Gas law Flashcards
Pressure
Units of pressure
1atm= 101.3kPa=760mmHg=760 Torr= 14.7
Force per unit area
Pressure
Rate of molecular collision
Temperature
Average molecular speed
Gas Laws Boyle
PV=k P1V1 = P2V2 P = pressure V=volume k=constant at a specific temp
Ideal gas behaviour
V is inversely proportional to P, if we graph it and straight line shows.
Charles’ Law
Volume and temperature are proportional with a fixed amount of gas
V1/T1= V2T2
Avogadro’s Law
Volume is proportional to the Number of moles of gas at Constant P and T
V1/n1=V2/n2
Ideal Gas Law
PV = nRT
Molar mass of a gas
n= mass/molar mass = m(g)/ MW P=nRT/V = mRT/molar mass V= dRT/ Molar Mass
Vapour Pressure
The pressure that results from a liquid when
rate of evaporation = Rate of condensation in a closed container
Temperature Dependent
Kinetic Molecular Theory of Gases
- Volume of each particle can be neglected
- Pressure results from the particle’s collision against the walls of the container
- Particles do not exert forces onto another
- Average kinetic energy of a gas particle is directly proportional to the temperature
Roots mean square velocity
Average of the squared velocity of the particles
u^2
Maxwell distribution law
Average distance a particle travels between collisions
Collision between particles = large range in velocity
Effusion
Measures rate at which the gas is transferred into the chamber
Rate of effusion of gas 1/ Rate of effusion gas 2 = square root molar mass 2 / square root molar mass 1
Collision with container walls
Collision rate
Depends on
Particle speed (Uavg)
Area (A)
Particle Density (# of particles / Volume = N/V)