Exam 3 Flashcards
Alloys containing more than 50wt.% Fe
Ferrous Alloys
Alloys containing less than 50wt.% Fe
Nonferrous Alloys
Based on carbon content:
(< 0.008wt% C)
Pure iron
Based on carbon content:
0.008 ~ 2.14wt% C
Steels
In most steels the microstructure consists of both
a and Fe3C phases
Carbon concentrations in commercial steels rarely exceed
1.0 wt%
Based on carbon content:
2.14 ~ 6.70wt% C
Cast irons
Commercial cast irons normally contain less than
4.5wt% C
Less than 0.25 wt%C, containing only residual concentrations of impurities and a little manganese.
Plain carbon steels
About 90% of all steel made is
carbon steel
more alloying elements are intentionally added in specific concentrations
Alloy steels
What are the 3 Ferrous Alloys — Steels?
Plain carbon steels
Alloy steels
Stainless steels
The first two digits indicate the
alloy content
The last two digits indicate the
the carbon concentration
For plain carbon steels, the first two digits are
1 and 0
alloy steels are designated by
other initial two-digit combinations (e.g., 13, 41, 43)
The third and fourth digits represent
the weight percent carbon multiplied by 100
For example, a 1040 steel is
a plain carbon steel containing 0.40 wt% C
A four-digit number
the first two digits indicate the alloy content; the last two, the carbon concentration
AISI
American Iron and Steel Institute
SAE
Society of Automotive Engineers
UNS
Uniform Numbering System
Low-carbon steels
Less than 0.25 wt%C
Medium-carbon steels
0.25 ~ 0.60 wt%C
High-carbon steels
0.60 ~ 1.4 wt%C
Unresponsive to heat treatments intended to form martensite; strengthening is accomplished by cold work
Low-Carbon Steels
Microstructures of low-carbon steel
ferrite and pearlite
Relatively soft and weak, but having outstanding ductility and toughness
Low-Carbon Steels
Typically, sy = 275 MPa, sUT = 415~550 MPa, and ductility = 25%EL
Low-Carbon Steels
Machinable, weldable, and, of all steels, are the least expensive to produce
Low-Carbon Steels
Applications for low-carbon steels:
automobile body components, structural shapes, and sheets used in pipelines, buildings, bridges, etc.
0.25 ~ 0.60 wt% C
Medium-Carbon Steels
May be heat treated by austenitizing, quenching, and then tempering to improve their mechanical
Medium-Carbon Steels
Often utilized in the tempered condition
Medium-Carbon Steels
Microstructures of medium carbon steel:
tempered martensite
Stronger than low-carbon steels and weaker than high-carbon steels
Medium-Carbon Steels
Applications for medium-carbon steels:
railway wheels and tracks, gears, crankshafts, and other machine parts and high-strength structural components calling for a combination of high strength, wear resistance, and toughness
0.60 ~ 1.4 wt%C
High-Carbon Steels
Used in a hardened and tempered condition
High-Carbon Steels
Hardest, strongest, and yet least ductile; especially wear resistant and capable of holding a sharp cutting edge
High-Carbon Steels
Containing Cr, V, W, and Mo; these alloying elements form very hard and wear-resistant carbide compounds (e.g., Cr23C6, V4C3, and WC)
High-Carbon Steels
Applications for high carbon steel:
cutting tools and dies for forming and shaping materials, knives, razors, hacksaw blades, springs, and high-strength wire
Stainless steels are selected for their excellent
resistance to corrosion
Stainless steels are divided into three classes:
martensitic, ferritic, or austenitic
The predominant alloying element in stainless steel is
chromium; a concentration of at least 11 wt% Cr is required
The predominant alloying element __________
permits a thin, protective surface layer of chromium oxide to form when the steel is exposed to oxygen
Aluminum and aluminum alloys are the most widely used
nonferrous metals
strengthened by cold working and alloying
Aluminum alloys
Nonheat-treatable: single phase, solid solution strengthening
Aluminum alloys
Low density (2.7 g/cm3), as compared to 7.9 g/cm3 for steel
High electrical and thermal conductivity
Resistant to corrosion in some common environments
Easily formed and thin Al foil sheet may be rolled
Al has an FCC crystal structure; its ductility is retained even at very low temperatures
Limitation: low melting temperature (660°C)
Properties of aluminum alloys
Al alloys can provide a weight savings of up to ___ compared to an equivalent steel structure
55%
________ is used in the manufacture of aircraft and for fuel tanks in spacecraft
Aluminum plate
- So soft and ductile that it is difficult to machine
- Unlimited capacity to be cold worked
- Highly resistant to corrosion in diverse environments
Unalloyed copper
strengthened by cold working and/or solid-solution alloying
Copper alloys
________ and _______ are two common copper alloys
Bronze and brass
Applications for copper alloys:
costume jewelry, cartridge casings, automotive radiators, musical instruments, electronic packaging, and coins
Bronze is an alloy of _______ and _____.
copper and tin
May contain up to 25% tin
Bronze
Brass is an alloy of ______
and ____.
copper
zinc
Contain 5-30% zinc
Brass
The zinc ________ the strength of the copper
increases
_______ and _______ are also increased by the zinc.
Ductility
formability
Relatively new engineering material that possess an extraordinary combination of properties
Titanium
Low density (4.5 g/cm3)
Titanium
High melting temperature (1668°C), high elastic modulus (107 GPa)
Titanium
What are the limitations of titanium?
- Chemical reactivity with other materials and oxidation problems at elevated temperatures
- Cost
What are the applications of titanium?
High-strength prosthetic implants, petroleum & chemical-processing equipment, airframe structural components
Most polymers are
hydrocarbons
Each carbon singly bonded to four other atoms
Saturated hydrocarbons
Example of a Saturated hydrocarbons
Ethane, C2H6
Double & triple bonds somewhat unstable – can form new bonds
Unsaturated Hydrocarbons
_______ found in ethylene (ethene) - C2H4
Double bond
_________ found in acetylene (ethyne) - C2H2
Triple bond
two compounds with same chemical formula can have quite different structures
Isomerism
Example of Isomerism
C8H18:
normal-octane
2,4-dimethylhexane
_______ is a long-chain hydrocarbon
polyethylene
Molecular Shape is also known as
Conformation
chain bending and twisting are possible by rotation of carbon atoms around their chain bonds
Molecular Shape
not necessary to break chain bonds to ________
alter molecular shape
two or more monomers polymerized together
Copolymers
A and B randomly positioned along chain
random
A and B alternate in polymer chain
alternating
large blocks of A units alternate with large blocks of B units
block
chains of B units grafted onto A backbone
graft
Crystallinity in Polymers
- Ordered atomic arrangements involving molecular chains
- Crystal structures in terms of unit cells
Polymer Crystalline regions
- thin platelets with chain folds at faces
- Chain folded structure
Polymers _____ 100% crystalline
rarely
in Polymer Crystallinity, it is difficult for all regions of all chains to become ________
aligned
Degree of crystallinity is expressed as
% crystallinity
Some physical properties depend on
% crystallinity
Heat treating causes crystalline regions to _____ and % crystallinity to _______
grow
increase