Factors effecting reaction rate Flashcards

1
Q

what does collision theory explain

A

how reactions occur and why they occur at different rates

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2
Q

what must happen for chemical reactions to happen

A

particle collision must occur

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3
Q

what is the activation energy

A

The activation energy is the minimum energy with which particles must collide in order to cause a chemical reaction.

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4
Q

what are the four main factors affecting reaction rates

A

1) Temperature
2) Concentration
3) Pressure
4) Surface area
5) Catalysts

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5
Q

what does increasing the concentration of dissolved reactants do

A

increasing the concentration of dissolved reactants increase the number of particle collisions

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6
Q

what does increasing the pressure of the gas reactants do

A

Increasing pressure is like increasing the concentration.

It increases the frequency (number) of collisions. This increases the rate of reaction (makes the reaction faster).

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7
Q

what does increasing the temperature do

A

Increasing the temperature increases the frequency (number) of collisions.

Increasing the temperature increases the energy of reactant particles. This means that a greater proportion (more) of the particles will have more energy than the activation energy that is needed.

Together, these lead to more successful collisions. This increases the rate of reaction.

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8
Q

what does increasing the surface are of the solid reactants do

A

Increasing the surface area increases the frequency (number) of collisions. This increases the rate of reaction.
This is often done by breaking up solids into smaller lumps (e.g. powders).

This increase in surface area to volume ratio makes sure that more particles are exposed to attack.

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9
Q

what does a catalyst do

A

catalysts speed up chemical reactions and cannot be used up during the process

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10
Q

what are the properties of reactants

A

1) Surface area of solid reactants
2) Concentration of dissolved reactants
3) Pressure of gas reactants

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11
Q

how do catalysts increase the rate of chemical reactions

A

catalysts increase the rate of chemical reactions by lowering the activation energy by providing a different reaction pathway

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12
Q

what does catalysts not being used up in reactions mean

A

1) it can be re-used indefinitely

2) they are not found in chemical equations

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13
Q

what will catalysts often need after being used

A

1) Catalysts will often need a clean after usage

2) Catalysts may require regeneration

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14
Q

what are enzymes and where can they be found

A

enzymes are biological catalysts which can be found in yeast to produce alcohol

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15
Q

what do catalysts often come as and why

A

catalysts often come as powders, pellets or fine gauzes as these substances have a high surface area

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16
Q

what does the collision theory state

A

the collision theory states that in order for a chemical reaction to take place particles must collide with sufficient energy

17
Q

What is a potential drawback of a fast rate of reaction in industry?

A

Expensive to generate conditions for a fast reaction

18
Q

When sodium thiosulfate reacts with hydrochloric acid, it produces sulfur amongst other things. The sulfur is a solid and causes the reaction solution to go cloudy.
A student carried out three experiments, mixing sodium thiosulfate with hydrochloric acid:

Experiment A:

25 cm3, 1 moldm-3 Sodium Thiosulphate + 25 cm3, 1 moldm-3 Hydrochloric Acid. 25 oC

Experiment B:

12.5 cm3, 1 moldm-3 Sodium Thiosulphate + 25 cm3, 1 moldm-3 Hydrochloric Acid. 25 o

Experiment C:

25 cm3, 1 moldm-3 Sodium Thiosulphate + 25 cm3, 1 moldm-3 Hydrochloric Acid. 35 oC

How could the student compare the rate of reaction between the experiments?

A

By measuring the time taken for the mixture to reach a certain level of cloudiness.

The best way to do this would be to put a piece of paper under the conical flask with the reactants in it. Measure the time taken for the cross to disappear.