Fires 8 Flashcards
What are the different ways that we can heat things up?
- Light
- Electricity
- Friction
- Contact with something hot
- Chemical reaction
- Nuclear fission
How do you achieve ignition?
The fuel (even if its just a small part of it) needs to have its temperature raised to its ignition temperature
How does radiation/light cause fires?
- Fuel must be able to absorb more heat than it can dissipate
- Radient heat from a fire can induce another fire (flashover)
- Sunlight can be focused by lenses or mirror if positioned just right
How does electricity cause fires?
- Sparks and arcs involves the movement of current through a gas, producing plasma
- Very localised so only ignites gases or vapours
- The build up of charge is big enough to ionise the gas between into a plasma
What is the difference between sparks and arcs?
- Sparks are shorter and smaller
- Arcs are longer and maintained
How does electricity cause fires in regards to overheating?
- Electrical currents generate heat when they meet resistance
- The amount of current that a wire can carry is proportional to its diameter, material and covering
What causes overheating in wires?
- Excessive current (wrong fuse, short circuit)
- Tightly coiled wires (which cant dissipate heat)
- Poor or loose connection
- Insulation breakdown (charred wood/plastic becomes a semi-conductor)
- Aluminium fitting (old) - not as good as a conductor like copper
How does friction cause a flame in lighters?
- Friction from striking the ‘flint’ generates hot shavings (mechanical sparks)
- This process is hot enough to auto-ignite the cerium in the flint
- These sparks are formed near a fuel which comes out when your thumb touches a button
- This can also occur in poorly lubricated train bearings
What is spontaneous combustion?
When some substances have naturally occuring exothermic reactions
How is an equilibrium temperature reached?
- Heat is lost from the surface of a material
- But the interior temperature continues to rise
- This accelerates the reaction but as this happens heat gets lost more rapidly
How does the size of an object affect a chemical reaction?
- In a large quantity of material, the surface area is relatively small
- Therefore there is more material to heat up and so it takes longer to reach the auto-ignition temperature
- The equilibrium temp is higher
What naturally occuring chemical reactions can mimic arson attacks?
- Sawdust, coal dust, hay, straw and landfill waste will get broken down by microbes and will exothermically generate heat
- Unsaturated (drying) oils that are soaked up in rags and papers will oxidise in air exothermically and then become fuel
- Some reactive species oxidise in air (K, Na metal, group 1)
Why do accidental fires need evidence of origin and faults?
Arsonists may disguise an intentional fire by setting it under an oven/BBQ to make them look accidental
What are examples of that can start gas flame fires?
- Open flames
- Cooking oils
- Bunsen burners
- Portable gas stoves
- Grease
- Towels
- Paper
- Clothing
Where will you find hot and burning fragments/sparks?
- Rubbish
- Bonfires
- Lanterns