FOODEMULSIFIERS Flashcards

1
Q

Surfactants (surface-active agents) are molecules that

A

migrate to the interface between two phases

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2
Q

FUNCTIONS OF EMULSIFIER: facilitate formation of

A

smaller oil droplets during emulsification process

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3
Q

FUNCTIONS OF EMULSIFIER: stabilising

A

the emulsion once it has formed

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4
Q

1) FACILITATE FORMATION OF EMULSION with high

A

interfacial tension at an oil-water interface

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5
Q

Emulsifiers adsorb

A

onto the interface during emulsification

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6
Q

Reduce the interfacial tension and increase

A

interfacial area between oil &water

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7
Q

2) Emulsifiers stabilize emulsions by accumulating

A

at the interface of the two phases where they
form a barrier that prevents the droplets of the discontinuous phase from coalescing

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8
Q

Amphoteric: hv both

A

positively and negatively charged ions

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9
Q

Emulsifiers that are easily soluble in water (more hydrophilic)

A

produce o/w emulsions.

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10
Q

The emulsifier interacts strongly with the water

A

reducing the surface tension of the water
approaches zero

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11
Q

Lipophilic emulsifiers are not water-soluble and

A

interact with the oil phase

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12
Q

the surface tension of the water is not
significantly reduced so

A

it remains as discrete droplets in the oil,
producing a w/o emulsion

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13
Q

3 classifications of emulsifiers based on their molecular weight

A

solid, high, low

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14
Q

solid

A

stabilize oil droplets in emulsions through adsorption at the interface (eg starch nanocrystals)

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15
Q

High molecular weight

A

Contain both hydrophobic and
hydrophilic moieties in their
polymer chain (eg protein, gum arabic, certain pectins)

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16
Q

Low molecular weight

A

Have hydrophilic head & hydrophobic tail (lecithin)

17
Q

SYNTHETIC EMULSIFIERS are made from

A

fats, oils, glycerols, organic acids,

18
Q

Monoglycerides as synthetic emulsifiers

A

produced by esterification or alcoholysis of edible fats and oils or fatty acid with glycerol in the presence of a catalyst

19
Q

NATURAL EMULSIFIERS

A
  • Polysaccharide
  • Protein-based
20
Q

Many proteins are surface active because

A

they contain a mixture of hydrophilic and hydrophobic amino acids along their polypeptide chains.

21
Q

protein can adsorb….. and coat…..

A

adsorb to oil–water interfaces and coat the oil droplets formed during homogenization

22
Q

protein Stabilize droplets from aggregation by

A

electrostatic repulsion [negative (COO−) or positive(NH3+)charges] & steric repulsion (thick layer)

23
Q

eg of protein emulsifier

A

Caseins , whey proteins (a-lactalbumin, b-lactoglobulin, immunoglobulins), gelatin, soy proteins, and pea proteins

24
Q

Most polysaccharides are

A

highly hydrophilic molecules that are not particularly surface-active, and are therefore not good emulsifiers

25
Polysaccharides tend to stabilize
emulsions by increasing aqueous phase viscosity and thereby inhibiting droplet movement
26
A number of natural or modified polysaccharides have hydrophobic groups
attached to a hydrophilic chain
27
Phospholipids are derived from
the cell membranes of plant, animal, or microbial tissues.
28
The phospholipids used in food and beverage applications are usually referred to
as lecithins
29
An emulsifier modifies gluten molecules and enhances its
film-forming power resulting in good spreadability and improvement of working efficiency. Thus, easy-rising bread can be obtained
30
When fats and oils form into crystal, an emulsifier promotes and inhibits
the crystal growth which prevents the formation of abnormal crystal