EXAM 1 Flashcards

1
Q

particles must what to in order to react?

A

Collide

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2
Q

what causes a greater reaction rate?

A

high concentration of reactants; the high concentration allows for high number of collisions; also energy because more energy, more collisions

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3
Q

What causes the reaction rate?

A

physical state of reactants

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4
Q

what is collision theory?

A

particles most collide in order to react

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5
Q

the number of collations depends on what ?

A

the product of the number of reactant particles,

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6
Q

in order to be effective, collisions between particles must what?

A

exceed a certain energy threshold

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7
Q

when particles collide effectively, they reach what?

A

an activated state

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8
Q

what is activation energy?

A

the energy difference between the reactants and the activated state

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9
Q

what are the two things particles need to be effective?

A

energy & relative orientation

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10
Q

what does an effective collision of pa articles lead to?

A

transition state or activated complex

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11
Q

what is the transition state?

A

unstable species that contains partial bonds, a pathway between reactants and products, cannot be isolated

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12
Q

what is molecularity?

A

the number of particles involved in the reaction

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13
Q

what is a catalyst?

A

a substance that increases the reaction rate without being consumed in the reaction

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14
Q

what does a catalyst provide?

A

an alternative reaction pathway that has a lower total activation energy.

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15
Q

what does a catalyst do?

A

it speeds up both forward and reverse reactions but does not the overall yield of the reaction ``

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16
Q

Why are chemical equilibriums a dynamic state?

A

because they continue to occur at the same rate with no net change

17
Q

what does k reflect?

A

a ratio of product concentrations to reactant concentrations, it indicate an extent of how far a reactions proceeds towards it products

18
Q

what does a small value of K rule in favor?

A

the reactants

19
Q

what does a large value of K rule in favor?

A

the products

20
Q

Q < K

A

reactants must decrease and the products increase ( reactants to products until equilibrium)

21
Q

Q > K

A

the reactants increase and the products decrease ( products to reactants for equlibirum)

22
Q

how does a system respond to a disturbance?

A

a shift in equilibrium position

23
Q

what does a shift to the left mean?

A

net reaction from product to reactant

24
Q

what does a shift to the right mean?

A

net reaction from reactant to product

25
Q

What are the three ways to maximize the yield of NH3?

A

Decrease [NH3] by removing NH3 as it forms.
Decrease the volume (increase the pressure).
Decrease the temperature.