Forensic chemistry Flashcards
What is Catenation?
The ability to form bonds between atoms of the same element
What is the suffix and example of an alkane?
-ane
Ethane
What is the suffix and example of an Alkene?
-ene
Ethene
What is the suffix and example of an Alkyne?
-yne
Ethyne
What is the suffix and example of an Haloalkane?
halo-
Chloroethane
What is the suffix and example of an Alcohol?
-ol
Ethanol
What is the suffix and example of an Aldehyde?
-al
Ethanal
What is the suffix and example of an Ketone?
-one
Ethanone
What is the suffix and example of an Carboxylic acid?
-oic acid
Ethanoic acid
What is the suffix and example of an Acyl chloride?
-oyl chloride
Ethanoyl chloride
What is the suffix and example of an Amide?
-amide
Ethanamide
What is the suffix and example of an Ester?
-yl -oate
Methyl ethanoate
What is the suffix and example of an Nitrile?
-Nitrile
Ethanenitrile
What is the suffix and example of an Amine?
-amine
Methylamine
What is the suffix and example of an Nitro?
Nitro -
Nitroethane
What is the suffix and example of an Sulphonic acid?
-sulphonic acid
benzene sulphonic acid
What is the suffix and example of an Ether?
-oxy -ane
Ethoxyethane
What is a free radical?
Reactive species which possess an unpaired electron
What are some ways a free radical is formed?
Homolytic fission of covalent bonds
Formed during chlorination
Formed during thermal cracking
What are the conditions needed in the Chlorination of Methane?
Uv light
Sunlight
What type of reaction is the chlorination of methane?
Free radical substitution
What are the bond angles around a C=C bond?
Planar
120
What is CIS isomerism?
Groups/atoms are on the same side of the double bond
What is Trans isomerism?
Groups/atoms are on Opposite sides across the double bond
What mechanism do Alkenes often undergo?
Electrophilic addition
What is the structure of a carbonyl group?
C=O bond
bond is polar due to electronegativity
How are aldehydes formed?
Oxidation of primary alcohols
How are Ketones formed?
Oxidation of secondary alcohols
Where do carbonyls have an IR peak?
1600-1900cm-1
What compound forms an orange precipitate with carbonyls?
2,4-dinitrophenylhydrazine
What is tollens reagent and what does it do?
Ammoniacal silver nitrate
Oxidises aldehydes forming a silver mirror
What is the equation involving the silver mirror test?
[Ag(NH3)2]+