Final Exam Flashcards

1
Q

In the nucleophilic substitution at saturated carbon experiment, you prepared a 100mL of 50% 2-propanol and 50% water as a solvent. Then you reacted 2-bromo-2-methylpropane and 2-bromopropane in the presence of a NaOH hydroxide solution. Which alkyl halide reacted first and why?

A

2-bromo-2methylpropane because the reaction goes through SN1 mechanism

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2
Q

Why was H2SO4 utilized during the dehydration of alcohol?

A

H2SO4 was utilized during the reaction to facilitate the formation of water which is the leaving group

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3
Q

Dehydration of 2-methylcyclohexane is a

A

elimination reaction

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4
Q

In the dehydration of cyclohexanol experiment, you added at the end anhydrous CaCL2 what was the purpose of it?

A

to remove any water (dry the product)

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5
Q

A test for the presence of C=C where the purple color of the KMnO4 decolorized and brown precipitate of MnO2 is formed. This reaction is called…

A

solubility

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6
Q

What will happen when bromine is added to ethene?

A

reddish brown color of bromine dicolorised

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7
Q

Which reagent was used in Baeyers test?

A

KMnO4

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8
Q

What is formed from CH3-CH=CH2 + Br2 –>

A

CH3CHBrCH2Br

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9
Q

Potassium permanganate in alkaline solution can be used to oxidise ___ to 1,2-diols

A

alkenes

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10
Q

Baeyers oxidation reaction is an example of ?

A

syn addition

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11
Q

Bromine addition to unsaturated hydrocarbon follows?

A

anti-addition

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12
Q

Which tests show can be used to show that a phenol is present?

A

iron (iii) chloride test

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13
Q

A positive chromic acid test gives what shade of color?

A

green

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14
Q

which of the following would NOT react in the chromic acid test?

A

tertiary alcohols

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15
Q

Conversion of an aldehyde to an alcohol is generally known as…

A

oxidation

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16
Q

Which pairing of alcohol and class is incorrect?

A

pentan-3-ol ; tertiary alcohol

17
Q

Treatment of pentan-1-ol with Jones reagent is expected to give which one of the following products?

A

pentanal

18
Q

An organic compound reacts with FeCL3 and a purple color I observed after the reaction. What kind of functional group is expected in the organic compound used?

A

phenol

19
Q

Phenols are good acid due to

A

resonance stabilized phenoxide ion

20
Q

Which of the following statements regarding the E1 mechanism is wrong?

A

reaction by the E1 mechanism usually occur in one step

21
Q

Which of the following statements regarding the SN2 mechanism is wrong?

A

SN2 reaction usually occur in two steps

22
Q

Which of the following statements regarding the SN1 mechanism is wrong?

A

the SN1 mechanism involves a single step

23
Q

Which is the most reactive compound by the SN2 mechanism

A

CH3CH2CH2CH2Br

24
Q

Which of the following statements is wrong?

A

the rate constant of an SN2 reaction does not depend on the nucleophile