Gas law Flashcards

1
Q

Pressure

A

Units of pressure
1atm= 101.3kPa=760mmHg=760 Torr= 14.7
Force per unit area

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2
Q

Pressure

A

Rate of molecular collision

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3
Q

Temperature

A

Average molecular speed

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4
Q

Gas Laws Boyle

A
PV=k
P1V1 = P2V2
P = pressure
V=volume
k=constant at a specific temp
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5
Q

Ideal gas behaviour

A

V is inversely proportional to P, if we graph it and straight line shows.

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6
Q

Charles’ Law

A

Volume and temperature are proportional with a fixed amount of gas
V1/T1= V2T2

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7
Q

Avogadro’s Law

A

Volume is proportional to the Number of moles of gas at Constant P and T
V1/n1=V2/n2

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8
Q

Ideal Gas Law

A

PV = nRT

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9
Q

Molar mass of a gas

A
n= mass/molar mass = m(g)/ MW
P=nRT/V = mRT/molar mass V= dRT/ Molar Mass
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10
Q

Vapour Pressure

A

The pressure that results from a liquid when
rate of evaporation = Rate of condensation in a closed container
Temperature Dependent

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11
Q

Kinetic Molecular Theory of Gases

A
  • Volume of each particle can be neglected
  • Pressure results from the particle’s collision against the walls of the container
  • Particles do not exert forces onto another
  • Average kinetic energy of a gas particle is directly proportional to the temperature
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12
Q

Roots mean square velocity

A

Average of the squared velocity of the particles

u^2

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13
Q

Maxwell distribution law

A

Average distance a particle travels between collisions

Collision between particles = large range in velocity

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14
Q

Effusion

A

Measures rate at which the gas is transferred into the chamber
Rate of effusion of gas 1/ Rate of effusion gas 2 = square root molar mass 2 / square root molar mass 1

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15
Q

Collision with container walls

Collision rate

A

Depends on
Particle speed (Uavg)
Area (A)
Particle Density (# of particles / Volume = N/V)

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16
Q

Ideal gas

A

behave ideally at low P/ High T

  1. Negligible particle Volume
  2. NO inter particle forces (attraction/Repulsion)
  3. Plot of PV/nRT vs P is unity = 1
17
Q

Ideal Behaviour in real gases

Low temp

A

-Few particles per unit volume
-Volume of particles is negligible compared to the volume of the container
- Interactions are minimized
Behaves more like ideal gas at low pressure

18
Q

Ideal Behaviour in real gases

Gas at high temp

A

Less interaction, particles move further apart, larger volume
at low temp, volume decreases, particles closer together
Real gas behaves more like an ideal gas at high temp