Gases Flashcards
Definition of Energy
Capacity to do work
Definition of Work
Motion against force
Boyle’s Law
At a constant temperature the volume of a fixed amount fo a gas is reduced as pressure increases.
Pressure is therefore inversely proportional to Volume given Temperature and Moles are constant
Charles’s Law
At a constant pressure, the volume of a fixed about of gas increases linearly with rising temperature.
Volume is therefore directly proportional to Temperature given Pressure and Moles are constant
Avogadro’s Law
Equal volumes of gases at constant temperature and pressure contain equal number of molecules.
Volume is therefore directly proportional to Moles given Temperature and Pressure are constant
Combination of Laws
This gives Volume is directly proportional to nT/p. Therefore pV is directly proportional to nT.
This proportionality is equal to multiplying by universal gas constant to give the Ideal Gas Equation.
Assumptions of Ideal Gas
Particles have no volume.
Particles have no interactions with other particles.
SI Units of Pressure
Pascals.
Equation for Pressure
Pressure = HeightDensityAcceleration due to gravity
p = phg
Standard Conditions and Molar Volumes
298.15 K and 1 bar (1x10^5 Pa)
Partial Pressure Ideal Gas pointers
Mole Fraction = Partial Pressure/Total Volume
Further Considerations of an Ideal Gas
No Rotational or Vibrational kinetic energy.
No intermolecular forces within an ideal gas.
No Electrostatic potential energy.
Internal energy of an ideal gas is determined by Temperature.
Thermodynamic state of an ideal gas determined by any two of: Pressure, Volume and Temperature.