G1 : rock forming processes KI1 (generation of magma) Flashcards
what is magmatic differentitation?
a number of processes that cause a parent magma to evolve into magmas of different compositions. this leads to different igneous rocks being produced from a single parent magma.
what is fractional crystallisation?
as olivine and pyroxene form at high temperatures, they use iron and magnesium from the magma in their crystal lattices. the high temperature plagioclase crystals are rich in calcium. the magma become depleted in iron, mg and ca. the remaining liquid becomes enriched in silica, potassium, na and h2o because the early formed minerals are poor in these elements. over time the composition of magma changes
what is gravity settling?
crystals are denser than the liquid and settle out. early formed minerals (olivine and pyroxene) have a greater percentage of iron and are denser to sink to form s cumulate layer at the base of the intrusion or magma chamber. crystals that remain suspended in magma will react with that magma over time, following either side of the bowens reaction series, gravity settling removes crystals from remaining liquid so they can no longer react with magma changing the composition
what is filter pressing?
during crystallisation of magma, there is a point where crystals and liquid exist together as a slushy mass. due to the weight of overlying crystals, the liquid gets squeezed out, forming a separate. layer above. this liquid is depleted in the elements which are incorporated into the early formed crystals and enriched in the elements which form felsic minerals.
what is the discontinuous series in bowens reaction?
the crystallisation of minerals that are rich in iron and magnesium with silica. in a mafic magma, olivine will be the first mafic mineral to form at a high temperature (>1500c). as the temperature lowers, pyroxene, then amphibole and finally biotite will form. if cooling takes place slowly then the early formed, high temperature minerals react with the magma to form the next mineral down the series.
whats a reaction rim?
one mineral surrounding another, as a result of a reaction between the inner mineral with the melt, to form the outer mineral
Incomplete reactions for the discontinuous series
Corona structure
what is the continuous series in bowens reaction
describes the evolution of the plagioclase feldspars as they evolve from being calcium-rich (anorthite) to more sodium-rich (albite)
anorthite-bytownite-laradorite-andesine-oligolcase-albite
whats a zoned crystal?
a crystal starts to grow of plagioclase feldspar when the temperature is high. as the magma cools the crystal continues to grow with new layers forming, gradually becoming richer in Na.
Incomplete reaction for the continuous series
how is bowens reaction series significant in the weathering of crustal rocks
lower temperature of crystal formation is more resistant as it is more used to the conditions on the surface.
What are the largest and most significant geological deposits of PGE commonly rich in
Platinum and palladium together with igneous intrusions are associated with sulfide minerals in layered mafic or ultramafic igneous intrusions (cumulate deposit)
When do magmatic sulfide deposits form
During the fractional crystallisation process when mafic magma becomes saturated in sulfide
What happens when magma can no longer hold sulfer in solution
The sulfer exsolves producing an immiscible sulfide liquid. Droplets from this liquid are denser than the magma and so sink through it.
What are siderophile elements
(Iron loving) platinum group elements and gold and nickel
What do siderophile elements do
Preferentially form metallic bonds with iron and will concentrate in molten iron
The only place a liquid like this exists is in the Earth outer core
What happens if siderophile elements do not have iron to react with
They behave like the chalcophile (ore loving) elements silver and copper and will concentrate in molten sulfide, bonding more readily with sulfer than with oxygen
They are therefore gathered up by sinking sulfide droplets and removed from the magma, to form layers that range from a few mm to a few m thick
What is the most reasonable mechanism for the largest sulfide deposits
Assimilation of country rock that is rich in sulfer or silica contamination from assimilation of silica rich country rock, which is thought to decrease the solubility of sulfer in a mafic magma
The skaergaard intrusion in Greenland
One of the most studied in the world and contains magmatic sulfide in layers rich in PGE, gold and selenium. It was intruded during the tertiary igneous province when the North Atlantic was opening
What happens when molten rock becomes solid
As a magma crystallises the crystals that form with have a different composition from the melt. When the crystals separate from the rest of the magma as they grow, the chemistry of the magma changes. A single magma could form ultramafic, mafic, intermediate and solicit rocks if there is enough time for differentiation.
If a parent magma is mafic than in theory what will it produce
-peridotite at the base of the intrusion, rich in dense olivine
-gabbro forming the main part of the intrusion
-diorite may exist towards the top of the intrusion
-granite may form veins or a thin layer at the top of the intrusion
What are major layered intrusions
Large mafic or ultramafic igneous intrusions that cooled slowly below the surface so there was time for them to form distinct layers. Most of the world platinum and chromium comes from them, giving an added incentive to understanding how they formed. Gravity settling is the key process in the key formation of layers of magnetite, chromite and platinum
The palisades sill in New Jersey
Crops out along the Hudson River and is over 300m thick, it was intruded into Triassic sediments at depth of about 3km, so that it cooled slowly and has now been exposed by erosion. This sill can be divided into three sections, each of which shows a different igneous process
1st section of the palisades sill
Only parts to cool rapidly are the upper and lower edges, which were in contact with cold country rock. These chilled margins have fine crystals and most importantly have the same composition as the original magma as they cooled before and differentiation took place. The rock is a basalt.
2nd section of the palisades sill
As the main part of the intrusion began to early formed olivine crystals began to sink by gravity settling. Olivine has a density of 3.8gcm-3 compared to 3.0gcm-3 for a mafic magma. The olivine crystals form a layer 10m thick at the base of the intrusion, just above the lower chilled margin
3rd section of the palisades sill
Crystallisation was taking place from both the top and bottom as the crystals grew in cooler areas. The main rock forming the intrusion has medium sized crystals and is a dolerite. The last part of the magma to crystallised is about 200m above the base and is a gabbro with coarse crystals, indicating it cooled slowly, as a result of fractionation, the composition is lower in mafic minerals than the original as the magma is depleted in iron and magnesium by the time the rock formed. It is richer in plagioclase as the last part of the magma to crystallise is enriched in silica
Hekla volcano in Iceland
Should be mafic as it is on a divergent plate margin, yet it erupts intermediate lave and has erupted rholitic lava in the past. The longer the period between eruptions the more acidic the magma is. If there is a long interval between eruption fractionation in the magma chamber causes more mafic minerals, which crystallise at high temperatures, to be found at the bottom and Felicia minerals at the top. Each ruction takes magma from the top of the magma chamber and then from lower in the chamber
The bushveld igneous complex in South Africa
Large layered igneous intrusion 400km x 800km with a volume of at least 1,000,000km3. It varies in thickness by reaches 9km in places. Formed at least 2 billion years ago, the complex contains some of the richest ore deposits on earth and the largest reserves of platinum group elements
What magmas are Felicia
Granitic and rhyolitic
What magmas are mafic
Basaltic, (gabbro and dolerite)
Magma formation
Pressure release
- the base of the crust is hot enough to melt mantle rock
-due to high pressure the rock does not melt
-a drop in pressure indicates “decompressional melting”
-pressure drops when hot rock rises (partial melting) to shallower depths
Why to magmas vary chemically
-initial source rock composition
-partial melting
-assimilation
-fractional crystallisation
Why do plutonic intrusions and larger igneous provinces often display a range of different rock types
-different composition of original magma
-magma mixing
-contamination of the magma by country rock assimilation
-evolution of a parent magma to produce one or more daughter magma through magmatic differentiation
What is magma mixing
Factors like density and thermal contrast keep different magmas separated. A vigorous stirring mechanism such as convection within the chamber is required to produce a magma that has an intermediate composition. The result combines the characteristics of the two magmas, often magma mixing is incomplete, resulting in blobs of one rock suspended within the other.
Stoping (contamination/assimilation)
Blocks of country rock from conduits or the walls/roof of the magma chamber are broken off by rising magma and incorporated into the magma as xenoliths, if these xenoliths melt and become assimilated into the magma they can contaminate it and change its bulk composition.
Why does magma migrate
It has a lower density that surrounding rock so rises upwards in the crust and may breach the surface (volcano). This transfers mass from deep to shallow parts of the earth, a crucial process in the earths system. Provides the raw material for soil, atmosphere and ocean
How does magma move and what factors increase the migration
-injection into cracks
-melting overlying rocks
-squeezed by overburden
Lower viscosity eases movement. Lower viscosity from - higher temperature means more fractures, lower silica content, higher volatile content
Effect of temperature of viscosity
Hotter - lower viscosity
Cooler - higher viscosity
Effect of volatile content of viscosity
Less volatiles - lower viscosity
More volatiles - higher viscosity
Effect of silica content of viscosity
Less SiO2 (mafic) - lower viscosity
More SiO2 (Felisic) - higher viscosity
Volatile content in magmas
Magmas contain small amounts of dissolved gas which is released as pressure is removed. Magma formed by melting of mantle rock has low volatile content, but those formed by partial melting of crystal rocks are volatile rich. A high volatile content decreases viscosity, and is one of the main factors in enabling some highly viscous melts to reach the surface. The release of gas during eruption will be explosive if magma is both viscous and volatile rich
Diapirism
Intruded buoyantly upward along fractures or zones of structural weakness through overlying rocks.
What are enclaves
Aggregate of minerals or rock observed inside another larger rock body. Usually referred to such situations in plutonic rocks. Micro granular enclaves in Celsius plutons result from the introduction of mafic magma into the magma chamber an it’s subsequent cool following incomplete mixing
Caldera
Collapsed volcano