Formation Of Coloured Ions Flashcards
Ligands split the 3d sub shell into
Two energy levels
Most electrons occupy the
Lower orbital/ ground state
To jump up to the higher orbital (excited state) the electrons need
Energy equal to the energy gap (deltaE)
DeltaE =
hv
Four factors affecting size of energy gap
1) central metal ion
2) cmi ox state
3) ligand
4) co ord no.
Colours of compounds (reflected) are the compliments of those
Absorbed
If there are no 3d electrons or the 3d sub shell is full then the compound will appear
White or colourless
Three causes of colour change
1) change in ox state
2) change in ligand
3) change in co ord no.
Spectrometry can be used to find conc of tmi by
Shining white light through a filter at an ion solution where the amt of light absorbed is recorded by a colorimeter
The higher the conc of solution the…the amt light absorbed
Higher