EXAM 2 chapter 13 Flashcards
solution is a homogeneous mixture which is
made up of two or more diff chemical substances in a single phase (solvent + solute)
solvent is the substance
present in the solution in the largest amount (commonly water)
other substances are
solutes
if one of the substances is liquid and the others are solids or gases than
the liquid is the solvent no matter what the quantities are
solution formation is the result of interaction of
the intermolecular forces of solvent and solute particles
nature has a tendency toward
and uniform mixing is generally
spontaneous mixing
more energetically favorable
amount of solute in a solution is
an important property of the solution
dilute solution contains
small quantities of solute relative to amount of solvent
concentrated solution contains
large quantities of solute relative to amount of solvent
common ways to report solution concentration
molarity, molality, parts by mass, parts by volume, mole fraction and mole percent
solubility is the amount of
substance that will dissolve in a given amount of solvent
solubility of a substance depends on
entropy (nature’s tendency toward spontaneous mixing) and types of intermolecular forces
water is solvent in a solution than it is
an aqueous solution
water isn’t a universal
solvent
IMFs may
hinder or promote the formation of a solution
three possible interactions that can exist in a solution
solvent-solute, solvent-solvent and solute-solute
a solution will generally form if
solvent-solute interactions are stronger or comparable to solvent-solvent/solute-solute interactions
if solvent-solute interactions are weaker than the sum of solute-solute/solvent-solvent interactions
the solution will form only if the energy diff is small enough to be overcome by increase in entropy from mixing
formation of solution step 1
solute is separated into its constituent parts
formation of solution step 2
solvent particles are separated from each other to make room for solute particles
formation of a solution step 3
the solute and solvent particles are mixed together
Hesse’s Law says that the enthalpy of the solution is
equal to the sum of the individual enthalpies