F325 Flashcards
Lattice enthalpy@
The enthalpy change that accompanies the formation of one mole of an ionic compound from its gaseous ions under standard condition. (Tick)
Enthalpy change of neutralisation @
The energy change that accompanies the neutralisation of an acid by a base to form 1 mole of H2O under standard conditions.
Strong acid @
Completely dissociate in solution @
Weak acid @
Partially dissociate in solution
Transition element @
A d-block element that forms an ion with incomplete d sub-shell. (tick)
Bidentate ligands @
Donates 2 lone pair of electrons to the central metal ion to form two coordinate bonds. (tick)
Ligands @
Donates a pair of electrons with the transition metal ion to form a coordinate bond. (tick)
Complex ion @
A transition metal ion bonded to one or more ligands by coordinate bonds. (tick)
Bronsted-lowry base @
Proton acceptor
Bronsted-lowry acid @
Proton donor
Lewis acid @
Lone pair acceptor
Standard electrode potential @
The e.m.f of a half cell compared with a standard hydrogen half cell measured at 298K with conc of 1 moldm-3.(tick)
Buffer solution @
A solution that minimises changes in pH after addition of small amount of acid or base. (tick)
What is pH @
pH= -log[H+]
tick
Initial rate of reaction @
Rate at start of reaction/ t=0
tick
Half-life of reaction @
Time for concentration of a reactant to fall to half original value. Half life of a first order reaction is independent of the concentration.
Rate of reaction @
The change in concentration of reactant or product per unit time. (tick)
Rate-determining step @
The slowest step in the reaction mechanism of a multi-step reaction
Enthalpy change of atomisation @
The enthalpy change that take place when one mole of gaseous atoms forms from the element under standard state. It is endothermic process because bonds have to be broken.
Enthalpy change of solution @
The enthalpy change when one mole of a compound is completely dissolved in water under standard conditions.
Standard enthalpy change of hydration @
The enthalpy change when one mole of gaseous ion is dissolved in water forming one mole of aqueous ions under standard conditions. Always exothermic because bonds are made between the ions and water molecules.
Lewis base @
Lone pair donor
Le chatelier’s principle @
The position of equilibrium will shift so as to minimise the effect of any change in conditions.
Enthalpy change of formation @
The enthalpy change that take place when 1 mole of a compound is formed from its constituent elements in their standard states under standard conditions.