final exam questions Flashcards
Two accelerators for gypsum?
- Sodium sulfate (low conc)
- Potassium sulfate and sodium chloride (low conc)
how does tri-sodium phosphate act as a retarder
tri-sodium phosphate reacts first with calcium sulphate. then sodium alginate reacts with calcium sulphate
should impression materials be plastic or elastic? why?
elastic; required to be stretched to a fairly large degree without suffering any permanent deformation (as in during removal of impression – put under compressive and tensile stress); plastic materials lack ability to record any undercut
why do u need adhesive on the tray
detached is grossly distorted and will lead to ill-fitting resto
Two retarders for gypsum?
- borax
- sodium chloride (high conc)
- sodium sulfate (high conc)
- glue
- agar
- coagulated blood
What provides the driving force for the setting reaction of gypsum?
water molecules in the dihydrate are found in alternating double layers
-dehydration process requires a lot of energy because the dihydrate is more stable at room temperature
What is the base, reactor, and retarder for alginate?
Base – Na alginate
Reactor – calcium sulphate
Retarder – tri-sodium phosphate
what is the activator for cold-cure PMMA
dimethyl-p-toluidine
criteria for good impression
- uniform, homogenous mix
- tray adhesive applied
- rigid impression tray
- no void or pulls on margins
- detailed margin
- no burn through of tray
- strong bond between light and heavy
shrinkage of polymeric material is caused by
- VDW volume reduction (due to single bonds)
2. free volume reduction (less rotation and distance)
4 reasons why we use custom trays
- Record most out of reach anatomical landmarks
- Minimize impression material distortion
- Prevent tissue distortion (can use low viscosity materials)
- Reduced cost
what can affect the mechanical/physical properties of a polymer
molecular weight and degree of polymerization
effect of oxygen on poly
- decrease rnx velocity
- decrease deg of poly
syneresis
loss of water from alginate
-excess water in contact with gypsum
name all components of alginate
- na/k alginate
- calcium sulphate
- tri-sodium phosphate
- mineral/silicon fillers
- potassium fluoride
- pigment particles
- organic glycol
imbibition
alginate absorbs water from gypsum
why might you have lack of detail on impression
- low temp (prolonged setting time; increase viscosity)
- too much pooled liquid (impression material doesnt flow)
What stage(s) does expansion occur during gypsum setting?
Plastic and friable stages
what type of impression material is alginate
irreversible aqueous hydrocolloid
Is alginate a hydrocolloid? what does it mean?
yes. hydrocolloids are uniform distribution of individual particles of one substance in water
list all properties of PMMA
- colourless
- any shade
- radiolucent
- chemically stable
- knoop hardness 15 to 18
- Tg=125 deg c
- absorb water
- low thermal conductivity
components of powder PMMA
- pre-polymerized beads of PMMA
- initiator: benzoyl peroxide
- plasticizer: dibutyl phthalate
- inorganic particles (hardness)
- organic pigments and dyes