Food Chemistry II Flashcards
Absorbed along with fats in the diet and are stored in the body’s fatty tissue and in the liver.
Fat-soluble Vitamins
Acts as coenzymes of several important enzymes for metabolic processes.
B Vitamins
B1, B2, B3, B5, B6, and B8 examples of B Vitamins (True or False)
False (True: B1, B2, B3, B5, B7, and B9)
_ is a cofactor in the hydroxylation of proline residues in collagen.
Ascorbate
It is necessary for bone remodelling.
Vitamin C
Vitamin C is also known as _
Ascorbic Acid
Iodometric determination of ascorbic acid involves ascorbic acid redox titration with iodine solution using _as an indicator.
Starch
_ is the gain of oxygen.
Oxidation
_ is the loss of oxygen.
Reduction
_ is the loss of electrons.
Oxidation
_ is the gain of electrons
Reduction
What determines the endpoint of titration?
The first excess of iodine in the reaction medium that reacts with starch.
What is formed when an excess of iodine and starch reacts in a reaction medium?
starch-iodide complex
What instrument uses the absorption or transmission of light?
Spectrophotometer
Used extensively in research and in the food industry due to its high accuracy.
High-performance Liquid Chromatography (HPLC)
Two (2) types of Rancidity
Hydrolytic and Oxidative
Rancidity is associated with characteristic off-flavors and odor of _ and _.
fats and oils
_ liberates fatty acids from the triglycerides to form di and/or monoglycerides and _.
Lipases; free fatty acids
Results when oil or fats react with oxygen.
Oxidative Rancidity
Enumerate the Primary Oxidation/Autoxidation
Initiation, Propagation, and Termination
It leads to the development of unfavorable off-flavors that can be detected early on in the development of rancidity.
Oxidative Rancidity
What happens in the Primary Oxidation “Initiation”?
- Light or heat reacts with oil and forms an alkyl radical.
- The alkyl radical reacts with oxygen to form peroxy-free radical.
In Primary Oxidation “Propagation”, what is tasteless and odorless?
Hydroperoxide
It is the process that starts until there is depletion of oxygen or when fatty radical reacts with a stable antioxidant radical or when two unstable radicals react.
Termination
What are products of the Secondary Oxidation?
Aldehydes, Ketones, Alcohols, and Acids
Primary Oxidation causes the characteristic off-flavors and odors of rancid fats and oils. (True or False)
False (True: Secondary Oxidation)
Unsaturated fatty acid such as oleic, linoleic, and linolenic are easier targets for oxidation. (True or False)
True
What factors affecting Oxidative Rancidity have detrimental effect on oil stability?
Pro-oxidants
_ acts as prooxidants by electron transfer whereby they liberate radicals from fatty acids or hydroperoxides.
Metals
The availability of what element is important in rate-determining factor as oxidation?
Oxygen
Antioxidants retard the onset of rancidity. (True or False)
False (True: onset of oxidation)
Most common pro-oxidants act as chain breakers by donating hydrogen atoms to the lipid radicals formed during initiation, thereby halting or slowing down propagation. (True or False)
False (True: Most common antioxidants)
Samples with high surface area in contact with air oxidize more rapidly. (True or False)
True
The reaction of oxygen with fats roughly doubles for every _ degrees Celsius _ in temperature.
10; increase