Exam 4 Flashcards

Chapter 9 and 10

1
Q

Solute

A

the thing being dissolved

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2
Q

Solvent

A

the thing doing the dissolving

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3
Q

Solution

A

A homogeneous mixture of two or more substances

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4
Q

colloid

A

a very finely divided substance which is scattered throughout another substance

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5
Q

What substances are soluble together?

A

“like dissolves like”; nonpolar and nonpolar; polar and polar; polar and ionic

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6
Q

What is a saturated solution?

A

Solutions that contain the maximum amount of solute at a specific temperature

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7
Q

What are unsaturated solutions?

A

Solutions that contain less than the maximum amount of solute at a specific temperature

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8
Q

What is a super-saturated solution?

A

Solutions that contain more than the maximum amount of solute with a change in temperature

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9
Q

How are supersaturated solutions made?

A

By forming a saturated solution at a high temp then cooling the solution without disturbing. (Disturbing the solution with cause the solute to crystalize out of the solution.)

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10
Q

How is solubility measured?

A

As the amount of solute that can dissolve in a specific amount of solvent at a given temperature and can be affected by temperature

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11
Q

What happens to a solids solubility as temperature increases?

A

The solid will become more soluble

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12
Q

What happens to a gases solubility as temperature increases?

A

The gas will become less soluble

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13
Q

What is Dilution?

A

Adding solvent (usually water) to a concentrated solution to decrease the concentration. volume goes up and concentration goes down

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14
Q

What happens to dissolved ionic compounds?

A

They dissociate into ions (electrolytes) when dissolved in water, which creates electrical conductivity

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15
Q

What are strong electrolytes?

A

Only exist as ions in solution (ionic compounds)

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16
Q

What are weak electrolytes?

A

Exist as ions & molecules in solution (semi-ionic with non-metal cation)

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17
Q

What are non-electrolytes?

A

Exist only as molecules in solution (polar covalent molecules)

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18
Q

What is OSMOSIS?

A

When a semi-permeable membrane separates sides of different concentration, water will flow through the membrane from the side of lower solute concentration to higher solute concentration to try and dilute it.

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19
Q

What does the movement of water create?

A

Hydrostatic pressure

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20
Q

What is osmotic pressure?

A

The pressure required to prevent the net flow of water through a semi-permeable membrane

21
Q

What is an isotonic solution?

A

Equal osmolarity of solute inside and outside cell (happy cell)

22
Q

What is a hypotonic solution?

A

When concentration inside the cell is greater than outside the cell (cell burst = hemolysis)

23
Q

What is a hypertonic solution?

A

When concentration outside the cell is greater than inside the cell (cell shrivel up = crenation)

24
Q

What is dialysis?

A

Movement of solute from higher to lower concentration through dialysis membrane

25
How to dialysis and osmosis differ?
In osmosis ONLY the SOLVENT can cross the membrane. In dialysis, small solute particles can move into the lower solute concentration to equalize concentrations. (In addition to regular osmosis movement)
26
What is an Arrhenius acid? How do you identify such acid?
Produces H+ ions when dissolved in water: To identify look for hydrogen atom at the beginning of its chemical formula, typically bonded to a highly electronegative element like oxygen or a halogen
27
What is an Arrhenius base? How do you identify such base?
Produces OH- ions in water: To identify look for a compound that, when dissolved in water, produces hydroxide ions (OH-) as its primary dissociated ion
28
What is a Bronstad-Lowry acid? How do you identify such acid?
H+ ion donor: To identify observe the reaction and count the hydrogens on each substance before and after reaction
29
What is a Bronstad-Lowry base? How do you identify such base?
H+ ion acceptor: To identify, if the number of hydrogens has increase that substance is the base
30
What are the six strong acids?
HClO4, HNO3, H2SO4, HCl, HBr, HI
31
Why do conjugate/base pairs exist?
This is because when an acid reacts with a base, the acid donate a proton to the base, which accepts it. Whatever the acid changes into, in the reverse reaction, acts as a base, by accepting a proton to reform the original acid.
32
How can acids be classified?
Acids can be classified as monoprotic, diprotic, or triprotic based on H+ available to donate
33
What is water?
Water AMPHOTERIC. This means it can wither be an aicd or a base
34
What does it mean for a substance to be amphoteric?
The substand must have H to give away (act as a acid) and either negative charge or lone pair of electrons where it can accept H (act as a base)
35
What is a strong acid?
Dissociates completely (or nearly so), meaning once they reach equilibrium there are almost no undissociated acid molecules remaining, the mixture will have mostly ions
36
What is a weak acid?
Only dissociate a small amount, meaning once they reach equilibrium there will be a lot of undissociated acid molecules & very little ions.
37
How do weak acids and strong acids differ when dissolved in water?
A strong acid completely dissociates into its ions, releasing all its hydrogen ions and creating a high concentration of H+ ions in the solution. While, a weak acid only partially dissociates, resulting in a much lower concentration of H+ ions due to equilibrium between the undissociated acid molecules and it ions.
38
What are buffers?
Solution that resist change in pH when small amounts of acid/base are added (*contain weak acid and conjugate base*)
39
What happens in a buffer solution when acid is added?
Added acid reacts with conjugate base to make more weak acid; this cause pH to decrease slightly
40
What happens to buffer solution when base is added?
Added base reacts with weak acid to make more conjugate base; this causes the pH to increase slightly
41
When do buffers function optimally?
At a pH level near the pKa value
42
When buffer contains equal amounts of the weak acid and congate base. What is the relationship between pH and pKa values?
pH = pKa
43
If weak acid > conjugate base
pH is slightly below pKa
44
If conjugate base < weak acid
pH is slightly above pKa
45
What is the main buffer system of the body?
H2CO3+H2O ----> HCO3- + H30+ its controlled by CO2
46
What is a neutralization reaction?
Acid + Base (hydroxide) = water and a salt HCl + NaOH ----> H-OH + NaCl
47
What is a special neutralization reaction?
Acid + carbonate/bicarbonate = release CO2 gas (and water + salt)
48
Conjugate acid/base reaction with acid and AMINE (N- containing organic molecule)
Acid + Ammonia (or derivative) ----> ammonium salt ex. NH3 + HCl ----> NH4Cl (NH4 = 1+ and Cl = 1-)
49
Concentration of an unknown acid or base can be found from ________
titration