FINAL Flashcards

1
Q

methyl is …

A

1 carbon

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2
Q

ethyl is …

A

2 carbon

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3
Q

propyl is …

A

3 carbon

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4
Q

butyl is …

A

4 carbon

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5
Q

electronegativity trend

A

up and to the right

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6
Q

what do shapes in orbitals mean

A

probabilities

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7
Q

how many p orbitals and what is special about their relationship

A

3… all orthogonal

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8
Q

hybridization of a carbon bonded to two other atoms? what is bond angle?

A

sp … 180

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9
Q

hybridization of a carbon bonded to three other atoms? what is bond angle?

A

sp2 … 120

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10
Q

hybridization of a carbon bonded to four other atoms? what is bond angle?

A

sp3 … 109

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11
Q

name hybridizations in order of increasing strength

A

sp3, sp2, sp

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12
Q

name hybridization in order of increasing bond length

A

sp, sp2, sp3

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13
Q

which hybridization is known to be more acidic? why?

A

sp because more s character and it is lower in energy

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14
Q

what is an important factor to keep in mind when dealing with hybridization

A

if resonance affects it

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15
Q

which is assigned a negative dipole

A

the more electronegative

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16
Q

direction of dipole movement

A

positive dipole to negative

17
Q

what does the length of the dipole vector mean

A

strength/distance (change in electronegativity)

18
Q

list the hybridizations in order of increasing energy

A

sp, sp2, sp3

19
Q

how can there be no net dipole

A

dipoles move in equal and opposite directions

20
Q

formal charge equation

A

charge = val e- - # bonds - # non-bonded e-

21
Q

what side is more favorable with regards to pKa

A

side with greater pKa

22
Q

which carbonanion is more stable

A

larger?

23
Q

when is hypovalent ok

A

in carbon

24
Q

when is hypervalent ok

A

never

25
Q
A