Experiment 7 Flashcards
Solubility limit
- The point to which a solute will dissolve
- (s)
- Concentration of the solute (mol/L) or (g/L)
- At which point NO further solid form of the solute will dissolve into the solution
After reaching solubility limit…
Solution is SATURATED
What does not occur in equilibrium expressions
Pure liquids and solids
Solubility products (Ksp)
Equilibrium constants that describe solubility processes
Conc Li2C03 LESS than Ksp
More solid lithium carbonate DISSOLVED into solution
Conc Li2C03 MORE than Ksp
Solid lithium carbonate will precipitate
LeChâtelier’s principle states that an equilibrium will shift to
minimize the amount of an additional reactant or product
Common ion effect
A salt will be less soluble in a solution that already contains one of the ions in the salt
Goal
Determine solubility of Calcium Hydroxide (Ca(OH)2) by measuring the CONCENTRATION of hydroxide in an aqueous saturated calcium hydroxide solution
Indicator used for both?
endpoint?
Methyl orange
Endpoints goes from yellow to a faint pink
Titrated with what
HCl for both
All anions are considered basic UNLESS…
it comes from one of the 6 strong acids
Common ion effect…does what?
DECREASES solubility
What if…ADD NaOH
Solubility of Calcium Hydroxide will DECREASE because common ion effect, rxn shifts to cause precipitation
Add HCl
INCREASE! decreases pH so increase solubility of soluble base/salt