Fires 8 - Ignition and Investigation Flashcards
What is needed to achieve ignition of a fuel?
the fuel (even if it is just a small part of it) needs to have its temperature raised to its ignition temperature
using a source of heat
In what 6 ways can we heat things up?
1 - light
2 - electricity
3 - friction
4 - contact with something hot
5 - chemical reaction
6 - nuclear fission
What is required for radiation to effectively heat a fuel?
the fuel must be able to absorb more heat than it can dissipate
(if it absorbs the same amount of heat it dissipates, radiation won’t heat the fuel)
What can radiant heat from another fire cause?
What is the term for this?
In what settings do we see this?
radiant heat from another fire can induce another fire
flashover (essentially the radiation component applied to a whole room)
- household settings (fireplaces and heaters, stoves, floodlights and lamps etc. - anything in close proximity can be charred/ignited)
how can sunlight be focussed by lenses or mirrors?
give two examples where this may happen
it involves focussing the lens just right therefore light-initiated fire is almost impossible
broken glass and bottles e.g. wildfires
shaving mirrors at home are convex so can focus light
define electrical arcs/sparks
what are electrical arcs/sparks essentially?
when do electrical arcs/sparks occur?
what state of fuel do electrical arcs/sparks ignite?
give examples of electrical arcs/sparks?
involves the movement of current through a gas producing plasma (5000 degrees)
little zaps of electricity
occurs when there is a build up of charge either side of two things
ignites gases or vapours as it is very localised - doesn’t ignite solid fuels
static sparks, spark plugs, hob sparks, lightning
e.g. door handle and your hand - build up of charge is big enough to ionise the gas between into a plasma so get a zap
what is the difference between an electrical spark and an electrical arc?
spark is short
arc occurs over a prolonged period of time and is maintained
In what two ways can electricity cause a fire?
by direct contact with electricity particularly in gases and vapours
can also happen with overheating
How does electricity and overheating cause a fire?
- electrical currents generate heat when they meet resistance
- amount of current that a wire can carry is proportional to its diameter, material and covering
- this is normally enough to handle heat produced but when it isn’t, this is what causes a fire
In what four ways can heat build up in a wire?
1 - excessive current (wrong fuse, short circuit)
2 - tightly coiled wires which can’t dissipate heat
3 - poor or loose connection e.g. wire on a screw terminal
4 - insulation breakdown - charred wood/plastic (insulator) becomes a semi-conductor then the current can flow through material, heats up, catches alight
5 - aluminium fittings (rare but can be found in old wiring systems) - not as good a conductor as copper, makes oxide films which creates a heat barrier. after formed oxide layer on aluminium surface, it will overheat when you put too much current through it. anything near aluminium fitting could reach ignition temperature
How do lighters work?
friction initiated fire
- lighters contain ferrocerium (Fe/Ce alloy) flint
- the friction from striking this generates hot shavings (mechanical sparks)
- Ce has an ignition temperature of 150 - 180 degrees
- these sparks are formed near the fuel that comes out when your thumb depresses the switch which then ignites the fuel (light petroleum distillate vapour or butane gas) - fuel is pushed out with right fuel/air ratio
What settings can friction initiated fires occur in?
- can occur in poorly lubricated train bearings (i.e. trains and industrial machinery)
- if the heat generated is great enough one of the two surfaces rubbing together can disintegrate and produce shower of incandescent particles
- spread to things around it and cause them to reach ignition temps
not likely to occur in the home
explain process of spontaneous combustion
- some substances have naturally occurring exothermic reactions (chemical oxidation, biological fermentation etc.)
- heat is lost from surface of the material and this is fast enough that the heat doesn’t build up
- if the dissipation isn’t quick enough, the temp starts to rise in the interior
- this accelerates the reaction so the heat generated gets lost more rapidly - results in an equilibrium temperature
- in a large quantity of material, the surface area is relatively small. as material gets bigger, relative surface area gets smaller but there is more material to heat up so it takes a long time
- therefore equilibrium temp is higher for larger quantities of material
- if temp exceeds auto-ignition temp, a fire can start within the bulk of the material
- this process can take a considerable time (many hours)
Give examples of chemical reactions that can mimic arson attacks
- fire in rubbish bin can look intentional
- microbe breaking down sawdust, coal dust, hay, straw and landfill waste
- unsaturated (‘drying’) oils that are soaked into rags, paper etc.
- unsaturated C=C bonds oxidise in air exothermically
- more C=C bonds = increase in likelihood of hazard
- some reactive species like K, Na metal that oxidise in air
Explain how gas fires occur
Why are they not likely?
- excessive gas isn’t commonly the cause of a fire
- when a gas fire does occur, the fires are usually caused by an initial explosion
- gas awareness is good so mistakes aren’t frequent
- any hot surfaces in boilers are tucked away and well insulated
How can arsonists disguise an intentional fire?
But what is problem with this?
- by setting it under an oven, BBQ etc.
- but need to prove a fault in gas appliance to rule out arson
- accidental fire needs evidence of not only origin but faults too
What can initiate accidental gas fires?
broken furnaces or driers can initiate fires by thermostat failure