Final KB Qs Module 4: Flotation Flashcards
Draw flotation cell and explain flotation in 3 points.
- Hydrophilic materials remain in suspension whereas hydrophobic minerals attach to air bubbles and enter the froth phase
- The hydrohilic gangue minerals are removed as the tailing fraction
- The mineralised froth overflows and is recovered as the concentrate
For multiple flotations in a row show how to find Cumulative recovery.
Give cumulative recovery vs time curve.
Give the assumed first-order reaction Recovery curve fomula.
R = Rmax * [1 – exp(-kt)]
Rmax which is the maximum theoretical flotation recovery
What is entrainment?
Non-selective recovery of particles in water recovered to float product. Water recovered because:
- Flow patterns in mixed/mechanical cells
- in pulp zone carried in water layer and wake behind bubbles
- pushed into froth (“bubble swarm effect”)
- carried through froth in Plateau borders
What is entrapment?
Entrapment is when the particles are trapped between other particles in the froth – non selective
Draw recovery vs particles size for Strongly hydrophobic, Weakly hydrophobic, Entrained.
Name reagents that can be added to the slurry to enhance the separation.
- Collectors
- Frothers
- Activators
- Depressants
- pH modifiers
Explain Frothers purpose in 2 and how they do it.
- They preserve the small bubbles produced
- They enable a stable froth to be formed at the surface
Frothers adsorb onto the surface of the bubbles, modifying the surface properties
Draw the classic representation of contact angle and surface tension forces.
Explain Collectors what they do and how they do it in 2.
Collectors are added to selectively adsorb onto a mineral surface and increase the hydrophobicity
- Contains a polar “head” which is hydrophilic (Polar head attaches to the mineral surface)
- Non-polar hydrocarbon “tail” which is hydrophobic
Explain Activators what they do.
An activator adsorbs to the surface of a particle, and induces a high affinity to the collector.
Explain Depressants what they do.
Depressants adsorb to the surface of hydrophobic minerals in order to render the surfaces hydrophilic. Therefore, separation of two hydrophobic minerals is enhanced.
Explain pH modifiers what they do.
The pH is also a factor in the physical adsorption. Adsorption of cationic surfactants, and consequently
flotation is depressed as pH is increased, and vice versa. This affects the ability of the collector to do his job.
Give the Size-by-size recovery formula.