Experiment 5: Types of reactions Flashcards
Combustion
Substances combine with oxygen and produce CO2 and water.
CH4+ 2O2 –> CO2 +2H2O
Oxidation
Oxidation state changes, lose electrons.
Sn2+ –> Sn3+ + e^-
Single Displacement
AB + C —> AC + B
Double Displacement
AB + CD —> AC + BD
Combination
A + B –> AB
Gas Evolution
Gas bubbles and effervescence is apparent, often CO2.
Acid-Base
Acid base,
HNO3 + NH3 –> NH4NO3
Reduction
Gain electrons
FE3+ + e^- –> Fe2+
Precipitation
leads to formation of insoluble product.
Na2SO4 + BA(NO3)2 –> Ba(SO4) (s) + 2NaNO3
Na2SO4 + Ba(NO3)2 –> ____
Precipitation;
Ba(SO4) (s) + 2NaNO3
Sn^2+ –> Sn^3+ + e^-
Oxidation
Fe^3 + e^- –>Fe^2+
Reduction
A+B–> AB
Combination
CH4 + 2O2 –> CO2 + 2H2O
Combustion
AB + CD –> AC+ BD
double displacement
HNO3+NH3 –> _____
Acid-Base
AB + C –> AC + B
Single displacement
CaCO3 –> CaO + CO2
Gas evolution
Visual reaction cues? (3)
Precipitation, color change, gas evolution
Non-visual reaction cues? (3)
pH, temperature, conductivity
Conductivity is…
1/R, 1/Ohms, Mho
Ions carry ____.
Electricity
High ion concentration = ______ conductivity
High
Smaller ions = ________ conductivity.
Higher (if both have same charge)
Higher charge = ______ higher conductivity.
higher (usually)
+2 is twice as conductive as +1. True/false?
False
Higher charge results in….
Solvation, surrounding of charge by water ions whose neg O is attracted to cations and H is attracted to Anions. This is why +2 =/ (+1)*2
Endothermic reactions ______ heat.
Absorb
Exothermic reactions ______ heat
release
HCL +H2O --> H3O^+ +Cl^- H3O^+ + Cl^- + NaOH --> Na + Cl + H2O. Type? Conductivity? Temperature?
Type: Dissolution, acid-base
Conductivity: 1) Linear rise with HCL, 2)same linear fall with NaOH, 3)equivalence point at bottom of v right here(mole HCL = mole NaOH), 4) Adding excess NaOH rises
Temp: Not substantial
H2O+NH3–>NH4+OH
NH4+OH+Cu(NO3)2 –> Cu(OH)2 (s) + NH4+NO3
Dissolution, acid-base, precipitate.
Conductivity: Rises with NH3, rounds off and decreases with Cu(NO3)2.
Temp: Not substantial.
H2CO3 –> H2O + CO2 (g)
Gas evolution
Conductivity: Rises, rounds off, falls slightly
Temp: Not substantial
Na+Cl+H2O+KNO3–> Na+Cl+H2O+K+NO3
Type: simple dissolution (no reaction)
Conductivity: Add Nacl=..25x, add KNO3=2x
(Exception here that larger(K +NO3) ions are better conductors than Na and Cl
Temp: Not substantial
NA2SO4+H2O–>2NA + SO4 + H2O
NA2SO4+Ba(NO3)2—> 2NA + 2NO3 + BaSO4(s)
Simple dissolution, precipitation
Cond: Add Na2SO4-y=x, Add Ba(NO3)2=-.5x
Temp: Not substantial
2FeCL3 + 3Sn —> 2Fe+ 3SnCl2
Type: (+3-1)+0–>0+(+2-1)
Reduction in oxidation number=redox. Sn oxidized, Fe reduced. Natural atoms oxidation number =0
Cond: Don’t care
Temp: Don’t care
Mg(s) +HCL–> MgCl2 + H2 (g)
Type: redox, acid-base, gas evolution.
conductivity: .5x, -.25x
Temp: Linear rise, not from 0.