Exam Flashcards
Describe features of good soil structure
- Stable (resistant to compression maintaining below attributes)
- Many small aggregates (good aeration, drainage, large SA)
What makes a clay soil “reactive”
Clay has an electrical charge, mostly negative, which means that it can attract cations such as K+ and NH4+.
It also has a very small size so a huge surface area to volume ratio
Why do coarse textured soils have good drainage but smaller total pore volumes
Coarse-textured soils have smaller total pore volume as coarse-textured soils cannot pack as close together so form more macropores. Macropres are important for drainage as the capillary action is too weak to hold water within them.
What is permanent wilting point
The point where the soil water content decreases so low that the plant dies.
What is plastic limit
Plastic limit is the moisture content at which soil begins to behave as a plastic material.
What is mottling
Mottling is when iron and aluminium oxides become insoluble again, precipitating in the soil profile.
Describe a method for determining soil structure within the field
You need to see the number and stability of peds. Working aggregates within fingers to determine the resistance to compression. The distinctiveness of aggregates and their stability under stress indicates the degree of development.
What is wilting point
Wilting point is the water content in the soil when the plants have extracted all the water that they are capable of taking from the soil.
What is soil saturation
A soil is said to be saturated when all the pores are full of water (i.e all the air has been displaced).
What is field capacity
Field capacity is the water content of the soil after all the excess water has drained away
What is stress point
The drier a soil is relative to field capacity, the greater the force that plants must exert to extract water. If a soil dries to a point where the roots cannot extract water, at the rate demanded by the leaves then the stomata will close and the plant will be “under stress”.
What is infiltration rate
The speed that water enters the profile
What is hydraulic conductivity
The speed that water moves through the soil
What is drainage
The speed that water exits the soil
What are some factors that affect available water storage?
- Pore size
- Texture
- Structure
- Organic matter content
- Depth to which plant roots can penetrate
What is CEC?
CEC is the amount of negative charge which is accessible for the retention of positively charged cations.
What is PZNZ?
The pH are at which the amounts of negative and positive charges on the soil particle surface are the same resulting in zero net charge.
What happens to the soil when the pH is above PZNC?
When the pH is above PZNC, the soil is net negatively charged, resulting in more cation retention.
What happens to the soil when the pH is below PZNC?
When the pH is below PZNC, the soil is postively charges, resulting in anion retention. This is impractical in most nz soils
What does isomorphous substitution create?
It creates a permanent charge that is not affected by the pH of the soil.
What does dissociation of H+/OH- create?
It creates a variable charge that is pH dependent.
How does isomorphous substitution create negative charge?
Permanent negative charges are created by substitution of higher valency cations with lower valency cations.
What are some examples of normal siliceous rocks in NZ?
- Greywacke
- Argillite
- Schist
- Granite
What soils are classified as azonal soils?
Recent soils from alluvium, recent soils from volcanic ash and skeletal soils in steep land.
The principal effect of biological activity in the soil is what?
The respiration of CO2 by plant roots and microorganisms increasing the acidity of the soil solution by producing carbonic acid.
Name 3 ways topography affects soil formation
- The effect of the slope on soil depth
- Modifying effects of climate
- Influencing soil moisture regimes
Chemical formula of phosphate in soil solution?
H2PO4-
Chemical formula of Sulphate in soil solution?
SO4-2
Chemical formula of Nitrate in soil solution ?
NO3-
Chemical formula of Sodium in soil solution?
Na+
Chemical formula of Magnesium in soil solution?
Mg2+
Chemical formula of Potassium in soil solution?
K+
3 types of ion mechanisms?
Root interception
Mass Flow
Diffusion
What mechanism does phosphorus adopt to reach the plant root?
Diffusion
How does phosphorus behave in soil?
As phosphate isn’t very mobile (is adsorbed by soil), fertiliser placement is critical but the potential for nutrient loss is small. Phosphorus doesn’t move more than 6mm to get to a root. Phosphorus is only lost if the soil itself is lost through erosion. Phosphorus accumulates in the soil.
How does nitrogen behave in soil?
As nutrient mobility increases, fertiliser placement becomes less critical, but the potential for nutrient loss becomes greater. Nitrogen placement relative to the plant isn’t very critical for uptake, but the potential for loss of nitrogen once it is applied to the soil is generally very high, and little available nitrogen will accumulate in the soil.
how do micronutrients behave in soil?
The behaviour of most micronutrients is similar to that of phosphorus. The other nutrients fall somewhere between these two extremes in mobility behaviour (phosphorus and nitrogen)
proportion of nutrient uptake by every mechanism
nitrogen - 99% mass flow phosphorus - 90% diffusion potassium - 78% diffusion calcium - 72% mass flow magnesium - 87% mass flow sulphur - 95% mass flow all consist of some root interception
what is pH buffering?
When a solution resists pH change of soil when acidic or alkaline materials are added.
what happens when lime is added to an acidic soil?
CaCO3 is a basic salt - it dissolves in water to form a strong base (Ca(OH)2) and weak acid (H2CO3), so the net effect is a basic solution.
For every mole of CaCO3 that reacts with water, 2 moles of OH- ions are generated. These two moles of OH- ions neutralise excess H+ in soil solution. H+ then moves into soil solution from the soil surface, buffering the change in pH.
PNZC related to the dissociation of H+/OH- ions?
When the pH is above PZNC, the soil is net negatively charged, resulting in more cation (H+) retention; when the pH < PZNC the soil is net positively charged, resulting in more anion (OH-) retention.
what causes a soil to have a high CEC value?
high CEC is when cations are held by the negatively charged clay and organic matter particles in the soil through electrostatic forces. (negative soil particles attract the positive cations). High CEC is caused by high negative charge.
what is the benefit of high CEC?
high CEC means more plant available cations. It represents the total amount of exchangeable cations that the soil can adsorb. The cations used by plants in the largest amounts are calcium, magnesium, and potassium.
what is flocculation?
the process in which particles disperse in a solution contact and adhere each another, forming clusters, flocks, flakes, or clumps of a larger size.
what is a diffuse layer?
the DL is the specific distance from the clay surface that the concentration of the bulk soil solution is equal, the anionic and cationic charges are balanced in solution.
Below the PZNC?
the surface bears a positive charge and can attract anions
Above the PZNC?
the surface bears a negative charge and can attract cations
increase of K+ from effluent…
K+ over time can displace adsorbed Ca2+ and Mg2+, releasing these cations into soil solution and thereby increasing their risk of leaching. Over time the Diffuse Layer may increase leading to soil deflocculation
Increase in H+ from increases in acidity
H+ over time can displace adsorbed Ca2+ and Mg2+, releasing these cations into soil solution and thereby increasing their risk of leaching. Over time the Diffuse Layer increases leading to soil deflocculation
Why is water at the permanent wilting point unavailable?
It is bonded too tightly inside molecules or in micro-pores whose capillary action is too strong for plants to overcome
Why should you not apply force to a soil when it is wetter than the plastic limit?
It will compact, forming pans, ruining aggregates impeding drainage and aeration
How do wetting and drying cycles create good soil structure?
Wetting breaks up as outside expands from absorbing water, creating a pressure difference that causes it to explode
Drying brings soil particles together in greater alignment, bonding and stablising the peds
How does soil structure develop?
Bigger aggregates may be broken up and stabilized Or substituents (sand,silt,clay) are brought into close proximity to form new aggregates
Difference between soil texture and soil structure?
Soil texture is the proportion of sand, silt, and clay in a soil whereas soil structure is the arrangement of soil particles into aggregates and the stability of these aggregates to stress