exam 1 ch 2 Flashcards

1
Q

what elements make up 95 percent of organic enviro

A

carbon, hydrogen, nitrogen, oxygen

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2
Q

molecules carrying ions interact how with water

A

favorably

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3
Q

uncharged molecules interact with water how

A

form few to no H bonds

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4
Q

electrostatic attractions strongest when..

A

atoms are fully charged

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5
Q

occur when atoms become close to each other

A

van der waals

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6
Q

proton from molecule gets attracted to what in water

A

oxygen (acids)

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7
Q

when a proton is attracted to O in water, what happens

A

hydronium ion formed

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8
Q

substance that release H+

A

acids

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9
Q

easily lose their proton

A

strong acid

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10
Q

any molecule capable of accepting a proton from H2O

A

base

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11
Q

cell is formed from what

A

carbon compounds

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12
Q

small molecules contain about how many carbons

A

30

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13
Q

what can small molecules be used for

A

to make macromolecule, used as energy source

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14
Q

4 major forms of small molecules

A

sugars, fatty acids, nucleotides, amino acids

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15
Q

most abundant c containing molecules

A

macromolecules

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16
Q

each polymer grows by what and what reaction

A

addition of monomer onto the end of the growing chain in a condensation reaction

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17
Q

what happens to h2o in condensation reaction

A

1 molecule of h2o lost

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18
Q

specify both precise shape of a macromolecule and its binding to other molecules

A

non covalent bonds

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19
Q

shapes of molecules usually highly constrained due to what

A

non covalent bonding

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20
Q

cell metabolism organized by what

A

enzymes

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21
Q

cell needs to control its chemistry via what

A

catalysts

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22
Q

catalysts are almost always what

A

enzymes

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23
Q

when dealing with enzymes, what is starting material called

A

substrate

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24
Q

breakdown food into smaller molecules, what process

A

catabolic

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25
use small molecules plus energy harnessed from catabolism to drive sys of many other molecules
anabolic
26
catabolic and anabolic processes together known as what
metabolism
27
biological order made possible by what
heat release
28
universe degree of disorder constantly increasing
2nd law of thermodynamic
29
amount of disorder in a system
entropy
30
greater disorder = what
greater entropy
31
why does cell not break 2nd law of thermodynamics
cell isn't isolated system
32
cell uses what to create order
energy
33
energy in its most disordered form
heat
34
energy can't be created or destroyed
first law of thermo
35
cell can't derive any benefit from the heat energy it releases unless what
heat generating reactions inside cell are directly linked to generating molecular order
36
cells obtain E how
oxidation of organic mole
37
e extracted from food molecules how
gradual oxidation aka controlled burning
38
removal of electrons
oxidation
39
addition of electrons
reduction
40
when a molecule picks up e-, often picks up what
H+
41
hydrogenations are what
reductions
42
dehydrogenations are what
oxidation
43
downhill reaction is what
spontaneous
44
substance that can lower activation E
catalyst
45
when enzyme lowers activation energy for forward reaction, what else does it do
lowers it for reverse reaction too
46
each enzyme has unique what
shape containing an active site
47
why can enzyme + substrate rapidly bind
motion caused by heat energy being very fast
48
movement of molecule from one place to another
translational motion
49
rapid back and forth movement of covalently linked atoms
vibration
50
translational movements, vibrations, and rotations all do what
help bring surfaces of interaction molecules together
51
molecules exploring spac einside of cell
diffusion
52
molecule bouncing off another then another then another
random walk
53
change in free E
delta G
54
cells can build ordered from unordered by what
coupling energetically favorable with unfavorable
55
reaction that leads to increase in randomness is what kind
spontaneous
56
spontaneous reaction have what delta g
negative
57
equilibrium constant
k
58
delta g prime
delta g when conc of x and y are the same
59
energy stored temporarily from food
carrier molecules
60
store E in easily exchangeable form, readily transferrable chem group or e-
activated carriers
61
activated carriers also known as what
coenzymes
62
most important coenzymes
ATP, NADH, NADPH
63
formation of activated carrier coupled to..
energetically favorable reaction
64
convenient and versatile store of energy
ATP
65
energy stored in ATP often harnessed to
bring 2 molecules together
66
is condensation reaction energetically favorable or unfav
unfavorable
67
what can condensation reactions be driven by
ATP
68
NAD+ and NADP+ both pick up what
2 e- and 1 H+
69
NADH and NADPH both carriers of what
hydride ions
70
NADPH donates hydride ions why
bc of large negative free E exchange
71
extra phos group of NADPH has no effect on e- transfer but does what
give different shape than NADH allowing them to bind to diff enzymes
72
used to add 2 c units
acetyl coa
73
hydrolysis favorable or unfavorable
energetically favorable