FOODEMULSIFIERS Flashcards

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1
Q

Surfactants (surface-active agents) are molecules that

A

migrate to the interface between two phases

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2
Q

FUNCTIONS OF EMULSIFIER: facilitate formation of

A

smaller oil droplets during emulsification process

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3
Q

FUNCTIONS OF EMULSIFIER: stabilising

A

the emulsion once it has formed

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4
Q

1) FACILITATE FORMATION OF EMULSION with high

A

interfacial tension at an oil-water interface

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5
Q

Emulsifiers adsorb

A

onto the interface during emulsification

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6
Q

Reduce the interfacial tension and increase

A

interfacial area between oil &water

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7
Q

2) Emulsifiers stabilize emulsions by accumulating

A

at the interface of the two phases where they
form a barrier that prevents the droplets of the discontinuous phase from coalescing

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8
Q

Amphoteric: hv both

A

positively and negatively charged ions

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9
Q

Emulsifiers that are easily soluble in water (more hydrophilic)

A

produce o/w emulsions.

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10
Q

The emulsifier interacts strongly with the water

A

reducing the surface tension of the water
approaches zero

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11
Q

Lipophilic emulsifiers are not water-soluble and

A

interact with the oil phase

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12
Q

the surface tension of the water is not
significantly reduced so

A

it remains as discrete droplets in the oil,
producing a w/o emulsion

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13
Q

3 classifications of emulsifiers based on their molecular weight

A

solid, high, low

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14
Q

solid

A

stabilize oil droplets in emulsions through adsorption at the interface (eg starch nanocrystals)

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15
Q

High molecular weight

A

Contain both hydrophobic and
hydrophilic moieties in their
polymer chain (eg protein, gum arabic, certain pectins)

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16
Q

Low molecular weight

A

Have hydrophilic head & hydrophobic tail (lecithin)

17
Q

SYNTHETIC EMULSIFIERS are made from

A

fats, oils, glycerols, organic acids,

18
Q

Monoglycerides as synthetic emulsifiers

A

produced by esterification or alcoholysis of edible fats and oils or fatty acid with glycerol in the presence of a catalyst

19
Q

NATURAL EMULSIFIERS

A
  • Polysaccharide
  • Protein-based
20
Q

Many proteins are surface active because

A

they contain a mixture of hydrophilic and hydrophobic amino acids along their polypeptide chains.

21
Q

protein can adsorb….. and coat…..

A

adsorb to oil–water interfaces and coat the oil droplets formed during homogenization

22
Q

protein Stabilize droplets from aggregation by

A

electrostatic repulsion [negative (COO−) or positive(NH3+)charges] & steric repulsion (thick layer)

23
Q

eg of protein emulsifier

A

Caseins , whey proteins (a-lactalbumin, b-lactoglobulin, immunoglobulins), gelatin, soy proteins, and pea proteins

24
Q

Most polysaccharides are

A

highly hydrophilic molecules that are not particularly surface-active, and are therefore not good emulsifiers

25
Q

Polysaccharides tend to stabilize

A

emulsions by increasing aqueous phase viscosity and thereby inhibiting droplet movement

26
Q

A number of natural or modified polysaccharides have hydrophobic groups

A

attached to a hydrophilic chain

27
Q

Phospholipids are derived from

A

the cell membranes of plant, animal, or microbial tissues.

28
Q

The phospholipids used in food and beverage applications are usually referred to

A

as lecithins

29
Q

An emulsifier modifies gluten molecules and
enhances its

A

film-forming power resulting in good
spreadability and improvement of working
efficiency. Thus, easy-rising bread can be obtained

30
Q

When fats and oils form into crystal, an emulsifier promotes and inhibits

A

the crystal growth which prevents the formation of abnormal crystal