to T

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13
Q

Explain how the experiment showing the pressure Law and be. used to prove P is directly proportional to T

A
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14
Q

what does the pressure law show?

A

P is directly proportional to T

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15
Q

What is the molar mass?

A

The mass of one mole of a gas (Mr)

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16
Q

What is the molecular mass?

A

The mass of one molecule of the gas

17
Q

Define mole

A

The number of atoms of C-12 in 12g of C-12

18
Q

What are the three gas equations (moles)?

A

mass = mr x mol

N = Na x mass / mr

mol = N / Na

N = No. of molecules

Na = Avagadro’s Constant

19
Q

What are the three arrangements of the ideal gas equation?

A

pV = nRT

P1V1 / T1 = P2V2 / T2

pV = NkT

20
Q

Define an ideal gas

A

One which obeys the equation pV = nRT at all temperatures and pressures

21
Q

What are real gases

A

Gases that behave like ideal gases at low pressures and temperatures above room temperatures

22
Q

When does an expanding gas do no work?

A

When it is expanding into a vacuum

23
Q

What is the equation for the work done by an expanding gas at constant temperature?

A

W = p∆V

24
Q

Why does a gas exert a force on a wall?

A
  • The gas molecules collide elastically with the walls of the container
  • Their velocity will change direction but keep the same magnitude
  • This causes the component of their momentum perpendicular to the wall to change
  • By Newton’s second law the molecules must have a resultant force on them to cause this change in momentum
  • This resultant force is exerted by the wall on the molecules
  • By Newton’s third law, if the wall puts a force on the molecules, the molecules must put an equal opposite force on the wall
  • The forces from all the molecules cause a pressure on the wall, which can be calculated by P = F / A
25
Q

Why does increasing the temperature of the gas increase the pressure?

A
  • Average kinetic energy increases
  • Higher average speed
  • Greater rate of change of momentum when hits wall so a greater force and so greater pressure
  • They also hit the wall more times per second
26
Q

Why does decreasing the volume of a gas increase the pressure?

A
  • More collisions with the container per second
  • Rate of change of momentum of the particles hitting the wall will increase
  • The force on the wall will increase
  • So pressure will increase as pressure = F / A
27
Q

Find the rms speed of molecules with speeds of 100,200,300,400,500 ms-1

A

rms = 331.6 ms-1

(1002 + 2002 + 3002 + 4002 + 5002) /6

28
Q

How do we assume the molecules behave in an ideal gas?

A
  • Number of molecules is very large
  • Molecules are in random motion
  • Forces between the gas molecules are negligible until they collide
  • The collisions between the molecules and the walls are perfectly elastic
  • The volume of the molecules is negligible compared to the volume of the container
  • The duration of the collisions between molecules and the walls of the container and each other is negligible compared to the time between collisions
29
Q

Describe what random motion is

A
  • They have a range of speeds
  • The motion of a molecule changes unpredictably
  • They have no preferred direction of motion
30
Q

What is a perfectly elastic collision?

A

A collision where they lose no kinetic energy when they collide

31
Q

Derive the formula for the force on the wall exerted by one molecule of gas.

A
32
Q

Derive the formula for kinetic theory (pressure exerted by N molecules)

A
33
Q

Derive 1/2mc2 = 3/2kT

A
34
Q

If you have hydrogen gas and oxygen gas at the same temperature, why does hydrogen have a huger Crms

A

The average kinetic energy will be the same, but the hydrogen has a lower mass so it will have a greater Crms

35
Q

What will happen to the Crms if the temperature of an ideal gas is doubled

A

x √2

36
Q

Prove that the Crms is directly proportional to the square root of the temperature.

A
37
Q

Derive the equation for pV = NkT

A