Exp. 6 - Ammonium Sulfide group Flashcards

1
Q

Al 3+ and excess NH4OH

A

insoluble

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2
Q

Al(OH )3

A

white gelatinous ppt

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3
Q

Al and excess NaOH

A

colorless solution

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4
Q

Al and Na2O2

= Na3AlO

A

Colorless solution

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5
Q

Al4[Fe(CN)6]3

A

white ppt

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6
Q

Cr(OH )3

A

grayish green

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7
Q

Cr in excess ammonium hydroxide

A

insoluble

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8
Q

NaCr02; Cr 3+ in excess NaOH

A

green solution

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9
Q

Na2CrO4

A

yellow solution

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10
Q

Cr4[Fe(CN)6]3

A

grayish green ppt

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11
Q

Zn(OH)2

A

white ppt

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12
Q

Zn ans excess NH4OH

A

Zn(NH3)4 2+

colorless solution

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13
Q

ZnS

A

white ppt

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14
Q

Na2ZnO2

A

colorless solution

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15
Q

Zn in Na2O2

A

no ppt

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16
Q

Zn2Fe(CN)6

A

white ppt

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17
Q

Zn3[Fe(CN)6]2

A

yellowish white ppt

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18
Q

Fe(OH)2

A

white-green-brown ppt.

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19
Q

Fe 2+ in NH4OH

A

Fe(OH)2

insoluble

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20
Q

FeS

A

black ppt

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21
Q

fe 2+ in dilute HCL ; HNO3

A

soluble

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22
Q

Fe 2+ in NaOH

A

Fe(OH)2

white-green-reddish brown ppt

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23
Q

Fe 2+ in excess NaOH

A

insoluble

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24
Q

Fe(OH)3 from Na2O2

A

reddsih brown ppt

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25
Q

F2Fe(CN)6

A

white to blue ppt

26
Q

Fe3[Fe(CN)6]2

A

turnbull’s blue ppt

27
Q

K3Co(NO2)6

A

yellow crystalline ppt

28
Q

Fe(OH)3

A

reddish brown ppt

29
Q

Fe2S3

A

black ppt

30
Q

Fe 3+ and Na2O2

A

not affected

31
Q

Fe4[Fe(CN)6]3

A

prussian blue ppt

32
Q

Fe 3+ in H2C2O4

A

soluble

33
Q

Fe(CN)3

A

brown solution

34
Q

Fe(SCN) 2+

A

blood red solution

35
Q

Fe 3+ in acetate and KNO2

A

no ppt.

36
Q

Co(OH)NO3

A

blue basic salt

37
Q

Co(NH3)4 2+

A

dirty yellow solution (turns red)

38
Q

CoS

A

black ppt

39
Q

Co(OH)3 to Co(OH)2

A

blue to pink ppt

40
Q

Co(OH)3 oxidized

A

black ppt

41
Q

Co2Fe(CN)6

A

green ppt

42
Q

Co3Fe(CN)6

A

reddish brown ppt

43
Q

Co(SCN)4 2-

A

deep blue solution

44
Q

Ni(OH)NO3

A

green basic salt

45
Q

Ni(NH3)4

A

blue solution

46
Q

NiS

A

black ppt

47
Q

Ni(OH)2

A

green apple ppt

48
Q

Ni2Fe(CN)6

A

greenish white ppt

49
Q

Mn(OH)2 to MnO •H2O

A

white to light brown ppt

50
Q

MnS

A

flesh to brown ppt

51
Q

Mn(OH)2 to Mno • H2O

A

white ppt to light brown ppt

52
Q

MnO2 • H2O from Na2O2

A

dark brown ppt

53
Q

Mn2Fe(CN)6

A

pinkish white ppt

54
Q

Cr3[Fe(CN)6]2

A

light brown ppt

55
Q

not affected by Na2O2

A

Fe 3+ , Ni 2+

56
Q

Soluble in Na2O2

A

Al 3+, Cr 3+ , Zn 2+

57
Q

Zn in excess NH4OH

A

soluble

colorless solution

58
Q

Co in excess NH4OH

A

soluble

dirty yellow solution

59
Q

Ni in excess NH4OH

A

soluble

blue solution

60
Q

No ppt or soluble in NH4Cl & NH4OH

A

Zn 2+ ,Fe 2+ , Co 2+

,Ni 2+ , Mn 2+

61
Q

Fe 2+ in NH4SCN

A

no reaction

62
Q

Al 3+ & NH4OH = Al(OH)3

A

white gelatinous ppt.