Final Flashcards

1
Q

ΔHrxn = …

A

ΔE + PΔV

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2
Q

ΔE = …

A

q + W

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3
Q

PΔV = …

A

-W

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4
Q

frequency =

A

c/wavelength

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5
Q

Energy =

A

h*frequency = hc/wavelength

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6
Q

de Broglie relation:

A

wavelength = h/(m*velocity)

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7
Q

Stupid space donut:

A

z^2

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8
Q

Positive ΔH and q =

A

Endothermic. Vaporization.

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9
Q

Negative ΔH and q =

A

Exothermic. Condensation.

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10
Q

Positive work:

A

Work done ON the system

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11
Q

Negative work:

A

Work done BY the system

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12
Q

Constant P:

A

Lower heat production

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13
Q

Constant V:

A

More heat production

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14
Q

Paramagnetic:

A

Has unpaired electrons. Interacts with magnetic field.

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15
Q

Diamagnetic:

A

No unpaired electrons. Does not interact with magnetic field.

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16
Q

Pauli exclusion principle:

A

No two electrons can have the same quantum number.

17
Q

Aufbau principle:

A

Orbitals fill from lowest to highest energy level.

18
Q

Hund’s rule:

A

One electrons per orbital with parallel spin until it becomes necessary to double up.

19
Q

Exceptions to Aufbau principle:

A

Cr, Cu

20
Q

Periodic table trends:

IE? Atomic radius? Metallic character?

A

IE = He
Radius = Rb
Metallic character = Rb

21
Q

Lowest IE =

A

Most exothermic

22
Q

Cations vs atoms vs anions

A

Cation < atom < anion

23
Q

What happens to reactivity as IE decreases?

A

Reactivity increases

24
Q

What happens to atom size as effective charge increases?

A

Atom size decreases

25
Q

Boyle’s law:

A

V -> 1/P

26
Q

Charles’ law:

A

V -> T

27
Q

Avogadro’s law:

A

V -> n

28
Q

What goes up when IMF goes up?

A

SA, mm, viscosity, length, pressure

29
Q

What goes down when IMF goes up?

A

Vapour pressure

30
Q

What happens to viscosity when temp goes up?

A

Viscosity decreases

31
Q

What happens to average energy when temp goes up?

A

Average energy increases

32
Q

What happens to boiling point as pressure increases?

A

Boiling point increases

33
Q

Metal/halogen reaction:

A

2M + X(2) -> 2MX

34
Q

Millikan oil drop experiment:

A

Charge of electron

35
Q

Rutherford gold foil experiment:

A

Atom model, nuclear theory