exam semester 1 Flashcards

1
Q

what are spontaneous chemical reactions

A

reactions that occur at room temperature without the impact of energy such as heat or electricity
-occur at room temp
some quick, some slow

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2
Q

whar are energy transformations

A

evident in changes in the temperature of surrondings and/or the emission of light

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3
Q

chemical reactions

A

involce the creation of new substances and associated energy transformations

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4
Q

what are some chemical equations

A

acid + sulphides —-> salt + hydrogen sulfide
acid + sulphite —–> salt + water + sulfur dioxide
water + active metal —-> salt + hydrogen
base + ammonium salt ——> salt + water + ammonia
base + non-metal oxide —–> salt + water

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5
Q

what is a precpitation reaction

A

reaction when solid formed

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6
Q

what are net ionic equations

A

Spectator ions are those ions that appear exactly the same on each side of the ionic equation.
dont effect the reaction

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7
Q

what is moler mass

A
mass in grams of 1 mole of sustance
take the atomic mass of the element of the periodic table and multiply it by the amount of times it occure in the equation
top m
left n
right mr
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8
Q

what is a mole

A

a counting unit

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9
Q

where did the mole come from

A

the number of atoms in exactly 12g of carbon-12 isotope

the number of particles in one mole, 6.022 x 10^23, is known as auogadros constant or number

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10
Q

what is the atomic mass

A

mass in grams of one mole of atoms in an element

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11
Q

what is number of particles

A

refers to many things - atoms, ionic unit, or molecules - dependant on the substance
formula: n=#p/na
n=moles
na = auogadros constant

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12
Q

what is stoichiometry

A

measures these quantitative relationships, and is used to determine the amount of products/reactants that are produced/needed in a given reaction.

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13
Q

what must happen for a chemical reaction to occur

A

the bonds between the atoms in the reactants must be broken and new bonds between the atoms in the product must be formed

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14
Q

what happens in an exothermic reaction

A

releases heat energy to the surrondings
the temperature of the surrondings increases
the energy released from forming new bonds is greater than the energy needed to break old bonds
(triangle) H is negative

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15
Q

what happens in an endothermic reaction

A

takes in heat from surrondings
the temperature of the surrondings decreases
the energy needed to break old bonds is greater than the energy released from forming new bonds
(triangle) H s positive

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16
Q

what requirements must be met before a chemical reaction will occur

A

the reacting particles must collide
they must collide with a specifc minimum amount of energy, called the activation energy
the particles must collide with a favourable orientation

17
Q

what is a succesful collision

A

has suffiecient energy and an appropiate orientation to allow old bonds to be broken and new bonds to be formed. this leads to the formation of products

18
Q

what is an unsuccesful collision

A

the energy and or orientation are not satisfactory. this doesnt lead to the formation of products

19
Q

what is the activated complex/transition state

A

a temporary, highly unstable structure that has more energy then either the reactants or products. it is the stage of maxium potential energy

20
Q

what is the activation energy

A

the miniumum amount of energy required for a reaction to occur

21
Q

what is enthalpy

A

the total energy possesed by a chemical substance

22
Q

what is an energy profile diagram

A

shows the enthalpy of the reactants, activated complex and products

23
Q

the number of successful collisons depends on

A

total number of collisions

percentage of collisions that are succesful

24
Q

what happens if the reactants only require a small amount of energy

A

the activation energy will be low

25
Q

how can you speed up the rate of reaction

A

increasing temperature, increasing surface area, increasing pressure, increasing concentration, adding a catalyst

26
Q

what happens when you increase the concentration in a reaction

A

the number of particles per unit increases
this increases the number of collisons, therefore increasing the number of succesful collisions and therefore increasing the rate of reaction

27
Q

what happens when you increase the pressure in a reaction

A

by increasing the pressure, the particles per unit volume increases
this increases the number of collisons, therefore increasing the number of succesful collisions and therefore increasing the rate of reaction

28
Q

what happens when you increase the surface area in a reaction

A

more of the solid is exposed and therefore more collsions are possible.
this increases the number of collisons, therefore increasing the number of succesful collisions and therefore increasing the rate of reaction

29
Q

what happens when you increase the temperature in the rate of reaction

A

the average kinetic energy of the particles is increased. therefore a greater proportion of particles have the minimum amount of energy to react and therefore increasing the rate of reaction

30
Q

what happens when you add a catlayst to a reaction

A

isnt used up in the reaction but is able to increase the rate of chemical reaction
it provides an alternate pathway with lower activation energy meaning a greater proportion of the particles have the required energy to react