Exams Flashcards

1
Q

What is the deal with recycling

A

The recycling of materials includes breaking down waste material to more useful products. The recycling of materials is becoming more increasingly important as the metal ores are finite and the non-renewable recourses must be preserved for future generation. The recycling of lead and aluminium is roughly 50% from scrap.

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2
Q

What are the benefits of recycling material

A

The material preserves finite recourses. Metal is expensive to creates large amounts of material, damages environment. Metal reduces emissions of soot, carbon monoxide, nitrogen oxide, and nitrogen oxides in metal production. Lowers greenhouse emissions reduces energy used associated with petroleum. Recycling used from solvent mostly from non-renewable energy. Waste materials are produced in production and can harm environment. Reduces landfill as metal in landfill is not reused.

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3
Q

What are the two types of recycling polymers methods.

A

Two methods of recycling polymers involve feedstock recycling and mechanical recycling. Mechanical recycling involves the physical break down of molecules, through melting, granulation and shredding. Whereas, feedstock recycling involves the creation of monomers in polymerisation of fuels. Conserves the petroleum that is finite. Conserves the use of less energy synthesising material and in landfill reduction. Moreover, plastic polymers are 100% useable and reused until structural integrity fails. The reduction is harder to recycle, they do not melt after prolonged heating they are shredded into smaller pieces into filler materials.

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4
Q

Disadvantages of recycling

A

Disadvantages involves collection, separation and repurposing of material.

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5
Q

Advantage of composite material

A

The materials are stronger and can be used to improved that is not in present in individual components. They can be designed for a particular use as matrix and reinforcement. Most composite can be moulded into complex shapes.

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6
Q

Describe the recycling of composites.

A

The reclycing is difficult as cross links, and cannot be reshaped. Involves grinding material to small pieces which can be used as filler or melt the or combust matrix and retain fibres. Prylosis is used to recover expensive carbon fibres. Carbon fibres retain more than 90% of original mechanical matrix.

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7
Q

Explain the importance of renewable energy

A

There is over 80% of the global energy which is derived from fossil fuels not even 10% is derived from renewable energy sources. Renewable energy sources are important because they do not exceed any emissions, namely, wind power and solar power. Biofuel emits significantly less than fossil fuels. The only catch fossil fuels are required for bio crops, biofuels and wind turbines. Carbon dioxide methane and nitrous oxides are all produced in extraction of fossil fuels.

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8
Q

Advantages of fossil fuels

A

Advantages
Currently fossil fuels are abundant and accessible
Fossil fuels have high energy density and large quantities of energy are released in the combustion of these materials
Extraction of fossil fuels is relatively easy and inexpensive
Fossil fuels are feedstock for thousands of commercially available products that are used in everyday living

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9
Q

Disadvantages of fossil fuels

A
Carbon dioxide (greenhouse gas) is released in the combustion of fossil fuels
Sulphur oxides (SOx) and nitrogen oxides (NOx) are released when coal and oil undergo combustion. These gases contribute to acid rain and smog.
Particular matter (PM) is released into the atmosphere in the extraction of coal and these materials are major contributors to global air pollution
Fossil fuels are non-renewable and cannot be replaced once they are consumed.
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10
Q

Fossil fuel feedstocks

A

Petroleum comprises most of the feedstock for fossil fuels 20% of all petroleum extraction is used for feed stock annually with over 5000 consumer goods. Including, alkenes as manufacture of polymers larger alkenes as lubricants, asphalt for road production and aromatic compounds as manufacture of polymers/solvents. Natural gas is also used as a feedstock for nitrogen fertilisers, hydrogen gas and methanol.

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11
Q

Advantages of wind power

A

Wind is an inexhaustible recourse of renewable energy with zero emissions of greenhouse gases during operation.
Currently wind power is one of the most cost-effective renewable energy technologies
Wind turbines do not require the use of water whereas steam turbines (used in power stations where fossil fuels are combusted) require large amounts of water.

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12
Q

Disadvantages of wind power

A

Wind turbines cannot provide a sustainable source of energy for domestic use in the absence of wind (can be unreliable.)
The best locations for wind turbines are often great distances from the users of electricity meaning that the power transmitted (inefficiently) over long distances
Wind turbines create noise pollution, have been describes as unsightly, and have been implicated in the death of birds and bats.

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13
Q

Whats the deal with wind power

A

Kinetic energy is converted to electrical energy by wind turbines. The large blades capture wind energy and turn it to electrical energy. The wind turbines are grouped together to form wind farms that are collectively used to form generate electricity for homes and businesses. Currently there are 16 wind farms in Australia.

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14
Q

Biofuel generations

A

Generation Description Examples

First Produced directly from food crops Bioethanol, biodiesel

Second Product from non-food crops such as wood, food crop waste, and organic waste Biogas (50-80% methane)

Third Produced in chemical processes carried out by genetically engineered algae. Biodiesel, butanol, gasoline, methane, and bioethanol

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15
Q

Advantages of biofuel

A

Advantages
Combustion of biofuels produces fewer greenhouse gases.
Biofuels crops remove carbon dioxide from the atmosphere during photosynthesis
Waste material can be used to produce biofuels which reduce emissions of greenhouse gases from waste and landfill.
Biofuel crops can be grown every year creating a renewable fuel source which has greater security in the future.

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16
Q

Disadvantages of biofuel

A

Disadvantages
Greenhouse gases are emitted in the fertilising, harvesting, refining and transporting of biofuel crops.
Biofuel crops occupy land that could be used for growing crops. This could lead to higher food prices in future.
The growth of biofuel crops requires a large amount of water which will contribute to water shortages in future.
The demand for palm oil has caused deforestation in some areas of the world.

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17
Q

Advantages of solar cells

A

Solar cells require very little maintenance once installed properly.
Solar cells can be engineered to any size to suit a variety of applications from charging a phone to powering a building.
The sun provides an inexhaustible amount of renewable energy that can be converted into electrical energy in all parts of the planet.
Conversion of electromagnetic radiation (light) into electric current does not involve any greenhouse gas emissions.

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18
Q

Disadvantages of solar cells

A

Power output of solar cells decrease in the absence of sunlight (at night) and in periods of high cloud cover
Solar cells in solar panels are fixed in a position that is not always facing the sun.
Currently solar cells have low energy efficiency (~20%) but advances in nanoscience and technology are improving the efficiency of solar cells every year.
80% of solar cells are made from high purity silicon which is an expensive raw material which greatly reduces the cost-effectiveness of solar cells.

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19
Q

How are biodiesel made

A

Biodiesel are esters compared with fatty acids with low molar mass alcohols such as ethanol or methanol. The ester is made in a process called transesterification involving the fatty acid and the low molar mass alcohol to form the biodiesel. It can be used in its pure form or combined with another diesel to create a combination which contributes to less fuel used annually. Moreover, the biodiesel emits less carbon dioxide than regular diesel. Oil seed crops are main sources of biofuel production

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20
Q

What is the deal with calorimetry

A

Calorimetry is a technique to measure the amount of heat formed in a reaction. The larger the carbon change in a homologous series is the more energy is released per mole in a complete reaction of oxygen. Calorimetry is used to measure the energy released per mole of simple hydrocarbons and alcohols. The molar enthalpy. The bond formation of water and carbon dioxide is exothermic.

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21
Q

What is energy density

A

Energy density is the fuel contained per unit of volume. Mixtures do not usually have a molar enthalpy as they have different molecules within them. The energy density is expressed per unit of volume. Kilojoules per litre. Specific heat multiplied by fuel density.

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22
Q

What is the deal with Steam turbines

A

The fuel is combusted, and the combusted fuel is converted to a large water volume that uses the kinetic energy for electrical energy. The energy combusted releases carbon dioxide. It involves a boiler, steam turbine and electrical generator.

23
Q

How electricity is obtained from photovoltaic cells

A

The electrons are travelled to the semiconductor of silicon which then transfers the electrons of the excited state to form an electric current which can be used for energy. The reaction does not use any greenhouse gases. The galvanic cells use the silmountous redox reaction of the cathode and anode reactions. The flow of electrons provides energy. Electrochemical cells.

24
Q

Advantages of fuel cells

A

Fewer greenhouse emissions. Hydrogen fuel cells do not emit carbon dioxide in the atmosphere.

Fewer pollutants emitted. Fuel cells do not emit particular matter (PM). Nitrogen oxides (NOx) or sulphur oxides (SOx)

High energy efficiency The efficiency of a fuel cell in converting chemical to electrical energy is 40-60%

Greater power output. Fuels used in fuel cells have greater energy density than fuels used in batteries to generate electricity.

25
Q

Disadvantages of fuel cells

A

Expensive raw materials. High purity fuels and precious metal catalysts used in fuel cells are expensive.

Hydrogen is derived from fossil fuels Most hydrogen fuel is derived from the reaction of natural gas (fossil fuel) and methane

Hazards associated with some raw materials Hydrogen fuel is potentially explosive, and some electrolytes used in fuel cells are highly corrosive.

Contamination of electrolytes and electrodes Electrolytes and electrodes can be contaminated during operation by impurities in the fuel and oxidant which reduces operating efficiency.

26
Q

The application of fuel cells include.

A

primary source in residential, commercial and industrial buildings.
• Fuel cells have been used as a power source in portable electronic devices and some have applications as electrochemical sensors in breathalysers and carbon monoxide detectors.
• Fuel cells have replaced the internal combustion engines in some motor vehicles.
• Fuel cell electric vehicles (FCEVs) including cars, buses, motorcycles, and boats generate energy for motion with fewer greenhouse gas emissions.

27
Q

What is the deal with water

A

Water is an essential recourse for extracted from environment to support households, industry, drainage, sewage and mining.

28
Q

Describe how water treatment changes on the intended use and source

A

Water is treated depending on its intended purpose. The method to disinfection and information for safe and healthy drinking water. For hard saline water it undergoes desalination. For fresh soft water it is conventional.

29
Q

Outline the brief steps of conventional water treatment

A

Conventional water treatment involves coagulation. The silicate particle charges are neutralised so they can form larger particles and settle or be filtered. Flocculation involves the agitation so larger particles can form large masses which settle or filtered from a solution. Sedimentation involves allowing the sediments to settle, it is allowed for numerous hours for it to occur. The solution can then be transferred to filtration tank, sediments are treated before disposal. Filtration water transfers through several filters to remove impurities. Disinfection. Water is treated using chemical agents or uv radiation. Storage, water is transferred to storage tanks to allow for suitable storage so it can be used for high use during rural or domestic period consumption.

Water filtration is depending on its intended use and origin. Suspended matter is removed from fluctuation, sedimentation then filtration. The surface of fine silicate and aluminium silicate in clays is negatively charged and can made to larger particles with addition positive highly charged cat ions such as aluminon ion and polymers

30
Q

Outline the steps of reverse osmosis

A

Reverse osmosis

Water undergoes a process of desalination through going water desalination through osmosis. The process of osmosis involves the travel of water from a low solute level to a high solute concentration. The semi-permeable allows diffusion of certain molecules, whilst preventing entrance of other molecules such as dissolved ions. The process of desalination involves forcing water from a region of high solute concentration to a low solute concentration through the semi-permeable membrane. The process removes dissolved salts, heavy metal ions, microorganisms, organic compounds. Fresh water product has a 99 to 100% purity. Impurities are collected and removed when forced through semi-permeable membrane

31
Q

Society benefits of desalination

A

The desalination plants there are over 18 000, they provide water in water scarce areas. They are providing potable water for over 300 million people. The water plant has benefits but also flaws including. Including.

32
Q

Disadvantages of reverse osmosis

A

Expenses:
The development, construction operation, maintenance of desalination plants.

Energy use:
Desalination plants use large amounts of electrical energy (for force in reverse osmosis) and thermal energy (thermal distillation) which is currently derived from non-renewable energy. Energy consumption increases greenhouse gas emissions contributes to global warming

Membrane fouling and scaling
The membrane pores become clogged with impurities including salts, silica and microorganisms and must be cleaned with hazardous chemicals or replaced.

Chemicals used in pre and post treatment:
The input (saline) and output (fresh) water is treated using a range of chemicals to remove organic compounds, minerals, and microorganisms before and after desalination. The chemicals used in treatment are hazardous

Discharge of brine:
The concentrated solution (brine) from desalination is a waste material that is disposed of by discharging the material into the ocean. This discharge may affect marine plants and animals.

Toxic chemicals in the waste material.
The waste material is discharged may contain trace amounts of toxic material that may be harmful to marine life in the ecosystem where the waste is discharged.

Death of marine animals and important microorganisms.
Fish and other marine organisms are killed during the inflow of saline water from the ocean. Smaller organisms including plankton and fish eggs are killed during treatment of saline water inside the plant.

33
Q

The difference between primary, secondary and tertiary alcohols

A

Primary - 1 - R group, secondary - 2 - R groups, tertiary - 3 - R groups attached.

34
Q

Greenhouse gas natural sources

A

CO2: Ocean-atmosphere exchange, Plant and animal respiration. Respiration of soil microbes and aerobic decay of organic matter in soils. Volcanic eruptions.

Methane: Methane-producing microbes in wetlands. Methane producing microbes in termites. Methane producing microbes in oceans.

Nitrous oxide-producing microbes in soil
Nitrous oxide-producing microbes in oceans
Chemical reactions in the atmosphere.

35
Q

Anthropogenic greenhouse gases and their sources.

A

Carbon dioxide: Combustion of fossil fuels for electrical energy production and transportation. Cement production and industry. Deforestation.

Methane: Fossil fuel production, distribution and use. Methane-producing microbes in livestock. Landfill and waste.

Nitrous oxide. Agriculture. Combustion of fossil fuels. Nitrous oxide-producing microbes in sewage.

36
Q

What is a primary and secondary pollutant

A

Emitted directly into the troposphere from a source such as a vehicle exhaust or an industrial plant. (NOx)

Secondary: Products of chemical reactions involving primary pollutants in the troposphere. Ozone (O3)

37
Q

Why is pipette and burette rinsed with distilled water than analyte solution

A

To remove reagents from previous use

To remove distilled water from the pipette.

38
Q

What does a pH indicator do with regards to end-point?

A

A pH indicator is used to approximate the equivalence point of the titration involving the neutralisation of an acid using a base. The point at which the indicator shows a permanent colour change is called the end-point.

39
Q

What does a colour change do with regards to end-point?

A

Colour change a colour change (end-point) occurs after the equivalence point has been reached without the addition of an indicator in some reactions. Redox reactions often involve a colour change as the oxidation number of the titrant and analyte change at the equivalence point, often producing different coloured products.

40
Q

Harmful effects of NOx

A

Nitrogen oxide pollution is associated with damage to the health of animals and plants. Breathing high concentrations of nitrogen dioxide causes inflammation of the lungs leading to reduced immunity and subsequently lung infections such as cold, influenza, and bronchitis.

Also acidic rain hydronium increase depletes soil nutrient in ion exchange

41
Q

Harmful effects of ozone

A

Irritates the nose, airway and lungs upon inhalation causing respiratory problems. Also damages plants leading to reduced yield. Ozone is a strong oxidising agent which reacts with and damages many essential molecules in the leaves of plants causing pigmentation (chloris) and necrosis (premature death of cells).

42
Q

What are catalytic convertors made from

A

Platinum, Rhodium or Palladium

43
Q

With regards to the graduation line and meniscus how is the volumes read

A

The plat of the meniscus on the graduation line.

44
Q

Examples of calcifying organisms

A

Shell fish and corals

45
Q

What are by-products?

A

Have a commercial value can be sold.

Can be reused/ recycled within the chemical processes in which they are produced.

Can be used to generate energy for the chemical plant.

Can be used in another chemical process.

46
Q

What are Waste material?

A

Have no commercial value.

Cannot be reused/ recycle within the chemical process in which they are produced.

Cannot be used in any other chemical process.

Cannot be used to produce energy for a chemical process.

47
Q

What do operating costs consist of?

A

Cost of raw material, Staff and salaries, maintenance of equipment, generating high pressures, generating high temperatures transport of materials.

48
Q

How to lower energy consumption

A

Recycle heat - Heat produced in exothermic reactions is transferred to a material (such as water) that stores the energy and transports it to another part of the manufacturing plant where it can be used to produce electricity.

Operating continuously - Operating reactors constantly saves energy and costs associated with heating the equipment to the appropriate temperature each day.

49
Q

Advantages of non-renewable materials

A

Currently, fossil fuels are abundant and accessible.

Manufacturing facilitates, processing plants and recycling facilities for petroleum-based plastics are well established.

50
Q

Disadvantages of non-renewable materials

A

Plastics are made from synthetic polymers can be recycled but most are disposed into landfill and most waste is non-biodegradbale.

51
Q

Advantages of renewable materials.

A

Plastics can be manufactured from renewable resources that are biodegradable.

Raw materials (plants, wood, corn, potatoes, and wheat) are relatively inexpensive.

Can be processed by the same machinery as petroleum based plastics.

Decomposition of hydrolysis does not produce toxic by-products

52
Q

Disadvantages of renewable materials

A

Growing crops for polymer feedstock could reduce the available land for food crops.

Sale price of raw materials increases resulting in an increase in global food price.

Hydrolysis occurs under the right conditions (temperature and humidity).

Sale price is currently higher and infrastructure for recycling is not as well established.

53
Q

Disadvantages of Biodegradable polymers.

A

A limited number of synthetic polymers are biodegradable.

Greenhouse gases (carbon dioxide, water and methane.) are released in the decomposition of biodegradable polymers.

Oxygen and water must be present (for microorganisms) for decomposition to occur. (Decomposition won’t occur if the material is buried in landfill).