Gas Supplies, Breathing Systems and Ventilators Flashcards
What is critical temperature?
The temperature above which, a substance cannot be liquefied irrespective of the amount of pressure applied
What is critical pressure?
The minimum pressure required to liquefy a gas at it’s critical temperature
What is a gas?
A compressible fluid where intermolecular spacing is so large that intermolecular forces are negligible
What is a vapour?
A gas below it’s critical temperature, thus compression to the liquid is possible
What is a fixed gas?
A gas above it’s critical temperature
What is latent heat?
The energy change associated with a change in state of a substance in either direction, with no change in temperature.
How is O2 supplied in hospital?
- One or more VIEs (vacuum insulated evaporators) with a cylinder manifold in back-up.
- A network of high-integrity copper pipes throughout the hospital
- supply maintained by hospital estates
- Chief pharmacist is legally responsible for certifying the quality of the gas supplied
What is the VIE?
A double-skinned steel tank with a vacuum of 0.16 - 0.3 kPa existing between skins.
What is the temperature inside the VIE?
Between -160 to -180 C.
Why is the temperature in the VIE low?
The VIE is below (-160 to -180C) the critical temperature of O2 (-118 C). This means O2 is a liquid inside with a saturated vapour at a pressure of 10 bar above the liquid.
How is O2 taken out of the VIE?
Oxygen vapour is drawn from the top of the VIE. Latent heat of evaporation is required to vaporize O2 to re-establish equalibrium.
Supplying latent heat from liquid ensures no external cooling system is needed.
How does low demand/warm weather affect the VIE?
- reduces the cooling effect of the vaporizing process
- pressure increases
- safety valve opens at 15bar
How does high demand/cold weather affect the VIE?
- insufficient energy to sustain adequate evaporation to meet demand
- liquid O2 can be tapped from the bottom of the system and warmed by the environment to restore vapour supply (Pressure-raising vaporizer)
How is the supply pressure of O2 maintained constantly at 4.1 bar?
By a system of pressure regulators
What is nitrous oxide inhaled and exhaled as?
It is inhaled as a vapour (below it’s critical temperature of 36.4 degrees) and exhaled as a fixed gas (above it’s critical temperature).
What are isotherms?
The curves of constant temperature
eg nitrous oxide
What law does the isotherm of a gas above critical temperature follow?
Boyle’s Law - the substance is a fixed gas above critical temp so can’t be liquefied by increasing pressure
What does the isotherm of nitrous oxide look like at it’s critical temperature (36.4C) ?
Demonstrates a sharp inflection at 73 bar (critical pressure) where it becomes a liquid.
When any vapour is at critical temperature, it’s on a “knife edge” of temperature and pressure. Any tiny change in either will cause liquefaction or transformation to a fixed gas so very little vapour exists.
What is the filling ratio of cylinders?
It’s based on WEIGHT not volume. It should be 75% of the weight of water that would completely fill the cylinder (67% in warmer climates).
Differing densities of N2O (1222 kg/m3) and water (1000 kg/m3) so 0.75 filling ratio does not give a cylinder 75% full by volume.
Why can standard Bourdon pressure gauges not be used to measure N2O cylinder content?
Because they measure the pressure of the vapour but not the remaining liquid at steady state.
The only true measurement is weight minus tare weight (empty weight of the cylinder).
What would happen to the Bourdon pressure gauge when a nitrous oxide container is used constantly?
Due to the cooling effect of the latent heat of vaporization during sustained use, a steady pressure drop will be observed.
When the cylinder is switched off and allowed to re-warm to ambient temperature, equalibrium is restored and a pressure of 53 bar is regained.
What is entonox?
A 50/50 mix of O2 and N2O by VOLUME
What is the pseudo-critical temperature of entonox?
*MINUS*
- 5.5 degrees C