Formation Of Coloured Ions Flashcards

1
Q

Ligands split the 3d sub shell into

A

Two energy levels

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2
Q

Most electrons occupy the

A

Lower orbital/ ground state

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3
Q

To jump up to the higher orbital (excited state) the electrons need

A

Energy equal to the energy gap (deltaE)

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4
Q

DeltaE =

A

hv

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5
Q

Four factors affecting size of energy gap

A

1) central metal ion
2) cmi ox state
3) ligand
4) co ord no.

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6
Q

Colours of compounds (reflected) are the compliments of those

A

Absorbed

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7
Q

If there are no 3d electrons or the 3d sub shell is full then the compound will appear

A

White or colourless

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8
Q

Three causes of colour change

A

1) change in ox state
2) change in ligand
3) change in co ord no.

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9
Q

Spectrometry can be used to find conc of tmi by

A

Shining white light through a filter at an ion solution where the amt of light absorbed is recorded by a colorimeter

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10
Q

The higher the conc of solution the…the amt light absorbed

A

Higher

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