Exam 1 Study Guide 6 Flashcards
The simplest of all organic compounds- composed only of carbon and hydrogen atoms
Hydrocarbon
Increase in number of carbon increases ___
boiling point
The structure of ___ reveals bend
propane
Hydrocarbons exhibit ___
isomerization
molecules with the same molecular formula but different arrangement of atoms
structural isomers
Carbon atoms have a characteristic ___ arrangement of their four single bonds
tetrahedral
Carbon-carbon single bonds have ___, as shown for the compound ethane
freedom of rotation
Double bonds are ___ and do not allow ___. The two doubly bonded carbons and the atoms designated A, B, X and Y all lie in the same rigid plane.
shorter
freedom of rotation
molecules that differ in the arrangement of functional groups at either side of a non-rotating double bond
geometric isomer
Hydrocarbons are composed of ___ and ___
Carbon
Hydrogen
Hydrocarbons are ___ and ___
non-polar
hydrophobic
Oxygen-containing functional groups are found in the following groups molecules
Alcohols organic acids carbohydrates amino acids nucleic acids lipids metabolites
Alcohols maintain inter-molecular hydrogen bonding and this hydrogen bonding contributes to the ___ for alcohols
higher boiling temperature
Because of hydrogen-bonding, alcohols are ___
water soluble
Final product of fermentation in many microorganisms
metabolites (ethanol)
all ___ contain an aspect ratio of one hydroxyl group per skeletal carbon
carbohydrates
___ are most commonly stored as glycerol esters
Fatty acids
Several of the ___ have side chains containing hydroxyl groups
amino acids
Aldehyde group is present in an important class of sugars: ___
aldoses
Name 3 Aldoses
glyceraldehyde
ribose
glucose
These reactions are particularly important in the chemistry of carbohydrates. These reactions are needed for conversion of a linear sugar to cyclic molecule.
Reactivity of Ketones with Alcohols
___ are carboxylated long-chain hydrocarbons
fatty acids
Reactivity of an alcohol and a carboxylic group generates an
ester
like carboxylic acids, esters are also ___
charged-polarized
amines act as ___
bases
___ are involved in a proton-transfer reaction
amino groups
amino acids contain both ___ and ___ groups
amino-
carboxy-
amino acids reacting with their amino and carboxylic ends generate a ___ and generate a ___
peptide bond
polypeptide
___ is the only amino acid with a guanidino-containing side chain
arginine
___ is a guanidino with high energy phosphate transfer potential
creatine
___ can act as acid or base
imizadole
___ in Cystein makes covalent bridges between polypeptides
sulfhydryl group
sulfhydryls and carboxylic groups react to make ___
thio-esters
___ are high-energy molecules and release a large amount of energy upon hydrolysis
Thio-ester
reactivity of alcohol and phosphate results in a ___
phosphate ester