Extrusion Processing Flashcards

1
Q

What is extrusion?

A

Continuous process for producing shapes of constant cross-section by forcing material through a shaped die with pressure.

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2
Q

What are the forms of products produced by extrusion?

A

Pipes - water, gas, sewage, plumbing

Profiles - windows, guttering, trunking

Sheet - roofing, cladding, vacuum forming

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3
Q

What are the pros and cons of extrusion?

A

Pros:

Continuous
High production volumes
Low cost per pound
Efficient melting
Many types of raw materials
Good mixing

Cons:
Limited complexity
Uniform cross section shapes only

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4
Q

Describe the process of extrusion

A

Solid polymer feedstock is converted into a homogenous melt as it is screwed through the barrel and pumped through a die at a constant rate and uniform temp and pressure.

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5
Q

What considerations should be taken with what material is fed into the extruded?

A

Spherical granules are more efficient, powders are the worst

Condensation on granules should be avoided as water vapour may create bubbles in the melt

Need to avoid oxidation, degradation and surface contamination post-extrusion

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6
Q

Why do some barrels have cooling elements as well as heating elements?

A

Shear working can raise the temp. So may need to be cooled.

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7
Q

What is the function of the extruder screw?

A

Transport solid feedstock

Compress and melt solid

Homogenise, provide sufficient pressure to pump melt against die resistance

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8
Q

What are the three features of an extruder screw?

A

Feed zone - constant screw depth, preheats material and conveys it to subsequent zones

Compression zone - screw depth decreases to compact, squeeze out air and improve heat transfer

Metering zone - constant shallow screw depth, melt homogenised to supply uniform temp and pressure to the die

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9
Q

What is bridging in the extrusion feed zone?

A

If the material is heated too quickly, resin can stick to the screw in the feed zone and rotate with it rather than be pushed forward.

To ensure it doesn’t happen, some screws are cooled with circulating water.

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10
Q

Why does the clearance h need to be as small as possible between the screw and barrel in the metering zone?

A

To prevent back flow as the pressure is high (should be of order x10-2mm)

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11
Q

What is the compression ratio?

A

Ratio of screw channel depth or volume from feed to metering zones

CR = Hfeed/Hmetering = Vfeed/Vmetering

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12
Q

What is a venting zone in an extruder screw?

A

Allows for removal of volatiles and gases.

It is a zone with an increased channel depth before a second compression zone. Volatiles and gases escape through a vent port.

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13
Q

How is a screw designed for amorphous polymers?

A

As amorphous polymers progressively soften through the Tg, they require a compression zone that covers most of the length of the screw, especially for heat sensitive polymers like PVC.

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14
Q

How is the screw designed for polymers with a sharp melting point?

A

Melting takes place quickly so compression of the melt can be performed in one pitch of the screw.

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15
Q

What does a filter do before an extrusion die? And what is a breaker plate?

A

Filters any inhomogeneous material that may clog the die. Supported by a breaker plate which has a large number of counter sunk holes to allow the melt to pass, while preventing dead spots where particles could gather.

Breaker plate also straightens the spirally melt flow emerging from the screw (changes rotational memory to longitudinal memory).

They both also help build up back pressure which improves mixing along the screw.

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16
Q

What is Barrel Residence Time?

A

Average time material resides in the barrel

17
Q

How is the overall flow rate calculated in a extruder?

A

Total Q = Drag flow + Pressure flow (negative) + Leakage flow (not usually used)

18
Q

What is leakage flow?

A

Can occur in gap between barrel and screw, mainly when screws are old and worn

19
Q

What would be the case for flow rate calculation if there was no die at the end of the extruder?

A

Pressure would be zero, Q would be max - equal to drag flow rate

20
Q

Why is the operating point of an extruder a trade off?

A

The die causes a higher pressure at the extruder outlet, so decreases the output flow rate.

However, the output from the die is increased with increasing pressure.

So the point they cross on a graph is the operating point.

21
Q

How is the operating point of an extruder found? (Equations)

A

When the equations Qdie and Qext are equal. (Extruder output and die output equal)

22
Q

How could you decrease the die head pressure while keeping the output flow rate unchanged?

A

Decrease polymer melt viscosity - increases the gradients of both extruder and die output equations

23
Q

How can you decrease the melt viscosity to aim for a reduced melt pressure? And what are the cons of doing so?

A

Increase die or extruder temperature profiles

Use a lower molecular weight

Use of additives such as lubricants or plasticisers

Beware of trade off of increased cooling or reduced mechanical properties

24
Q

What are the four die zones?

A

Screen pack
Head (die entry)
Tapered zones
Die land

25
Q

What is drawdown ratio?

A

Ratio of haul off velocity to die exit velocity OR CSA of die to CSA of extrusion

26
Q

What is haul-off equipment and why is it used?

A

Pulls extrudate away from die which counteracts the swell and helps orientate the molecules which increases linear strength

27
Q

What is the effect of high drawdown ratios?

A

Can lead to too much residual stress and cause high shrinkage of the finished profile

28
Q

What is the defect called sharkskin?

A

Roughened surface of extrudate due to the velocity profile having zero at the wall so when it exits the die, the wall material has to accelerate and generates tensile stresses that rupture the surface.

29
Q

What is fusion or gelation?

A

PVC particle breakdown, which accompanies melting and compression. Gelation is progressive and can be controlled at processing stage.