EXAM 2 Flashcards
Polymers that form gels
Carbs: Amylose fraction of starch (polymer of glucose); Pectin (Polymer of galacturonic acid)
Protein: Gelatin (polymer of amino acids)
Emulsion
liquid in liquid dispersion
- dispersed or discontinuous phase= usually oil
- dispersion or continuous phase= most likely water-based
Emulsifier
- a stabilizing compound that helps keep one phase dispersed in another
- act as a surfactant: surface-active agent that reduces a liquid’s surface tension to increase its wetting and blending ability
- large molecules with hydrophilic and lipophilic ends
Thickeners
used in food preparation to improve mouthfeel of foods by increasing viscosity of liquids
Most Common thickeners
Carbs: Cereal Grains; Roots and Tubers
Proteins: egg and gelatin
Viscosity
The property of a fluid that resists internal flow by releasing counteracting forces
Coalescence
To grow together, unite into a whole
- may happen in extreme temps
Moist heat
gelatinizes starches
dry heat
caramelizes sugars
Heat application of proteins
denatures or coagulates proteins
Water
Foods have 0-95% water content
Chemically: H+ and OH- (polar)
- one oxygen atom flanked by two hydrogen atoms (H2O)
Solute
solid, liquid, or a gas compound dissolved in another substance
Dispersion system: Two Phases
Dispersed Phase: Solute
Continuous Phase: Solvent
What does the classification of solutions depend on?
- state of matter
- size of the dispersed particle
Classification of Solutions
A. True Solutions
B. Colloidal Dispersions
C. Coarse Dispersions (Suspensions)
True Solutions
- Homogeneous
- Stable
- Very Small Particle
Colloidal Dispersions
- Heterogeneous
- Less Stable
- Intermediate Particle Size
Coarse Dispersions (Suspensions) - all 3 involve a solute and a solvent [a dispersed phase (particle) and continuous phase (dispersed medium)]
- Heterogeneous
- Very Unstable
- Large Particle Size
Solution
- Common in foods
- solute (dispersed phase) very small ions or molecules
- Mixture is homogeneous due to kinetic motion of solute
- Usually very stable
- Incapable of forming gels
Types of Colloidal Dispersions
- Gel
- Foam
- Emulsion
- Sol
Gel
liquid-in-solid dispersion (somewhat rigid)
- jam, gelatin, cheese, butter
Structure:
- Long chain like polymers cross-linked randomly to produce a 3D structure
- Large particles connect loosely: Forms a network that traps liquid, liquid keeps the polymer network from collapsing
Produced mixing larger water soluble molecules in solvent
- gel
- protein
Foam
gas-in-liquid or gas-in-solid dispersion
- Air/raw egg white, whipped cream, marshmallow
Emulsion
liquid-in-liquid dispersion
- oil/vinegar, milk, butter, mayonnaise, salad dressings
Produced by mixing 2 immiscible substances
- oil and vinegar
- Fat and Water
Sol
Solid-in-liquid dispersion (pourable)
- gravy, jellies
Gels: Characteristics
- Mainly fluid, behave like rigid solids
- Soft, but resilient and elastic
- Holds the shape of its container
- Affected by temperature, pH, and concentration
Starch Thickeners
- used to increase viscosity of soups, and gravies to improve the mouthfeel of the solution
- product then becomes a coarse dispersion (suspension)
Starch
- Complex carbohydrate
- provides energy
- Well-balanced diet has 45-65% calories from carbohydrate
- Food industry uses starches widely
Characteristics of Starch
- Plants serve as source of starch granules
- granules are plant cell’s unit for starch storage
- Common sources: wheat, rice, and corn
- root starches: Potatoes, arrowroot, and cassava (tapioca)
Starch granule sizes (largest to smallest)
- Potato starch granules
- Corn
- Tapioca
- Rice
- Taro root
Cornstarch
Wet milling derives starch from corn
- major source (90%+) of starch in the United States
Starch in Food Products
- Thickening Agent
- Edible Films
- Dextrose (e.g., sweetener)
- Starch Syrups (e.g., corn syrup)
Starch Structure
- Polysaccharide
- long chains of repeating glucose molecules
- linked together in form of either:
- amylose
- amylopectin
amylose
primarily linear molecules
amylopectin
highly branched
Starch Characteristics in forming Gels
Starch Structure
- Most starches are about 75% amylopectin and 25% amylose
- High-amylose starches: 40-70% amylose
- All starches contain some amylose
- The varying content of amylose is what causes texture difference in starchy foods
waxy
starches consisting entirely of amylopectin
Starches with higher levels of amylose
tend to gel
- grain starches (corn, wheat)
starches with higher levels of amylopectin
are nongelling, still somewhat gummy
- root starches (potato, tapioca)
Starches are valuable due to their ability to undergo
- gelatinization
- gel formation
- retrogradation
- dextrinization
Concentration of amylopectin and amylose in a starch determines to which degree these processes will take place
Gelatinization definition
Increase in volume, viscosity, and transluscency of starch granules when heated in a liquid
- cells swell, absorbing water, increase volume, improve viscosity
factors influencing gelatinization
A. Water- sufficient to hydrate starch
B. Temperature- varies for starch
C. Heating time- do not go beyond temperature time
D. Stirring- to prevent lumping
E. Acid- neutral pH necessary
F. Sugar- competes with starch for water; add more water
G. Fat- delays gelatinization
Gel Formation
Viscous hot paste (sol) upon cooling becomes semi-rigid (gel)
Reversible process
Sol–Gel
Gel+Heat–Sol
Cooled Sol to gel–process is called gelation
Dependent on presence of enough amylose molecules
- amylose will gel
- amylopectin will not gel
High amylopectin starches
- thicken at lower temperatures
- are ideal for pie fillings and sauces
Include: - cornstarch
- tapioca
- potato
- wheat flour
retrogradation
As gels cool, bonds continue to form between amylose molecules, and retrogradation occurs
- phenomenon during cooling of gelled starch when amylose and amylopectin molecules “retrograde” and realign themselves
- staling in baked products and syneresis (weeping) in gels may occur
Dextrinization
breakdown of starch molecules to smaller, sweeter-tasting dextrin molecules in the presence of dry heat
- results in an increase in sweetness
- dextrinized starches lose much of their thickening power
- dry heat applied to starch
ex. toasted bread
Modified Food Starch
- manufactured product from natural starches by chemically altering molecular structure
- created to satisfy a particular food manufacturing purpose (stronger gel, freeze resistant)
- Do not separate (retrogradation or syneresis)
- Safe (FDA- just as digestible as unmodified)
pregelatinized starch
Instant or pregelatinized starches - to alter starch's gelatinization, heating times, freezing stability, cold-water solubility, or viscosity, starches can be modified - physically - enzymatically - chemically Starch cooked and dried Used in "instant" mixes
Gelatin
- Protein used in foods to form gels
- Extracted from the hides, skin, and connective tissue of all types of animals
- Obtained from hydrolysis of collagen
Preparation of gel
- Add water to gelatin powder
- disperse by heating
- Stir
- Cool
Phases of Gel Formation
- Hydration
- Dispersion
- Gelation
Hydration
- Gelatin can absorb 5x its weight in hot water
- extremely effective gelling agent
Dispersion
- hot liquid added to disperse protein molecules
- After Protein is completely dispersed, remaining liquid may be cooled
Gelation
Viscous hot paste (sol) cools to a gel
- change occurs as protein molecules form cross-linkages to trap water in a meshlike network
- water remains trapped
Factors influencing gel formation
- concentration of gelatin
- temperature
- sugar
- acid
Things to avoid in gelatin
- Salts
- Foods containing the following proteolytic enzymes
- Added Solids
Most common cereal grains
- Corn, rice, wheat, and barley (95%)
- remaining 5% of world production of grains include sorghum, millets, oats, and rye
Reasons cereal grains are consumed worldwide
- easily produce
- low cost
- nutritional value (fiber, complex CHO), especially whole grains–possessing functional food properties (lower CVD risk)
DGA’s recommend ___ of cereal intake should be ____ _____
1/2, whole grains
Structure of cereal grains
- Endosperm
- Husk “chaff”
- Bran
- Germ
Husk “chaff”
- protection from weather
- not usually consumed; can be processed into fiber supplements
Bran
- removed in the process of making white flour
- excellent source of indigestible fiber, vitamins and minerals
- Aleurone–high in protein, B-Vitamins and minerals, and some fat
- makes up 14% of the kernel
Endosperm
- makes up 83% of the grain
- contains starch
- source of complex digestible carbohydrate
Germ
- 2.5% of the grain
- rich in fat, incomplete protein, vitamins, and minerals
- susceptible to spoilage due to fat content
- Sold separately as wheat germ (excellent source of B-vitamins & Vitamin E)