exam 2 Flashcards

1
Q

dilution

A

M1V1=M2V2

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2
Q

temperature/solubility relationship

A

inverse

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3
Q

Henry’s Law

A

C (concentration of dissolved gas) = k (constant) x P (partial pressure of a gas)

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4
Q

Boyle’s Law

A

V = (1/P)k

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5
Q

Charles’ Law

A

V=k(constant) x T (Kelvin)

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6
Q

Avogadro’s law

A

V = k x n(moles)

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7
Q

ideal gas law

A

PV=nRT
- no interactions between gas atoms
- gas atoms have 0volume

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8
Q

R (ideal gas law questions)

A

0.08206 Latm/molK

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9
Q

STP

A

273.15 K, 1 atm = 760 torr

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10
Q

gas volume at STP

A

22.4 L/mole

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11
Q

molar mass (using ideal gas law)

A

PV = mRT/MM

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12
Q

dalton’s law of partial pressures

A

P (total) = P1 + P2 + P3 +…

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13
Q

arrhenius acids and bases definition

A
  • too limiting
    acid = H+ donor
    base = OH-
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14
Q

bronsted-lowry acids and bases definition

A

acid = proton donor
base = proton acceptor

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15
Q

oxidation

A

loss of electrons

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16
Q

reduction

A

gaining electrons

17
Q

oxidizing agent

A

does the oxidizing so it gets reduced (gains electrons)

18
Q

reducing agent

A

does the reducing so it gets oxidized (loses electrons)

19
Q

molarity

A

moles/liters

20
Q

molality

A

moles/kg of solvent

21
Q

mole fraction

A

mole A/total moles

22
Q

average kinetic energy of one mole of gas

A

E =3/2RT
R = 8.31J/kmol
J= kg x m^2/s^2

23
Q

velocity proportion of average kinetic energy of one mole of gas

A

E = 1/2MMu^2

24
Q

root mean square velocity

A

u (rms) = sqrt (3RT/2MM)

25
Q

graham’s law of effusion

A

rate of effusion of g1/rate of effusion of g2 = sqrt(MM2)/sqrt(MM1)

26
Q

kinetic molecular theory

A
  1. particles volume is negligible (=0)
  2. particles are in constant motion
  3. particles neither repel nor attract each other
  4. average kinetic energy of gas particles is assumed to be directly proportional to temperature (K) of gas
27
Q

work

A

w = f x d
w -P(delta)V

28
Q

change in internal energy

A

deltaE = q + w

29
Q

calorimetry

A

q = mCdeltaT
m=mass
cdelta= specific heat capacity
T=temperature

deltaE=mCdeltaT

30
Q

real gases are ideal when

A

have high temperature and low pressure