Gaseous State Flashcards
Avogadro’s Law
Volume, V, of a gas is directly proportional to the amount of gas particles (in mol) at constant temperature and pressure
V direct to n
Boyle’s Law
Volume, V, of a fixed mass of gas is inversely proportional to its pressure, p, at a constant temp
V inverse to p
Charles’ Law
Volume, V, of a fixed mass of gas is directly proportional to its absolute temperature, T, at a constant pressure
V direct to T
Gay-Lussac’s Law
Pressure, p, of a fixed mass of gas is directly proportional to it’s absolute temperature, T, at a constant volume
p direct to T
Assumptions of the kinetic theory
- There are no intermolecular forces of attraction between the particles of an ideal gas
- The volume of the ideal gas is negligible as compared to the volume of the container
- Collisions between particles of an ideal gas are perfectly elastic i.e. no loss of KE upon collision
- Gas particles are in rapid, continuous and random motion
- The average KE of the particles is proportional to its absolute temperature measured in Kelvin
Gas deviates more from ideal behaviour at.. (1)
High pressure because
- volume of container decreases and particles are packed closer together
- so the volume of the particles become significant compared to the volume of the container
Gas deviates more from ideal behaviour at.. (2)
Lower temperature because
- The particles have less KE and will move slower, hence collide with one another with less force
- Makes the IMOF more significant compared to the forces of intermolecular collisions
Dalton’s Law of partial pressure
The total pressure of a mixture of gases that do not react chemically with one another is the sum of the partial pressures of the constituent gases