Exam questions Flashcards
What is a hybrid composite?
Matrix + 2 reinforcements
What length of fiber is necessary for fiber pull out?
Shorter than lc
There is a growing interest in thermoplastic matrix composites. Give at least three reasons for this.
Possibility to re-process by melting + reshaping
short cycle production long shelf-life increasing service temperature being enabled by several thermoplastics dimensional stability resistance to moisture good to excellent dielectric properties abrasion resistance.
There are certain disadvantages in using thermoplastic matrices Give at least two such hindering reasons.
- expensive tools and processing equipment due to high pressures and temperatures involved
- high viscosity during manufacturing
- less stiff and stiffness decrease with T
What is Ps in Weibull?
Probability of survival
Is the value of m (Weibull shape parameter) for carbon fibres typically higher or lower than that for aramid fibres?
CF has a large variability in strength which means that the Weibull parameter is low.
Unsaturated polyester (UP) is common matrix for composite materials. During the polymerization four compounds are active. Which of these materials is important for the cross-linking?
Styrene
Why are fibres so interesting as reinforcing elements in composites? Give at least two reasons.
- They are flexible
- materials are typically more strong in fiber form
- they have low probability of defects which gives a positive influence on mechanical properties.
With ceramic matrix composites (CMC)/metallic matrix composites (MMC) in mind, what are the three forms of interfaces between two phases in a composite?
• Direct bonding with no intermediate layer
• Intermediate layer in form of a solid solution of the matrix and dispersed phases
constituents
• Intermediate layer in form of a third bonding phase (adhesive)
What’s the difference between trans-granular and inter-granular cracking? Explain how the fracture surface looks like
Inter-granular fracture is most likely when the grain boundaries are weak and the individual grain boundaries/facets are visible on the fracture surface. In trans-granular (cleavage) fracture, the crack passes through the grains. The fracture surface may be smooth or shows small steps.
Explain in detail how fibres can reinforce a brittle (ceramic) material
When the crack grows in the matrix, the reinforcement (fibers) remains intact and bridge the crack. This promotes multiple cracking – each contributing its own energy and thereby raising the overall dissipation. When the fibers do break, the breaks are statistically distributed, leaving ligaments of fibers buried in the matrix. The pullout, as the crack opens up, dissipates more energy by friction.
Which parameter in the Nielsen equation does not appear in the Halpin-Tsai equation?
Parameter Ψ does not appear (or the maximum packing fraction Φmax).
Describe what is meant by the critical fibre length. Give at least two quantities that determine the critical fibre length.
General description of the critical fibre length including that the fibre can be pulled out of
the matrix when the fibre length is shorter than the critical fibre length
Interfacial shear strength, fibre strength, fibre diameter
Roughly, what is that critical length typically for practical polymer matrix composites?
Millimeter range
What is a symmetric laminate
A symmetric lamina with matching plies on each side of the midplane
What is a cross-ply laminate?
A cross-ply laminate consists of plies oriented either in 0° or 90°.
In case of thermosets, what are the three elementary tasks that must be achieved during
processing/manufacturing of a PMC product (except curing)?
There are three elementary tasks carried out during processing of a PMC: fibres must be
wetted out, forming (shaping) must take place, and depending on the manufacturing route, drainage of resin must take place.
In which way does shrinkage influence moulding (processing) of PMCs?
High resin shrinkage can contribute to moulding defects, such as internal stress, warpage and sink marks, however, can be desirable for easy mould release.
From composite manufacturing viewpoint, injection moulding (IMCs) is attractive, and thus widely applied. However there are some disadvantageous features. Mention at least 1 important advantage and 1 important disadvantage.
+ fast cycle timme
- Fibers get crushed during process
- Expensive moulds is also a drawback.
Describe briefly in words vacuum infusion moulding (also called vacuum injection moulding). Mention at least two common applications.
A stack of dry fibres is placed between a rigid mould half and a flexible and airtight bag. The bag is sealed to the mould, except at certain positions being open for resin inlets and outlets. Liquid resin is then forced into the stack by reduction of the pressure at the outlets, while keeping the pressure atmospheric at the resin inlets.
Common applications include: boats, yacht hulls, offshore structures, vehicle body panels, wind turbine rotor blades and others.
Give at least two ways or requirements for obtaining a good wetting of fibres and particles by a liquid (or resin).
- Low contact angle (clean surface)
- low viscosity of the liquid
- no entrapment of air (smooth surface).
Name at least three types of interfacial bond that may form between the matrix and fibre. Which one gives a particularly high contribution to interfacial strength?
- Molecular entanglement
- electrostatic attraction
- presence of anionic groups
- chemical bonding
- mechanical keying.
Chemical bonding highly contributes to interfacial strength.
Why should you use low frequency and not high one when measuring the S/Nf plot?
Low frequency should be used (say below 10 Hz) to avoid heat build-up.
List three mechanisms increasing PMCs toughness, and select one and explain it.
- Crack deflection, delamination
- use of more tough matrix
- frictional sliding during fibre pull-out.
- debonding
Sandwich structures consist in most cases of a core and two facings (skins). There are three primary types of core structures.
Honeycomb , foam (cell structure) and balsa
Explain/sketch what is exfoliation and intercalation for layered-silicates (montmorillonite),
to obtain nanoplatelets.
In order to obtain clay nanocomposite material, tactoids have to be intercalated and finally delaminated in the surrounding matrix. The mechanism of exfoliation during the melt processing consists of a combination of shear
and diffusion of polymer chains in-between the layered silica. During shearing the tactoids experience dis-
placements in the shearing direction, thus facilitating the diffusion process. Furthermore, along with the penetration of polymer chains within the tactoids,
the layers become prone to breakage and exfoliation due to the shear forces.
A common method to enhance exfoliation is through the cation exchange process.
Mention at least 2 critical issues in preparing carbon nanotube (CNT) composites.
- dispersion
- alignment
- manufacturing
- cost effectiveness.
- de-agglomeration
- functionalization (CNTs are rather inert from the start).
- toxic aspects.
Give two examples of thermosets and thermoplastics.
Epoxy, UP (unsaturated polyester)
PP (Polypropylen), PVC (Polyvinylcloride), PA (Polyamide)