Exam 1 Study Guide 6 Flashcards

1
Q

The simplest of all organic compounds- composed only of carbon and hydrogen atoms

A

Hydrocarbon

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2
Q

Increase in number of carbon increases ___

A

boiling point

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3
Q

The structure of ___ reveals bend

A

propane

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4
Q

Hydrocarbons exhibit ___

A

isomerization

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5
Q

molecules with the same molecular formula but different arrangement of atoms

A

structural isomers

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6
Q

Carbon atoms have a characteristic ___ arrangement of their four single bonds

A

tetrahedral

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7
Q

Carbon-carbon single bonds have ___, as shown for the compound ethane

A

freedom of rotation

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8
Q

Double bonds are ___ and do not allow ___. The two doubly bonded carbons and the atoms designated A, B, X and Y all lie in the same rigid plane.

A

shorter

freedom of rotation

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9
Q

molecules that differ in the arrangement of functional groups at either side of a non-rotating double bond

A

geometric isomer

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10
Q

Hydrocarbons are composed of ___ and ___

A

Carbon

Hydrogen

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11
Q

Hydrocarbons are ___ and ___

A

non-polar

hydrophobic

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12
Q

Oxygen-containing functional groups are found in the following groups molecules

A
Alcohols
organic acids
carbohydrates
amino acids
nucleic acids
lipids
metabolites
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13
Q

Alcohols maintain inter-molecular hydrogen bonding and this hydrogen bonding contributes to the ___ for alcohols

A

higher boiling temperature

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14
Q

Because of hydrogen-bonding, alcohols are ___

A

water soluble

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15
Q

Final product of fermentation in many microorganisms

A

metabolites (ethanol)

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16
Q

all ___ contain an aspect ratio of one hydroxyl group per skeletal carbon

A

carbohydrates

17
Q

___ are most commonly stored as glycerol esters

A

Fatty acids

18
Q

Several of the ___ have side chains containing hydroxyl groups

A

amino acids

19
Q

Aldehyde group is present in an important class of sugars: ___

20
Q

Name 3 Aldoses

A

glyceraldehyde
ribose
glucose

21
Q

These reactions are particularly important in the chemistry of carbohydrates. These reactions are needed for conversion of a linear sugar to cyclic molecule.

A

Reactivity of Ketones with Alcohols

22
Q

___ are carboxylated long-chain hydrocarbons

A

fatty acids

23
Q

Reactivity of an alcohol and a carboxylic group generates an

24
Q

like carboxylic acids, esters are also ___

A

charged-polarized

25
Q

amines act as ___

26
Q

___ are involved in a proton-transfer reaction

A

amino groups

27
Q

amino acids contain both ___ and ___ groups

A

amino-

carboxy-

28
Q

amino acids reacting with their amino and carboxylic ends generate a ___ and generate a ___

A

peptide bond

polypeptide

29
Q

___ is the only amino acid with a guanidino-containing side chain

30
Q

___ is a guanidino with high energy phosphate transfer potential

31
Q

___ can act as acid or base

32
Q

___ in Cystein makes covalent bridges between polypeptides

A

sulfhydryl group

33
Q

sulfhydryls and carboxylic groups react to make ___

A

thio-esters

34
Q

___ are high-energy molecules and release a large amount of energy upon hydrolysis

A

Thio-ester

35
Q

reactivity of alcohol and phosphate results in a ___

A

phosphate ester