Exam 1 Flashcards
base unit for length
meter
base unit for mass
kg
base unit for time
seconds
base unit for temp
kelvin
base unit for amt of substance
mole
celsius to kelvin
C+273.15
celsius to fahrenheit
(Cx(9/5))+32
Fahrenheit to celsius
(F-32)x(5/9)
Kelvin to celsius
K-273.15
density 3 formulas
D=M/V
M=DxV
V=M/D
physical change
state of matter changes, composition doesn’t
ex: melting
chemical change
composition changes
ex: oxidation
Democritus
4th century BCE philosopher postulated the existence of an “uncuttable” piece of matter
Dalton
atom is indivisible
JJ Thomson
discovered electron
cathode ray tube
measured charge to mass ratio for electron
Rutherford
atoms are mostly made up of air
positive charge and most of the mass located in nucleus
gold foil experiment
Millikan
measured charge on electron and determined its mass
Oil drop experiment
Chadwick
discovered the neutron
Ion
atom with an unequal number of protons and electrons
protons>electrons
positive –> lose electrons
protons<electrons
negative –> gain electrons
atomic number
number of protons
on bottom
atomic mass
number of protons and neutrons
on top
Isotope
atom with a different number of neutrons (atomic mass)
does frequency increase or decrease from left to right
increase
does energy increase or decrease from left to right
increase
does wavelength get longer or shorter from left to right
shorter because frequency increases
list the types of waves from lowest to highest frequency/ energy
radio wave, microwave, infrared, light, UV, x-ray, gamma ray
einstein photoelectric effect
when light strikes a metal surface, electrons are emitted
he figured out that metals like to give up electrons
threshold frequency
the minimum frequency of radiation needed for an electron to be emitted
Schrodinger
described electron density and atomic orbitals
De Broglie formula
wavelength=h/m x v
What De Broglie discover
electron can behave like a wave
Heisenberg uncertainty
can not know position and momentum (velocity) of a particle at the same time
principle quantum number n
size and energy
<0 whole numbers only
angular quantum number l
shape
0 - (n-1)
l=0 is what orbital
s
l=1 is what orbital
p
l=2 is what orbital
d
l=3 is what orbital
f
magnetic quantum number ml
orientation
-l,0,+l
spin quantum number ms
spin behavior
+1/2 (spin up) or -1/2 (spin down)
how does the n value correspond to the l value
n value is how many numbers starting at 0 l can be
ex: n=1 -> l=0
n=2 -> l=0,1
does first IE increase or decrease from left to right
increase
does effective nuclear charge (Zeff) increase or decrease from left to right
increase
does electron affinity increase or decrease from left to right
increase
does metallic character increase or decrease from left to right
decrease
does atomic radius increase or decrease from left to right
decrease
does first IE increase or decrease down a group
decrease
does effective nuclear charge (Zeff) increase or decrease down a group
decrease
does electron affinity increase or decrease down a group
decrease
does metallic character increase or decrease down a group
increase
does atomic radius increase or decrease down a group
increase
group 1A
alkali metals
group 2A
alkali earth metals
group B
transition metals
groups 3A-7A
other metals, metalloids, nonmetals
group 8A
noble gases
isoelectronic
two different atoms with the same charge
what do groups on the periodic table correspond to
number of valence electrons
what do periods correspond to
n value/E level
paramagnetic
unpaired valence electrons
diamagnetic
all valence electrons are paired
speed of light formulas
c=λv
v=c/λ
λ=c/v
light energy formulas
E=hv
E=hc/λ
s orbital shape
sphere
p orbital shape
dumbell
d orbital shape
clover
f orbital shape
flower
extensive property
depends on amt of substance
mass of volume
intensive property
independent of amt of substance
density
hypothesis
testable explanation which explains observations
theory
explains data from experiments
explains why not what
law
mathematical statement that explains how something happens
light
a form of electromagnetic radiation
what is electromagnetic radiation composed of
perpendicular oscillating waves one for the magnetic field and one of the electric field
s orbital
1 orbital (2 electrons)
p orbital
3 orbitals (6 electrons)
d orbital
5 orbitals (10 electrons)
f orbital
7 orbitals (14 electrons)
electron configurations
description of the orbitals occupied by electrons