Fulton sem 1 reaction reagents Flashcards
What reagents are needed for aromatic nitration
Concentrated HNO3 and H2SO4
What reagents are needed for aromatic sulfonation
SO3 in the presence of strong acid eg H2SO4
What reagents is needed for halogenating of aromatics
Halogen (Br2,Cl2) and a Lewis acid catalyst like FeX3 or AlX3 where X is the halogen
What reagents are needed for a friedel crafts alkylation
An alkyl halide (R-Cl, R-Br or R-I) and a Lewis acid catalyst like AlCl3
What reagents are needed for a friedel crafts acylation reaction
An acyl halide or acid anhydride and a Lewis acid catalyst such as AlCl3
What reagents are needed to produce a benzenediazonium salt from phenylamine
Sodium nitrate (NaNO2) and a strong acid like HCl
What reagents are needed to go from a diazonium salt to a halide benzene like (ArCl, ArBr, ArCN)
To chlorobenzene - Cu(I)Cl
To bromobenzene - Cu(I)Br
To cyanobenze - Cu(I)CN
What reagents are needed to go from a diazonium salt to iodobenzene
Potassium iodide
What reagents are needed to go from a diazonium salt to fluorobenzene
HBF4 then heat
What reagents are needed to go from a diazonium salt to phenol
H3O+
What reagents are needed to go from a diazonium salt to ArH
H3PO2
What reagents are needed for the oxidation of alkylbenzene and what must the substrate possess
KMnO4, H2O (95 degrees Celsius)
The substrate must possess benzylic hydrogens
What reagents are needed for the bromination of alkylbenzene
N-bromosuccinimide (NBS) and UV
What reagents can be used to selectively reduce double bonds in presence of aromatic rings
H2 Pd/C
EtOH
What reagents are needed for hydrogenation of aromatic rings
100atm of H2, nickel catalyst and 50 degrees Celsius
What reagents are used for a basic pinacol rearrangement
Sulfuric acid H2SO4
What reagent can be used for the rearrangement of epoxides
MgBr2
What reagents can be used for semipinacol rearrangements
Toluenesulfonyl chloride (TsCl)
What reagents is used for Beckmann rearrangement oxime -> amide
Concentrated sulfuric acid (H2SO4)
What reagents is used for the Beckmann rearrangement of unsymmetrical ketones
H2NOH then Al2O3
What reagents is used for the Baeyer villager reaction
Peroxybenzoic acid
What reagent is used for the favorskii rearrangement
NaOMe - sodium methoxide
What is the claisen rearrangement
Allyl phenyl ether -> allyl phenol
