Frank Marken Flashcards
What is proportional error?
Uncertainty depends on the size of the sample
What is constant error ?
The error doesn’t depend on the size of the sample
What is a random error
Causes scatter about the true value
What is a systematic error
Affects all readings in the same way
Contrast the principles and applications of the t-test and the Q-test
Qtest based on the assumption of a true random error. Evaluation of potential outliers and self consistency of data sets
T test based on the assumption of true random error. Comparison of 2 data sets. Statistical significance of differences given the standard deviation.
What could cause a systematic error?
Incomplete dissolution Poor drying Wrong reagent concentrations Poor technique Incorrect instrument settings Wrong calibrations
What could cause a random error?
Is meniscus on the mark Temperature Draughts Angle of holding the pipette Drainage time Underlying natural fluctuation
What is AFS
Secondary emission lines are possible after excitation into a higher electronic state and rapid decay or collision induces changes before emission