Exam 1 Flashcards

1
Q

What does the first law of thermo define?

A

Define Internal Energy and introduces enthalby

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2
Q

What is Internal Energy (U)?

A

The total capacity for heat transfer and work in the system

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3
Q

What does the 2nd law of thermo define?

A

Entropy (S)

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4
Q

What is Entropy?

A

A measure of molecular randomness in a system

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5
Q

What is an intensive property? Give examples

A

Independent of amount of mass.

E.g.: Density, Temperature, Pressure

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6
Q

What is an extensive property? Give examples

A

Dependent on amount of mass in a system.

E.g.: Volume, mass, total energy

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7
Q

What property is held constant in ISOBARIC PROCESS?

A

Pressure

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8
Q

What property is held constant in ISOTHERMAL PROCESS?

A

Temperature

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9
Q

What property is held constant in ISOCHORIC (OR ISOMETRIC) PROCESS?

A

Volume

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10
Q

What property is held constant in ISOENTROPIC PROCESS?

A

Entropy (S)

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11
Q

Gage Pressure

A

Pgage = Pabs - Patm

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12
Q

Vacuum Pressure

A

Pvac = Patm - Pabs

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13
Q

Define Macroscopic form of energy and give examples

A

The energy of system as a whole with respect to some outside reference frame.
E.g., kinetic energy and potential energy of an object

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14
Q

Define Microscopic form of energy and give examples

A

Related to the molecular structure or molecular activity of the system. The sum of all the microscopic forms of energy is call internal energy

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15
Q

Define total kinetic energy (macroscopic)

A

the energy that a system possesses as a result of its motion relative to some reference frame

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16
Q

What does adiabatic mean?

A

No heat transfer

17
Q

What two functions are dependent of the PATH followed

A

Heat & Work

18
Q

What functions are dependent on the state (Point functions)

A

Properties (P, T, v, u)

19
Q

What is the most common form of mechanical work in thermo?

A

Boundary Work

20
Q

What are the two requirements for a work interaction between a system and its surroundings?

A
  1. Must be a FORCE acting on boundary.

2. Boundary must MOVE

21
Q

Define Pure substance

A

Has a homogeneous chemical composition and may exist in more than one phase (mixture of elements, mixture of two or more phases)

22
Q

Examples of a Pure Substance

A
  1. Mixtures of gases, such as air
  2. Water
  3. Carbon Dioxide
  4. Nitrogen
23
Q

What are the 5 phase-change processes of pure substances

A
  1. Compressed liquid
  2. Saturated liquid
  3. Saturated liquid-vapor mixture
  4. Saturated vapor
  5. Superheated vapor
24
Q

Define Saturation Temperature

A

Temperature at which a pure substance changes phase at a given pressure

25
Q

Define Saturation Pressure

A

Pressure at which a pure substance changes phase at a given temperature

26
Q

Define Enthalpy (H)

A

Heat content of a system