FINAL Flashcards
What is soil organic matter and what does it do?
0-10% of soil volume
In surface soils
Driver of soil life
Improves physical characteristics (structure, porosity and Db), increases water holding capacity, soil structure and aggregation, decreases bulk density while increasing porosity
Improves chemical characteristics, increases CEC and makes soil more resistant to pH changes
Improves biological activity – slow release fertilizer for N, P, K and S
Supports large and varied microbial communities
inorganic vs organic C
Inorganic C: CO2 in soil and air and carbonates (in lithosphere) – ex. Ca, Mg, K, Na
Organic C: soil organic matter and carbon
What are the typical sizes of carbon reservoirs?
Active pool = 3000Pg
Turnover: CO2 - CHO - CO2
Sedimentary rocks = 10^8Pg
Turnover: geologic - active - geologic
Ocean and lakes: 36000Pg
Lithosphere: 75MPg
Atmosphere: 800Pg
Hydrosphere: 36000Pg
What is soil health?
the continued capacity of the soil to function as a vital living ecosystem that sustains plants, animals and humans through nutrient cycling, water, filtering, buffering, physical stability/support and as a habitat for biodiversity
SOC vs SOM
SOC = 0.58SOM
SOM = 1.72SOC
How is SOC measured?
Measurement of SOC = dry combustion (20mg)
Carbon released measured as CO2
Analytical
How is SOM measured?
SOM = measured by loss on ignition (5g)
Gravimetric
What is SOM composed of?
58% C
3-5% H
30-40% O
2-5% N
Living biomass, humus, residues/detritus, non-humic substances and humic substances
What is decomposition?
chemical reaction occurring during the decay of plant/animal remains
Altered chemical composition to produce E
What is mineralization?
release of soluble or gaseous inorganic constituents during decomposition
What is humification (old vs new theory)?
decomposition results in black, greasy OgM
Old theory: condensation reaction – low molecular weight biopolymer to high MW biopolymer
New theory: stabilization of SOC by 3 mechanisms
What is cellulose?
linear polymer of glucose units (polysaccharide, carbohydrate) – about 30% of plant material (cell wall)
What is hemicellulose?
branched polymer of different sugars (glucose, fructose, polysaccharide) – about 20% of plant material
What is lignin?
branched, aromatic polymer (volatile) – about 20% of plant material (woody material)
What are lipids?
fats/waxes – about 20% cellular material
What is protein?
amino acids (N is present), biochemical machine (photosynthesis) – high N content, about 5% of plant material
What is the old theory of humification?
theoretical framework derived from analytical methods – alkali extraction method produced 3 fractions – theory of C stability determined from this data
In order of increasing complexity and decreasing N
Protein > hemicellulose > cellulose > lignin > fats
What are humic fractions?
Operationally defined fractions: humin, humic acid and fulvic acid
Historic method for examining soil fertility
Fractions are artifacts of extraction procedure
What is the SOM stabilization theory?
Contemporary theory
Based on decreasing molecular size
Stabilization in aggregates and on mineral surfaces
Generates a lot of data saying old theory is wrong – we can have very old C in soil but made up of labile constituents – humus doesn’t exist, it is made up of identified biopolymers
What is the soil carbon model?
Plant residue to microbe using an enzyme system to SOM (mineralization and stability)
Low vs high C:N
Lower ratio = implies labile plant residue or fertile/easily decomposed SOM
High ratio = implies resistant plant residue or less fertile/harder to decompose SOM
What is mean residence time?
time of atoms to cycle through pools – plant residue (biopolymers, some chemical resistance) – affects turnover
What are the SOM theoretical pools?
chemical/physical protection and organo-mineral associations
What are the E sources?
Photo = suns E
Chemo = E from organic C
Litho = E from soil redox reaction
People = chemo-heterotrophs
Plants = photoautotrophs
Fungi = chemo-heterotrophs
Bacteria = everything (capable of alternate metabolism
What are the C sources?
Autotrophs use CO2
Heterotrophs use organic C