Functional Groups 2 [Alcohols] Flashcards
Halide + _____ = Alcohol?
Consider 1/2/3.
1 and 2 degree halides react with -OH and tertiary react with H2O.
Alkene + ____ = 1 Alc?
B2H6 then H2O2/-OH
Alkene + ____ = 2/3 Alc
H2O/H+
Aldehyde + ______ = 1 Alc
NaBH4 or LiAlH4
Aldehyde + _____ = 2 Alc
Grignards
Ester + LiAlH4
1 degree alc
Methanal + ______ = 1 Alc
Grignard
Ketone + NaBH4 or LiAlH4 = ?
2 Alc
Ketone + Grignard = ?
3 Alc
1 Alc + _____ = 1 Halide
Type of reaction?
Conc. HCl
SN2
2 Alc + ______ = Alkene
Type of reaction?
Conc. H2SO4 + heat
E1/2
1 Alc + ______ = Alkene
Type of reaction?
Conc. H2SO4 + heat
E2
1 Alc + _____ = Aldehyde
PCC
1 Alc + ______ = Carboxylic
H2CRO4
2 Alc + _____ = Ketone
PCC or H2CRO4
3 Alc + _____ = 3 Halide
Type of reaction?
Conc. HCl
SN1
3 Alc + ______ = Alkene
Type of reaction?
Conc. H2SO4 + heat
E1