Exam 1 Flashcards

1
Q

t

the number of ________ defines the element

A

protons

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2
Q

t

the _____ _____ is defined by the number of protons in an element

A

atomic #

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3
Q

t

what is the equation for the atomic mass #

A

of protons + # of neutrons

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4
Q

t

atoms with specific combination of protons and neutrons

A

nuclides

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5
Q

t

same element, different mass numbers

A

isotopes

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6
Q

t

unstable nuclei that spontaneously release particles and/or change into another element

A

radioactive nuclides

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7
Q

t

do not undergo observable radioactive decay

A

stable nuclides

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8
Q

t

what are the three unifying chemical principles in oceanography

A

atoms cannot be creased or destroyed (Conservation of mass), some processes are possible, others unlikely (thermodynamics), all processes take time to happen (Chemical kinetics)

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9
Q

t

________ of chemicals at each place in the ocean are complete records of their histories (within uncertainty)

A

abundances

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10
Q

t

what are the 3 things atoms can do?

A

move (to different places), transform (interact and combine/react with other atoms in definite proportions and geometries, interact with their environment (absorb and scatter energy)

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11
Q

t

what are the 3 ways that atoms MOVE from place to place

A

advection, diffusion, sinking/rising

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12
Q

t

move with water . solutes carries by currents

A

advection

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13
Q

t

move through water. from regions of high to low concentration. generally much slower than advection

A

diffusion

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14
Q

t

moving through water. denser things sink, buoyant things rise. Generally, MUCH faster than advection

A

sinking/rising

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15
Q

t

during advection solutes move ______- water

A

with

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16
Q

t

in diffusion, particles move _____ water

A

through

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17
Q

t

when particles are sinking/rising they _____ ______ water

A

moving through

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18
Q

t

homogeneous mixtures

A

solutions

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19
Q

t

how densely populated a chemical substance is in a mixture

A

concentration

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20
Q

t

a measure of salt concentration in seawater

A

salinity

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21
Q

t

what is Marcets Principle ?

A

ratios between the amounts of the major ions in the waters of the open ocean are nearly constant

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22
Q

t

seawater is generally ________

A

unreactive

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23
Q

t

how do we observe chemicals in the ocean (3s’s)

A

satellites ( surface) , sensors (anywhere), samples )collecting atoms, anywhere)

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24
Q

t

depth profiles are a graph of

A

property vs depth

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25
Q

t

a contour plot is a graph of

A

property vs area

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26
Q

t

ocean section is a graph of

A

property over area

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27
Q

t

when making an ocean section graph, you cruise across the ocean and ______ ____ _____ along the way, and plot them at each location

A

take depth profiles

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28
Q

t

wind velocity is influenced by how many factors

A

4

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29
Q

t

what are the four factors the influence wind velocity

A

buoyancy, pressure gradient force, friction, coriolis force

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30
Q

t

air becomes more buoyant when it is _______ than the surrounding air

A

hotter and/or more humid

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31
Q

t

explain why humid air is less dense

A

water has a lower molar mass of air and when humid, it displaces some of the heavier gasses making moist air less dense

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32
Q

t

air accelated from regions of _____- to _____ pressure

A

high to low

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33
Q

t

when are there stronger winds

A

pressure difference is larger and/or distance smaller between the two places (when isobars are closer)

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34
Q

t

transfers energy from wind to surfaces, causing winds to slow near earths surface

A

friction

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35
Q

t

pushes winds 90 to the right in the northern hemisphere and 90 to the left in southern hemisphere

A

coriolis effect

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36
Q

t

which way does the coriolis effect push winds in the N hemisphere

A

right

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37
Q

t

which way does the coriolis effect push winds in the southern hemisphere

A

left

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38
Q

t

when is the coriolis effect stronger

A

winds are faster, closer to the poles, faster planetary rotation rate

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39
Q

t

why is there no coriolis effect on the equator?

A

there is no curving of the objects path, straight line , so no coriolis effect

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40
Q

t

what are the 4 simplifed steps to general circulation of lower atmosphere

A
  1. Earth is mostly a closed system with respect to matter, but not to energy
  2. Earths surfaces heated unevenly, more strongly near the equator
    3.Equatorial air rises to stable altitude (less dense)
  3. surrounding surface air replaces “void”
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41
Q

t

where are hadley cells

A

tropics

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42
Q

t

air rises and cools near the equator

A

hadley cells

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43
Q

t

what latitudes do hadley cells run from

A

30N to 30S

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44
Q

t

the hadley cells create this zone

A

intertropical convergence zone

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45
Q

t

after the air rises and cools near the equator the high air is now ______ and spreads poleward and ______

A

dry eastward

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46
Q

t

hadley cells make what winds by moving surface air to the equator

A

trade winds

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47
Q

t

there are major _______ where hadley cell air descends, dries, compresses, and thereby warms

A

deserts

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48
Q

t

where do the polar cells lie

A

60N and 60S

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49
Q

t

cold air cools and ____ near polls, spreads equatorward creating surface Polar Easterlies winds

A

sinks

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50
Q

t

ferrel cells

A

60-30N 30-60s

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51
Q

t

_____ cells depend on Polar and Hadley cells

A

ferrel

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52
Q

t

surface winds and storms move from __ _ ___, creating the prevailing westerlies

A

west to east

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53
Q

t

wind driven waves and currents

A

friction

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54
Q

t

winds “____” water via friction

A

drag

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55
Q

t

Winds drag water, but coriolis causes NET movement in upper ~100m of water to move 90right in NH and 90left in SH

A

ekman transport

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56
Q

t

if winds push surface water away from coast, deeper water rises to replace it

A

upwelling

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57
Q

t

if winds push water towards coast, the water pile up nearshore and sinks to deep sea (pressure pushes it down)

A

downwelling

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58
Q

t

what are the 3 important features of major surface currents

A

western boundary currents, gyres, and antarctic circumpolar current

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59
Q

t

major surface currents flow _________ in the northern hemisphere

A

clockwise

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60
Q

t

major surface currents flow ________ in the southern hemisphere

A

counterclockwise

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61
Q

t

changing temperature and or salinity changes __________

A

buoyancy

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62
Q

t

lines of constant density

A

isopycnal

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63
Q

t

seawater can become denser due to

A

cooling, evaporation (increasing salinity), cabbeling

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64
Q

t

mixing of two waters with the sae density but different temperature and salinity can yield a denser solution

A

cabbeling

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65
Q

t

N Atlantic is _____ salty than the N Pacific

A

more

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66
Q

t

why is the N atlantic saltier than the N pacific

A

N atlantic gyre is sunny and swept by dry trade winds from Sahara, water evaporated from the gyre carried to Pacific

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67
Q

t

the cooling salty water in the north atlantic is sufficiently dense due to

A

downwelling

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68
Q

t

band of continent free sea surface and cold strong winds

A

southern ocean

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69
Q

t

the southern ocean is a major site of ____ ____ _________

A

deep water formation

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70
Q

t

explain how north atlantic deep water forms

A

warm salty gulf stream moves north, cools, gets denser and sinks (downwells)

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71
Q

t

how is atarctic bottom water and -intermediate water made

A

wind driven upwelling intensely mixing waters vertically around antarctica; seaice formation makes residual water denser, sinks

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72
Q

t

wind driven upwelling intensely mixes waters vertically around antarctica: sea ice formation makes residual water denser, sinks

A

antarctic bottom water and antarctic intermediate water

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73
Q

t

what are the three waters that make up the antlantic ocean, top to bottom

A

antarctic intermediate water, north atlantic deep water, antarctic bottom water

74
Q

t

tradewinds move

A

east to west

75
Q

t

westerlies run

A

west to east

76
Q

t

polar easterlies run

A

east to west

77
Q

t

solar energy heating Earths surface ______ leads to pressure differences and the pressure gradient force.

A

unevenly

78
Q

t

how we expect gases to partition between atmosphere and seawater under specific conditions given enough time

A

thermodynamic perspective

79
Q

t

different gases have different _______ in water

A

solubility

80
Q

t

what formula is used to estimate Solubility

A

henrys law, k= equilibrium concentration of gas in a solution / equilibrium partial pressure of gas in air

81
Q

t

concentration expected at equilibrium of a gas dissolving under specific conditions

A

solubility

82
Q

t

EXPECTED concentration of gas for TOTAL air pressure

A

Normal atmospheric equilibrium concentration

83
Q

t

all gases are less soluble at _____ temperature

A

higher

84
Q

t

_____ gases are more sensitive to Temperatures

A

some

85
Q

t

higher temp means _____ solubility

A

lower

86
Q

t

why are all gases less soluble at higher temperature

A

at a higher temperature, harder to keep gas molecules confined

87
Q

t

_____ salinity takes up more space for other gasses to take up

A

high

88
Q

t

more salts _____ soluble

A

less

89
Q

t

what are the 4 potential causes of disequilibrium

A

rapid pressure or concentration changes, conservative mixing, bubble injection, in situ production or consumption

90
Q

t

how do rapid changes in pressure of concentration cause disequilibrium

A

inadequate contact time with atmosphere to reach equilibrium

91
Q

t

how does conservative mixing cause potential disequilibrium

A

solubility = non-linear function of T but conservative mixing = linear function of T

92
Q

t

how does bubble injection cause potential disequibirum

A

additional area and contact time on bubble surface for gas transfer, and or complete collapse of bubble

93
Q

t

how does in situ production or consumption cause potential disequilibrium

A

photosynthesis, respiration, chemistry, radioactivity

94
Q

t

describes HOW FAST we can expect gases to move between atmosphere and seawater under specific conditions

A

kinetics perspective

95
Q

t

explain what flux is

A

net number moving through a unit area of sea surface per unit time

96
Q

t

what is the flux equation

A

flux = gas exchange coeffecient (equilibrium - observed)

97
Q

t

if equilibrium concentration > observed concentration

A

undersaturated into sea

98
Q

t

concentration at equilibrium = concentration observed

A

saturated, nothing

99
Q

t

concentration at equilibrium < concetration observed

A

oversaturated into air

100
Q

t

gas flux primarily limited by diffusion through thin film of stagnant seawater at interface

A

stagnant film model

101
Q

t

what is the equation for the gas exchange coefficient

A

k = diffusion coeffecient / thickness of stagnant film

102
Q

t

thicker the film the ______ the gas change coefficient

A

slower

103
Q

t

what are the 3 realistic gas exchange is also influenced by

A

winds/turbulance
bubble injection
spatial and temporal variability

104
Q

t

higher wind speeds means a ______ gas exchange

A

higher

105
Q

t

breaking waves can cause ____ ______

A

bubble injection

106
Q

t

synthesis of organic matter from inorganic substances and energy by organisms

A

primary production

107
Q

t

elements in specific forms that sometimes limit primary production

A

nutrient

108
Q

t

what are the two forms of nutrients in the redfield organic matter equation

A

no3- po4 3-

109
Q

t

Not a molecule, average element ratios in planktonic organic matter

A

redfield organic matter

110
Q

t

what are the ratios in redfield organic matter

A

106CO2 16HNO3 1PO4 -> 138 oxygen

111
Q

t

takes in oxygen and creates co2

A

aerobic respiration

112
Q

t

RATE of organic matter synthesis from inorganic materials by organism per area unit volume

A

primary productivity

113
Q

t

production - respiration

A

net primary productivity

114
Q

t

sunlit surface layer extending to a depth where 1% of insolation remains unabsorbed

A

euphotic zone

115
Q

t

what do nutrient type profiles look like

A

concentration low near the surface, increases to nearly uniform concentration with depth

116
Q

t

what is an example of a low productivity zone

A

central gyres (oligotrophic)

117
Q

t

what is an example of a high productivity zone

A

equatorial zones, coastal regions

118
Q

t

why are there areas that have high nutrients and low chlorophyll regions?

A

nitrate and phosphate are not the only nutrients that can be limiting, iron can be limiting as well as light

119
Q

t

what two factors control the geographic distribution of nutrients

A

physical transport, in situ sources and sinks(formed where found)

120
Q

t

______ _____ does not limit primary productivity

A

carbon dioxide

121
Q

t

carbon dioxide hydrates to form _______ _____, then dissociates to make carbonates

A

carbonic acid

122
Q

t

is carbonic acid organic or inorganic

A

inorganic

123
Q

t

how big is dissolved organic matter

A

<1um

124
Q

t

how big is particulate organic matter

A

> 1um

125
Q

t

for spherical particles sinking in a calm ocean, an analogous settling velocity can be estimated using _____ ______

A

stokes law

126
Q

t

what do you have to assume for stokes law

A

all sinking particles are spherical and sinking in a calm ocean

127
Q

t

what are the parts of stokes law

A

acceleration due to gravity, density difference between particle and water, radius^2, fluid viscosity, 2/9

128
Q

t

density of the particle is greater than water then

A

sink

129
Q

t

if density of particle is less than fluid it will

A

float

130
Q

t

stokes law and how fast a particle sinks is very sensitive to _______

A

size

131
Q

t

dissolved organic matter gets to the bottom of the ocean via ______

A

currents

132
Q

t

organic material produced with nutrients recycled from respiration

A

regenerated production

133
Q

t

organic matter from “new” nutrients delivered to euphotic zone from atmosphere, land, or from mixing w deeper waters

A

new production

134
Q

t

production that is exported from surface to the deep ocean

A

export production

135
Q

t

where is the oldest water located

A

pacific ocean

136
Q

t

the pattern of DOC in the deep ocean primarily results from

A

long transit times from the sources, chemical recalcitrance (slow minerization along the way)

137
Q

t

~96% of all organic carbon atoms in seawater are _________

A

recalcitrant

138
Q

t

____ abundances tell us ages and sources of carbon

A

c14

139
Q

t

explain the same 3 steps of the biological pump

A

1 net primary production in euphotic zone
2 densely packaged organic particles sink
3 co2 and nutrients regenerates by respiration of OM

140
Q

t

productions of respiration are ________, they no longer sink through water, but must move _____ water

A

dissolved with

141
Q

t

DIC and nutrients accumulate, ____ diminishes along the deep conveyor belt

A

oxygen

142
Q

t

what ocean has the least amount of oxygen

A

pacific

143
Q

t

where is the highest amount of DIC accumulation

A

pacific

144
Q

t

where is the highest amount of NO3 accumulation

A

pacific

145
Q

t

where is the highest amount of H3PO4

A

pacific

146
Q

t

why are there the most nutrients in the pacific ocean, HNO3 H3PO4

A

more respiration over time

147
Q

t

what is the apparent oxygen utilization formula

A

aou = conentration at equilibtrium - oxygen oserved

148
Q

t

what must we assume when using the apparent oxygen utilization equation

A
  1. water mass had attained gaseous equilibrium with the atmosphere
  2. the partial pressure of oxygen in the atmosphere has not changes since the water mass was last at the sea surface
  3. neither have in situ temperature and salinity
149
Q

t

the highest AOU or consumption is found in what ocean?

A

pacific

150
Q

t

_____ carries that unused “performed” amount to depth; respiration adds to it

A

downwelling

151
Q

t

what are the assumptions about the performed nutrient equation

A
  1. total concentration = performed + respired concentratin
  2. nutrients accumulate with redfield stoichiometry
  3. all aou assumptions
152
Q

t

what is the equation for finding performed nutrients

A

performed = observed - AOU/138

153
Q

t

the amount of material contained in a defined physical regime such as in the atmosphere, the surface ocean or sediment, (how many people are in the room- variable size)

A

reservoir

154
Q

t

the amount of material transported from one reservoir to another through unit area in per unit time

A

flux

155
Q

t

input of material into a reservoir (water going into the system)

A

source

156
Q

t

output of material out of a reservoir

A

sink

157
Q

t

a balance of sources and sinks for a given reservoir

A

budget

158
Q

t

the ratio of the size of a reservour divided by the total sources or sinks (sum of sources or sum of sinks)

A

residence time

159
Q

t

material is tranfered between various reservoirs following closed circuits

A

cycle

160
Q

t

when the sources = sinks and the reservoir does not change

A

steady state

161
Q

t

when mass and or energy exchanges with outside the system

A

open system

162
Q

t

when mass and or energy cannot exchange with outside the system, but cycle within the system (the earth is one to matter)

A

closed system

163
Q

t

define the limits of a system

A

boundaries

164
Q

t

characterized by exchange of mass and or energy with surroundings (accross the boundary)

A

system

165
Q

t

earth is _____ with respect to matter, _____ with respect to energy

A

closed open

166
Q

t

fluxes: amount added (Sources) or removed from (sinks) the reservoir in a given period of time is _______

A

steady

167
Q

t

what if the system is not in a steady state? and what if the budget is not balanced? or missing sources and sinks? the reservoir could ______ ___ ______

A

accumulate or dissipate

168
Q

t

nutrients have a _____ residence time at the surface then something like Cl which is abundant, mixing is dominant

A

shorter

169
Q

t

simple box model equation

A

rate of change of reservoir = sources - sinks

170
Q

t

what are the two main processes in ocean carbon cycle?

A

photosynthesis, respiration

171
Q

t

what are the main cabin reservoirs in the ocean

A

inorganic carbon, organic carbon

172
Q

t

what are the two forms of inorganic carbon

A

DIC and PIC

173
Q

t

what are the two types of organic carbon

A

POC and DOC

174
Q

t

Co2 fluxes are controlled by

A

temperature, wind speed, sea surface roughness, local biological production

175
Q

t

what are the 3 sources inot the surface ocean

A

atmosphere, deep sea, marine biota

176
Q

t

what happens in denitrification

A

NO3 to N2

177
Q

t

what happens in nitrification

A

NH4+ to NO3-

178
Q

t

what happens in Nitrogen reduction

A

NO3- to NH4+

179
Q

t

what happens in nitrogen fixation

A

N2 to Organic Nitrogen

180
Q

t

NH4+ to NH2OH to NO2- to No3-

A

nitrification

181
Q

t

NO3- to NO2- to NO to N2O to N2

A

denitrification

182
Q

t

nitrate is highest in the pacific ocean

A

pacific