Exam 3 Flashcards

1
Q

Which way does the mechanism arrow point?

A

the destination of the electrons

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2
Q

what type of electrons can move in a mechanism?

A

lone pair or bond

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3
Q

What is the charge if the atom gives up electrons?

A

positive

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4
Q

What is the charge of the atom if the atom gains electrons?

A

negative

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5
Q

What is the charge of the atom if the atom gains and loses electrons?

A

charge doesn’t change

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6
Q

What is a resonance structure?

A

hybrid of lewis structure where only the electrons are moving

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7
Q

where can we have resonance?

A

nonbonding electrons that are next to each other (atom without an octet or pi bonds)

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8
Q

How do you rank the importance on non-equivalent resonance structures?

A

1) satisfies the octet rule
2) least amount of charges (negative on the most EN atom)

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9
Q

What is meant by conjugated bonds?

A

adjacent pi bonds or non bonded

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10
Q

What does an acid do?

A

donate H+

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11
Q

What does a base do?

A

accept H+

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12
Q

What is a conjugate base?

A

the base that is formed in the forward reaction

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13
Q

Which way does the arrow go in acid/base reactions?

A

from the base to the H+ of the acid

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14
Q

What does a negative pKa value indicate?

A

strong acid (HCl)

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15
Q

What does a high pKa value indicate?

A

strong base

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16
Q

What correlates with increased acidity?

A

higher electronegativity and electron affinity

17
Q

How does the strength of the bond affect acidity?

A

stronger acid = weaker bond

18
Q

How does charge correlate to acid/base reactions?

A

more charge is a better acceptor

19
Q

How does acid strength increase on the periodic table?

A

stronger to the right and to the bottom

20
Q
A