Formulas 5.1 - Masses of Particles Flashcards
How do you calculate the approximate mass of an atom relative to carbon-12 isotope?
(# of Protons + # of Neutrons ) * 12
12
What formula do you use to calculate Relative Atomic Mass from Isotopic Masses and Percentage Abundances?
Using the data below, calculate the relative atomic mass of Silver.
Ar = (106.9 * 51.8) + (108.9 * 48.2)
100
= 5537.42 + 5248.98
100
Ar(Ag) = 107.86
Using the data below, calculate the relative atomic mass of Hydrogen.
Ar = (1.008 * 99.986) + (2.014 * 0.014) + (3.016 * 0.0001)
100
= 100.786 + 0.028 + 0.000
100
Ar(H) = 1.008
What formula is used to calculate the Percentage Abundance of each isotope from the mass spectrum?
Peak Height for each isotope
Total Peak Height = Sum of Peak height for each isotope
then multiply by 100.
Repeat for each Isotope
Using the data below, calculate the percentage abundance of each of the three isotopes.
Iso 1: 2.2Pb
Iso 2: 2.8Pb
Iso 3: <span>5</span>Pb
Total Peak Height = (5 + 2.8 + 2) = 10
- 2 / 10 * 100 = 22%
- 8 / 10 * 100 = 28%
- 0 / 10 * 100 = 50%
What formula do you use to calculate the percentage abundance of each isotope from the mass spectrum?
Step 1: Abundance of the Lighter Isotope
Ar (Relative Isotopic mass)
= ( (Relative Isotopic mass Light * x) + (Relative Isotopic mass Heavy * (100 - x) ) / 100
= x%
Step 2: Abundance of the heavier isotope = 100 - x%
The element Litium has two isotopes:
6Li with a relative isotopic mass of 6.02
7Li with a relative isotopic mass of 7.02
The relative atomic mass of lithium is 6.94. Calculate the percentage abundance of the lighter isotope.
6.94 = ( 6.02x + (7.02 * (100 - x) )
100
6.94 = 6.02x + 702 - 7.02x
100
(x 100 each side) 694 = 6.02x + 702 - 7.02x
(Align x’s on one side) 694 - 702 = 6.02x - 7.02x
(Simplify) -8 = -1x
(x -1 each Side) x = 8%
What formula do you use to calculate the relative Molecular Mass of Molecules?
Mr = (# of Atoms * Relative Atomic Mass from the periodic table) + (# of Atoms * Relative Atomic Mass from the periodic table)
Calculate the Relative Molecular masses of
ammonia (NH3)
Ar(N) = 14.0 Ar(H) = 1.0
1 x N Atom 3 x H Atom
Mr = (1 * Ar(N)) + (3 * Ar(H)
Mr = (1 * 14) + (3 * 1)
Mr = 14 + 3
Mr = 17
What formula do you use to calculate the relative formula mass of ionic compounds?
Mr = (# of Atoms * Relative Atomic Mass from the periodic table) + (# of Atoms * Relative Atomic Mass from the periodic table) etc.
Calculate the Relative Molecular masses of sodium carbonate (Na2CO3)
Ar(Na) = 23.0 Ar(C) = 12.0 Ar(O) = 16.0
2 x Na Atom 1 x C Atom 3 x O Atom
Mr = (2 * Ar(Na)) + (1 * Ar(C)) + (3 * Ar(O))
Mr = (2 * 23.0) + (1 * 12.0) + (3 * 16.0)
Mr = 46.0 + 12.0 + 48.0
Mr = 106.0 (Don’t forget the .0 at the end)