Exam 2 Prep Flashcards

1
Q

positive charge (typically metals)

A

cations

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2
Q

negative charge (typically nonmetals)

A

anions

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3
Q

average distance from the nucleus _____ down a group

A

increases

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4
Q

Zeff ______ across a row

A

increases

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5
Q

atom sizes decrease

A

across a row

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6
Q

cations are _____ than their parent ions

A

smaller

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7
Q

anions are _____ than their parent atoms

A

larger

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8
Q

amount of energy required to remove an electron from the ground state of a gaseous atom or ion

A

ionization energy

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9
Q

ionization energy ______ down a group

A

decreases

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10
Q

ionization energy _______ across a row

A

increases

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11
Q

Going down a row, ____ energy is required to remove the first electron

A

less

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12
Q

Going across a row, it gets ______ to remove an electron

A

harder

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13
Q

_____ is required to remove each successive electron

A

more

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14
Q

when all valence electrons have been removed, the ionization energy is _____

A

much greater

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15
Q

the energy involved when a gaseous atom gains an electron to form an anion

A

electron affinity

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16
Q

what type of elements have no affinity for electrons

A

noble gases

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17
Q

ionic bonds usually form between

A

a metal and a nonmetal

18
Q

the amount of energy related when gas-phase ions combine to form one mole of a crystalline solid

A

lattice energy

19
Q

Lattice energy becomes more exothermic as the ____ on the ions increases

20
Q

Lattice energy becomes less exothermic as ____ increases

21
Q

an atom’s tendency to attract electrons toward itself within a covalent bond

A

electronegativity

22
Q

electronegativity ______ going left to right across the periodic table

23
Q

Electronegativity _____ moving up the periodic table

24
Q

electronegativity of hydrogen is approximately equal to that of ____

25
Why does EN increase going left to right across the periodic table
greater effective nuclear charge
26
why does EN decrease going down a column
more shells
27
The greater the difference in _____, the more polar the bond
electronegativity
28
The central atom of a lewis structure is ______ that isn't hydrogen
the least electronegative
29
valence electrons - ( lp electrons + 1/2 # of bp electrons)
Formal Charge
30
SN=2
Linear
31
SN=3
Trigonal Planar
32
SN=4
Tetrahedral
33
Bonded atoms:3 Lone Pairs:0
Trigonal Planar Bond Angle: 120
34
Bonded atoms:2 Lone Pairs:1
Bent Bond Angle: <120
35
Bonded Atoms:4 Lone Pairs: 0
Tetrahedral Bond Angle: 109.5
36
Bonded Atoms:3 Lone Pairs:1
Trigonal Pyramidal Bond Angle: <109.5
37
Bonded Atoms:2 Lone Pairs:2
Bent Bond Angle: <109.5
38
the 3D arrangement of bonding pairs and lone pairs of electrons about a central atoms
electron-pair geometry (Based on SN)
39
The 3D arrangement of the atoms in a molecule
Molecular geometry
40
(# of atoms bonded to central atom) + (# of lone pairs on a central atom)
SN formula
41
a model predicting the arrangement of valence electrons pairs around a central atom that minimizes their mutual repulsion to produce the lowest energy orientations
Valence-shell electron-pair repulsion (VSEPR)
42
Separation of electrical charge created when atoms with different electronegativities form a covalent bond
Bond Dipole