FOODEMULSIFIERS Flashcards
Surfactants (surface-active agents) are molecules that
migrate to the interface between two phases
FUNCTIONS OF EMULSIFIER: facilitate formation of
smaller oil droplets during emulsification process
FUNCTIONS OF EMULSIFIER: stabilising
the emulsion once it has formed
1) FACILITATE FORMATION OF EMULSION with high
interfacial tension at an oil-water interface
Emulsifiers adsorb
onto the interface during emulsification
Reduce the interfacial tension and increase
interfacial area between oil &water
2) Emulsifiers stabilize emulsions by accumulating
at the interface of the two phases where they
form a barrier that prevents the droplets of the discontinuous phase from coalescing
Amphoteric: hv both
positively and negatively charged ions
Emulsifiers that are easily soluble in water (more hydrophilic)
produce o/w emulsions.
The emulsifier interacts strongly with the water
reducing the surface tension of the water
approaches zero
Lipophilic emulsifiers are not water-soluble and
interact with the oil phase
the surface tension of the water is not
significantly reduced so
it remains as discrete droplets in the oil,
producing a w/o emulsion
3 classifications of emulsifiers based on their molecular weight
solid, high, low
solid
stabilize oil droplets in emulsions through adsorption at the interface (eg starch nanocrystals)
High molecular weight
Contain both hydrophobic and
hydrophilic moieties in their
polymer chain (eg protein, gum arabic, certain pectins)
Low molecular weight
Have hydrophilic head & hydrophobic tail (lecithin)
SYNTHETIC EMULSIFIERS are made from
fats, oils, glycerols, organic acids,
Monoglycerides as synthetic emulsifiers
produced by esterification or alcoholysis of edible fats and oils or fatty acid with glycerol in the presence of a catalyst
NATURAL EMULSIFIERS
- Polysaccharide
- Protein-based
Many proteins are surface active because
they contain a mixture of hydrophilic and hydrophobic amino acids along their polypeptide chains.
protein can adsorb….. and coat…..
adsorb to oil–water interfaces and coat the oil droplets formed during homogenization
protein Stabilize droplets from aggregation by
electrostatic repulsion [negative (COO−) or positive(NH3+)charges] & steric repulsion (thick layer)
eg of protein emulsifier
Caseins , whey proteins (a-lactalbumin, b-lactoglobulin, immunoglobulins), gelatin, soy proteins, and pea proteins
Most polysaccharides are
highly hydrophilic molecules that are not particularly surface-active, and are therefore not good emulsifiers