ES1001 Flashcards

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1
Q

What is Earth’s geographical column?

A

om locality to locality around the world, geologists have pieced together a composite stratigraphic column that represents the entirety of Earth’s visible history

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2
Q

Relative vs. numerical age:

A

The age of one feature relative to another is known as its RELATIVE AGE. The age of a feature given in years is its NUMERICAL AGE

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3
Q

What is radioactive decay?

A

When isotopes undergo a conversion into a different element (Bonus point: In half life)

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4
Q

What is Geochronology?

A

We investigate the what, when, and how of planetary-scale of a process

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5
Q

What is a seismic wave?

A

Rupture of intact rock or frictional slip along a fault produces seismic waves (and earthquakes), these move outward in all directions

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6
Q

What density of rock will make p-waves travel at an increased velocity?

A

Denser rock, such as igneous
(Example: peridotite vs sandstone)

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7
Q

Do seismic waves travel faster or slower in solids? In comparison to liquids

A

They travel faster through solids

(Example: they move more slowly in liquid than solid rock)

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8
Q

Can s-waves go through liquid?

A

both P- and S-waves can travel through solids but only P-waves can travel through liquid

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9
Q

When do seismic waves refract?

A

Seismic energy as waves will reflect and/or refract when reaching the interface between two layers of rock of differing compositions and/or densities

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10
Q

Define a rock
(Like no seriously…)

A

A naturally occurring and consolidated material usually comprised of one or more mineral phases

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11
Q

What rock type is igneous

A

Something which directly crystallised form a liquid rock (melt)

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12
Q

What rock type is sedimentary

A

Bits of other rocks in one place

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13
Q

What rock type is metamorphic

A

Cooked rocks

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14
Q

Why do sedimentary rocks form at or near the Earth’s surface?

A

Cementation of grains and/or fragments derived from pre-existing rocks

Precipitation of minerals from water solutions

Growth of skeletal material in organisms

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15
Q

What is weathering

A

The processes that break up and corrode solid rock, eventually transforming it into sediment

Physical weathering breaks rocks into unconnected grains or chunks

Chemical weathering refers to the chemical reactions that alter or destroy minerals when rock comes into contact with water solutions or air

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16
Q

Fun fact!!
(Lemme have fun jeez… flip!!)

A

Sedimentary Rocks are sometimes made of dead things

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17
Q

How are metamorphic rocks formed?

A

A rock that forms when a pre-existing rock (igneous or sedimentary) is affected by changes in its physical or chemical environment

include variations in temperature (T) and pressure (P), these changes result in the growth of new minerals and textures

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18
Q

What is ‘plate tectonics’

A

The lithosphere is divided into 15-20 plates of varying sizes

The plates move relative to each other

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19
Q

Explain a ‘hot spot’

A

Isolated volcanic centres far away from plate boundaries, many lie at the end of a chain of extinct volcanic islands and seamounts known as a hotspot track

hot spot tracks are thought to be the result of plates moving over stationary plumes

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20
Q

Why do we study minerals?

A

They make up everything, the majority of Earth, any rock is an aggregate of two or more mineral grains.

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21
Q

Definition of a mineral

Aka the web of lies

A

A mineral is a crystalline, homogenous, inorganic solid with a defined chemical composition that occurs naturally

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22
Q

Explain the minerals crystal structure

A

Their building blocks (atoms, ions, molecules) are arranged in an ordered and repeated pattern.

The unit cell is the smallest unit that still has the full symmetry of the crystal structure of a material.

Repeating the unit cell over and over again forms a crystal.

The ordered atomic network within a crystal can be simple or fairly complex.

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23
Q

What is a mineraloid?

A

Some minerals are not (fully) crystalline. These are called mineraloids.

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24
Q

Explain why crystals SHOULD be homogenous

A

Following from the infinitely repeatable unit cell of the crystal structure, minerals should by definition be homogenous

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25
Q

What may be the cause of a non homogenous mineral?

A

Zonations and crystal defects

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26
Q

What are the examples of an organic ‘mineral’

A

Biominerals - formed by a living organism usually inorganic in composition may contain organic material

Amber - fossilised tree resin organic composition

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27
Q

What is a polymorph?

A

Minerals with the same composition but different crystal structure

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28
Q

What is coordination?

A

The number of direct neighbours that an atom/ion is bonded to in a crystal structure.

Typically we talk about cations and their surrounding anion-neighbours.

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29
Q

What is coordination?

A

the number of direct neighbours that an atom/ion is bonded to in a crystal structure.

Typically we talk about cations and their surrounding anion-neighbours.

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30
Q

What is a site?

A

A space in a crystal lattice that can be occupied by an atom/ion. It is typically named by its coordination.

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31
Q

What is compatibility?

A

Atoms/ions in a crystal lattice can be substituted by other elements, as long as their radius is similar.

Ideally, their charge would also be the same! If an element fits readily into a crystal structure, it is called compatible

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32
Q

Nesosilicates

A

Island silicates

Consist of isolated “islands” of [SiO4] 4– tetrahedrons.

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33
Q

Sorosilicates

A

Group silicates

Two SiO4-tetrahedrons can share one oxygen and form a group

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34
Q

Cyclosilicates

A

Ring silicates

When a SiO4-tetrahedron shares two of its oxygen corners, we can form rings

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35
Q

Inosilicates

A

Chain silicates

Like an unclosed ring, sharing two oxygen corners creates chains

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36
Q

Phyllosilicates

A

Sheet silicates

Sheets of Inosilicates

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37
Q

Tectosilicates

A

Framework silicates

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38
Q

What is ‘plate tectonics’?

A

The lithosphere is divided into 15-20 plates of varying sizes
The plates move relative to each other

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39
Q

Hot Spots?

A

Isolated volcanic centres far away from plate boundaries

Many lie at the end of a chain of extinct volcanic islands and seamounts known as a HOT SPOT TRACK

Hot spot tracks are thought to be the result of plates moving over stationary plumes

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40
Q

Defniton of a mineral?

A

A mineral is a crystalline, homogenous,
inorganic solid with a defined chemical
composition that occurs naturally

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41
Q

How d minerals have a crystalline structure?

A

Their building blocks (atoms, ions, molecules) are
arranged in an ordered and repeated pattern.

Aka repeating he UNIT CELL

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42
Q

What a a mineral which isnt fully crystalline?

A

Mineraloid

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43
Q

What is a polymorh?

A

Polymorphs are minerals with the same
composition but different crystal structure.

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44
Q

How do minerals form

A

crystallisation of a magma due to cooling effectively the same as freezing

Magma cools below its liquidus, and starts to crystallise minerals.

The mix of melt + minerals keeps on crystallising until it ”hits” the solidus, now all melt has solidified

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45
Q
  1. Elements
A

Pure elements, metals often called “native”…

usually bound by metallic (in metals) or covalent bonds

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46
Q
  1. Sulphides
A

Minerals that have sulphur as anion.

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47
Q
  1. Halides
A

Minerals with halogens (F, Cl, Br, I) as anion.

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48
Q
  1. Oxides/ Hydroxides
A

Minerals with oxygen and/or OH as anion.

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49
Q
  1. Carbonates
A

… with the carbonate ion (CO3) 2- as anion.

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50
Q
  1. Borates
A

… with the borate ion (BO3) as anion.

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51
Q
  1. Sulphates
A

with the sulphate ion (SO4) 2- as anion.

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52
Q
  1. Phosphates
A

… with the phosphate ion (PO4)
3- as anion.

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53
Q
  1. Silicates
A

Form 90% of Earths crust

Si and O as anions

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54
Q

Building silicates

A

SiO4 tetrahedredreon

1 Si with 4 O- atoms
Si4+ (+) 4o^2- makes [siO4]4^4-

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55
Q

Neosilicates - Island silicates

A

consist of isolated “islands” of [SiO4]4– tetrahedrons.

Since a mineral cannot be charged, we have to balance the quadruply-negative charge.

A charge balance can be achieved by throwing cations in the mix.

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56
Q

nesosilicates - island silicates EXAMPLE

A

Olivine

achieves charge balance by adding two divalent cations per [SiO4]4– island.
It can be either Mg2+ or Fe2+
→ (Mg,Fe)2SiO4

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57
Q

Sorosilicaties - group silicates

A

Two SiO4-tetrahedrons can share one
oxygen and form a group:
2 Si4+ + 7 O2- makes [Si2O7]6-

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58
Q

Sorosilicates-group silicates EXAMPLES

A

Zoisite

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59
Q

Cyclosilicates - ring silicates

A

When a SiO4-tetrahedron shares two of its oxygen corners, we can form rings

Depending on the number of rings, we get different molecular anions, with different charges…

But always a multiple of Si4+ + 3 O2- → [SiO3]2-

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60
Q

Cyclosilicates - ring silicates EXAMPLES

A

Tourmaline, Beryl

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61
Q

Inoslicates - chain silicates

A

Like an unclosed ring,
sharing two oxygen corners creates chains
2 Si4+ + 6 O2- → [Si2O6]4-

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62
Q

Inosiliictes - chain silcates EXAMPLES

A

Pyroxenes
have two slightly different cation-sites in their lattice
M2 (larger cation site)

M1 (smaller cation site)

e.g. Augite

Amphiboles … are complicated and have a lot of cation-sites, but are a common mineral

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63
Q

phyllosilicates - sheet silicates

A

Every SiO4-tetrahedron shares three of its corner oxygens
Si4+ + 1O2- + 3*½O2- = SiO2.5 = [Si4O10]4-

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64
Q

phyllosilicates - sheet silicates EXAMPLES

A

Micas

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65
Q

Tectosilicates
- framework silicates

A

Every SiO4-tetrahedron shares all four of its corner oxygens
Si4+ + 4*½O2- = SiO2 = [SiO2]0 - No charge!

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66
Q

Tectosilicates
- framework silicates EXAMPLES

A

Quartz
is a very happy chappy,
doesn’t need any cations
to charge balance and
therefore usually is very pure.
Formula: SiO2

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67
Q

Composition of a mineral

A

Heavy element = heavy mineral (duh)

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68
Q

Packing

A

More atoms = more dense

Like more socks = more dense suitcase

Relative estimates

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69
Q

Colour

A

colour as a result of interaction with (sun)light

(Sunlight = white light
contains all wavelengths of the visible spectrum)

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70
Q

Colour WARNING!

A

Small changes in a crystal
can change the way it interacts with light.

(e.g amethyst, quartz, citrine)

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71
Q

Streak colour?

A

We can powder” a mineral by grinding it
against a hard and
rough surface, like an
unglazed ceramic tile.

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72
Q

Transparency

A

Describes whether a material allows light
to pass through.

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73
Q

Lustre

A

How a mineral reflects

Just make up your own words

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74
Q

Twinning

A

Twinning describes the intergrowth of two
(or more) crystals of the same mineral
through a slight change in orientation of
the crystal lattice.

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75
Q

Double refraction

A

Technically the majority of transparent and translucent
minerals double-refract light;

CALCITE is so very slay that u can see double

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76
Q

Photo - Luminescence

A

In some minerals, absorbing (high-energy) light results in the emission of (visible) light.

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77
Q

Fluorescence

A

The light emission stops when the
high-energy light stops

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78
Q

Phosphorescence

A

The light emission can continue for some time after the excitation stops

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79
Q

Magmatism

A

Magnetite is magnetic

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80
Q

Taste

A

Salty stuffs

Halite tastes salty.
It is table salt after all.

Sylvite tastes salty, too,
but has a bitter aftertaste.

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81
Q

7 crystal system SHAPES
(teigan terms dw)

A

Cube
Chip
Matchbox
Pencil
Triangular prism
Flattened matchbox sidey-ways
Stack of cards pushed askew in two directions

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82
Q

7 crystal TERMONOLOGY

A

cubic
tetragonal
orthorhombic
hexagonal
trigonal
monoclinic

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83
Q

What is metamorphism

A

The mineralogical and
structural adjustment of solid rocks to physical
and chemical conditions that have been
imposed at depths below the near surface zones
of weathering and which differ from conditions
under which the rocks in question originated.

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84
Q

What are the key factors of metamorphism

A

The precursor rock
Pressure
Temp
Deformation

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85
Q

Where does the heatcome from within metamorphism

A

Conduction (mantel)
Advection (magma/hot fluid)
Radioactive decay ( U, Th, K etc)

Temps of 250 to >1000°C

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86
Q

Where does pressure come from with metamorphism

A

Overlying rock mass
Horizontal tectonic forces

Pressure= fore per unit
Lithostatic pressure = density x gravity x height

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87
Q

Why do newminerals grow?

A

More stable at better conditions
Determined by thermodynamics

Thus, thermodynamics determines which collection of minerals have thelowest energy for a particular rock composition, pressure and temp

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88
Q

Regional metamorphism

A

Due to burial
Occurs with deformation
Occurs over large areas

Called belts
Shows continental collision (therefore mountain ranges)
Occurs formulations to 10s of millions of years

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89
Q

Contact deformation

A

Localised heat sources
Occurs around large igneous intrusions (dominated by heating n cooling)
Occurs oversmaller areas

Area around the intrusion is called the contact aureole

Short-lived

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90
Q

Hydrothermal metamorphism

A

Ocean floor basalts interact with hot fluids
The basalt is metamorphosed

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91
Q

Impact metamorphism

A

This occurs when you drop a huge rock from space (meteorite) onto the earth.
¨ Enormous transient pressure and temperature changes
¨ Very short lived - seconds-days
¨ Also called shock metamorphism
¨ Pressure from the impact (force per unit area)
¨ Temperature from friction

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92
Q

Fault related metamorphism

A

Related to brittle or ductile deformation in faults and shear-zones
Intense deformation allows new minerals to grow
¨ Sometimes friction can provide additional heat
Commonly associated with hydrothermal metamorphism

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93
Q

Metamorphic rocks are classified in general on their
appearance
¨ This is controlled by:

A

Composition
P and T conditions
Deformation

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94
Q

Features of metamorphic rocks!
Inherited features

A

Eg bedding in metamorphosed sediments
Eg large igneous crystals from metamorphosed
igneous rocks

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95
Q

Features of metamorphic rocks!
Metamorphic features

A

Minerals of different sizes

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96
Q

Features of metamorphic rocks!
Metamorphic and deformation features

A

Distinct layers
Aligned grains (preferred orientation)
Folds

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97
Q

Metamorphic fabric and structure

A

Layering
Alternating layers of different compositions
May include inherited features such as bedding

Foliation
A planar feature in a rock defined by the preferential
orientation of mineral grains

Lineation
A linear feature in a rock defined by the preferential
orientation of mineral grains

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98
Q

Crenulations

A

Small scale folds

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99
Q

Porphyroblasts

A

Metamorphic rocks may have some garians that
are much bigger than the average grain size

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100
Q

Porphyroclasts

A

In FAULT related rocks they are metamorphic rocks may have some garians that are much bigger than the average grain size

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101
Q

Phenocrysts

A

The big grains in igneous rocks

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102
Q

Matrix

A

The finer-grained minerals that host the
porphyroblasts are collectively referred to as
“matrix”

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103
Q

Matrix minerals

A

Individual minerals are called “matrix minerals”

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104
Q

Using structure no foliation

A

No foliation
¨ Hornfels
¨ Granofels

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105
Q

Using structure with foliation/lineation

A

Foliation/lineation
¨ Slate
¨ Phyllite
¨ Schist
¨ Gniess
¨ Layered or banded gneiss & Migmatite

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106
Q

Using structure- intensely foliated

A

Intensely foliated and sheared rocks
¨ Mylonite

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107
Q

What is a metamorphic assemblages

A

Is those minerals that appear to co-exist stably in a rock
¨ i.e it is a list of minerals

AKA Christmas rock
Garnet-clinopyroxene(omphacite)-quartz

Metamorphic assemblages are important for constraining metamorphic grade (Pressure & Temperature)

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108
Q

What is a metamorphic facies

A

any two rocks with the same chemical
composition that are metamorphosed at the same P-T conditions will contain the same minerals in the same proportion

¨ This is governed by thermodynamics
¨ We can use common rock types to define broad P-T regions based on the mineral assemblage they contain

These broad P-T regions are called metamorphic facies

Metamorphic facies can also be determined using other
rock types such as metapelites

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109
Q

What are the 5 main metamorphic facies

A

¨ Greenschist facies
¨ Amphibolite facies
¨ Granulite facies
¨ Blueschist facies
¨ Eclogite facies

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110
Q

What is metamorphic evolution

A

As metamorphic rocks occur at the surface today, they
must also experience a period of cooling after
metamorphism

¨ We can divide the metamorphic evolution into parts based on whether T is increasing or decreasing

T increasing prograde
T highest peak
T decreasing retrograde

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111
Q

P-T pathways

A

The tall, elongated, clockwise path is characterised by deep burial and exhumation with limited heating

The shorter, rounder clockwise red path is represents both substantial burial and heating

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112
Q

What is a metamorphic zone (zonen)

A

In contact metamorphism there is a strong temperature gradient away from the intrusion
¨ This results in changes in mineral assemblages away from the intrusion

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113
Q

What is a metamorphic isograd?

A

Some regional metamorphic belts show a consistent change in minerals across them.
¨ The appearance of a key mineral can be mapped in as an isograd.

Each metamorphic zone is separatrated by an isograd

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114
Q

Whatis continental collision in metamorphism

A

The most important metamorphic environment

If metamorphism occurs when continental plates collide then ancient
metamorphic belts show us how and when the continents were assembled into their current configuration

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115
Q

Ocean subduction I metamorphism

A

If metamorphism occurs in subduction zone then some metamorphic belt tell us where old subduction zones were

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116
Q

Metamorphic - Diverent plate boundaries

A

Plates move apart
¨ This is where new oceans form if the process continues

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117
Q

Metamorphic - transform plate boundaries

A

Plates slide laterally
¨ May involve a component of extension (transtension) or compression (transpression)

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118
Q

Metamorphic- convergentplate boundaries

A

Plates collide
¨ If one or both of the plates is oceanic then subduction occurs
¨ If both are continental then continental collision occurs

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119
Q

Orogenesis

A

Building mountains

Mountains represent crust/lithosphere that has been thickened
¨ Sometimes to more than double its normal thickness
¨ Thickened crust is not stable, but occurs because of tectonic forces

Mountains are controlled by isostacy (the iceberg effect)
¨ The higher the mountain the thicker the crust/lithosphere

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120
Q

Examples of continental collision

A

Alps and himalayas

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121
Q

Regional metamorphism - With regards to subduction

A

Here we have subduction causing continental collision.
There is defm & thickening due to the applied stresses

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122
Q

Subduction zones and island arcs

A

Two types

Ocean-ocean
¨ Makes island arcs
¨ Eg Japan

Ocean-continent
¨ Makes continental volcanic arcs and mountains on the continental margins
¨ Eg the Andes

These may evolve into collision zones

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123
Q

Subduction metamorphism

A

Subduction involves high pressures. SO the rocks formed in subduction zones are blueschists and eclogites

During burial and heating the rock experiences prograde metamorphism. The prograde reactions release water which enters the hot mantle.

This water can initiate melting of the mantle: also melting of the slab
can occur

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124
Q

Metamorphic - volcanic arcs

A

The large input of magma heats and thickens the arc crust

Arcs are very hot environments
Get high T at relatively shallow depths

Very high temperatures common in the lower half of arc systems
High temperature-low pressure metamorphism due to magmatic heat

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125
Q

Explain the biosphere structure

A

Living organisms (biota) and non-living (abiotic) factors from
which they derive energy and nutrients

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126
Q

What are the two Geobiological energy sources?

A

Phototrophy and Chemotrophy

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127
Q

What is an autotroph

A

Primary Producers: build organic matter by fixing carbon
Provide most organic carbon for the biosphere
Cyanobacteria

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128
Q

What is a Heterotrophs

A

Cannot fix carbon to form their own organic compounds.
Consumes organic compounds/primary producers

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129
Q

Energy flow in ecosystems

A

The biosphere is an open system with regards to energy
→ energy flow upwards in a food pyramid is inefficient, and relies on
continued primary production

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130
Q

What is the residence time? (Equation)

A

Mass of substance
————————– = residence time (10^12kg/year = GtC) of carbon
Flux (in or out of)

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131
Q

What is a feedback?

A

A feedback is a self-perpetuating mechanism of chang

132
Q

What is negative feedback?

A

diminishes disequilibrium to maintain a steady state

133
Q

What is positive feedback

A

enhances the effects of perturbation and drives the
system further from equilibrium.

134
Q

Organic stored carbon

A

Terrestrial: Coal (land plants in anoxic swamps)
Marine: Petroleum in shales (phytoplankton debris)

135
Q

Inorganic stored carbon

A

Carbonates; limestone, aragonite, chalk etc

136
Q

What is geobiological weathering

A

Bicarbonate produced by weathering of both carbonates and silicates

137
Q

The Archean (Geobiology)

A

Single cellular life; chemotrophs and/or non photosynthetic phototrophs

Stromatolites: oldest unambiguous fossils at 3.4 Ga. Microbial mats formed of cyanobacteria (modern examples) and interleaved sediments.

138
Q

The Proterozoic (Geobiology)

A

True multicellularity has only ever arisen among the eukaryotes

Results in:
• Specialised cells
• Increase in size
• Increased morphological diversity
• Sexual reproduction

139
Q

Whatis biomineralisation

A

Largely calcium carbonate plus silica and phosphate
Likely as a response to predation→ modern food webs

140
Q

What waste Cambrian Explosion

A

Rapid diversification in body plans, particularly Bilatera
• Divergence of nearly all extant phyla
• Expansion in mode of life: burrowing, active swimming, pelagic

141
Q

Mesozoic Life (Geobiology)

A

Rapid diversification after the P-T mass extinction
Rise and dominance of the dinosaurs! + grass + flowering plants

142
Q

Cenozoic life

A

Loss of dinosaurs following the K-T mass extinction
Rapid diversification and dominance of mammals

143
Q

The end-Permian “P-T” mass extinction

A

Largest know mass extinction: occurred in two
waves at ~252 Ma
~90 % of marine species and ~70 % of terrestrial
vertebrates lost

Siberian Traps: giant volcanic eruption coincident with the P-T extinction
Dust, volcanic gases (SO2; CO2), intruded into coals → Global Warming

Ocean acidification, enhanced weathering and eutrophication-induced “super”anoxia

144
Q

The end-Cretaceous (“K-T”) mass extinction

A

Impact at Chicxulub: resulted in 180 km diameter crater.
Iridium (+other PGE) spike, shocked quartz, glassy beads (ejecta spherules)
Impacted anhydrite or gypsum → massive sulphur release

145
Q

Glaciation for energy resources

A

Hydroelectric power from glacially fed catchments is a major source of energy
in some regions
British Columbia, Canada: >85% of electricity from hydropower, and in
summer 50% of water supplied by glaciers

146
Q

What is an ice sheet

A

Largest masses of ice, covering huge countries or continents such as Antarctica and Greenland
Characterised by a slow-moving interior plateau and fast-moving edges forming outlet glaciers or ice
streams

1-3km thick! Melting would cause 70 m of sea level rise

147
Q

What is an ice shelf

A

Large areas of floating ice in embayments or along the margins of an ocean basin, fed by ice streams
from a neighbouring ice sheet e.g., Antarctic margin

148
Q

What is the cryrosphere

A

Its the frozen part of Earth and the most susceptible to
anthropogenic climate change
• Important for controlling global sea level

149
Q

Whatis an ice cap

A

Smaller accumulations of ice covering high topography or high latitude regions, characterised by radial
flow outwards from the centre

150
Q

What is sea ice?

A

Freezing of sea water at high latitudes
Sea ice extent has been declining in recent decades due to climate change

151
Q

What is permafrost?

A

Freeze-thaw activity within the upper “active layer” produces patterned ground structures such as icewedge
polygons and pingos

152
Q

What is patterned ground?

A

regular pattern of circles / polygons formed in active layer due to cyclical freezing and thawing of water in the pore spaces and frost heaving

153
Q

Whatis a pingo?

A

Small hills of earthcoveredice that form by expansion of pore water through the active layer as a result of pressure from expanding permafrost underneath

154
Q

What is a cirque (corrie) glacier

A

smallest – found in cirque (bowlshaped depression on side of mountain formed by glacial erosion)

155
Q

What is a valley glacier?

A

A cirque glacier that expands outward and downward into a valley

156
Q

Whatis a fjord glacier?

A

When a glacier valley is partly filled by an arm of the sea, the valley is called a fjord, and the glacier is a fjord glacier

Bits fall off to cause icebergs

157
Q

What’s a piedmont glacier

A

Forms when valley glacier spreads out onto lowlands

158
Q

Formation of sea ice

A

• Air temperature falls below freezing point of salt water

• Consists of freshwater as salt is excluded from ice crystals as they form

• First ice to form consists of small crystalline needles: frazil ice (pure H2O)

• As more crystals form they produce a viscous mixture at the ocean surface, eventually freezing together to make continuous ice cover

• Cold air no longer in contact with seawater and so sea-ice growth then proceeds by addition of ice to base

• Melting, sublimation removes ice from surface

• But loss at surface compensated by ice crystals added to the base

159
Q

Sea ice Zonations
Perennial sea ice:

A

The sea ice that persists for multiple years

• In Arctic, just north of Resolute Bay: can be 3-4 m thick and
decades old
• In Antarctic, confined to semi-enclosed seas (Ross, Weddell): can
be 5 m thick, but <5 yr old

160
Q

Sea Ice Zonations
Seasonal sea ice

A

sea ice cover that varies annually

• Cause of variation in extent varies between Arctic and Antarctic
• Arctic: warmer air temperatures is major factor in retreat of the ice margin
• Antarctic: warmer ocean temperatures is major factor in
retreat of the ice margin

161
Q

Glacier formation - from snow to ice

A

Compaction by overlying snow
• Air penetrates pore space and evaporation occurs at points of snowflakes
• Moisture freezes between points, near center
• Formation of granular snow called FIRN, intermediate stage between snow and glacial ice
• Snow gradually loses interstitial air to become glacier ice

162
Q

Glaciers brittle upper layer

A

Top 50 m of glacier is brittle –does not flow because has relatively little weight on it

• Crevasses form in top layer as glacier bends over topography (e.g., an abrupt change in slope)

• Provide a conduit for meltwater from surface to get to depth in glacier through englacial channels

• Meltwater can also percolate through firn layer

163
Q

Glacier surges

A

Some glaciers undergo periodic surges – rapid advances
• Several kilometres per year
• May be related to buildup of water at base

164
Q

Glacial erosion

A

Mechanisms:
• freeze-thaw at base of glacier
• abrasion
• plucking

165
Q

The oceans general knowledge

A

Cover 70.8% of the Earth’s surface,
Contains 97% of the Earth’s water,
Have an average depth of 3.6 km.

166
Q

Oceanic crust

A

Oceanic crust is denser than continental crust,

The light thick continental crust floats higher on the mantle than the dense thin oceanic crust

167
Q

Ocean lectures - spreading and subduction

A

Sea floor spreading creates mid-ocean ridges
Subduction creates deep ocean trenches

168
Q

What pattern is seen within nutrients in the oceans

A

Dissolved nutrients to support primary production are low in surface waters and
then regenerated at depth.

169
Q

Impacts of ocean stratification

A

inhibits the vertical mixing of ocean waters, preventing dissolved nutrients being transported back to the sea surface.

170
Q

Effect of mixing within the ocean

A

Storm mixing and tidal mixing in shelf seas breaks down seasonal stratification

171
Q

How are ocean basin formed?

A

Plate tectonics

172
Q

How are continental slopesare shelfs produced

A

Water overfills the basins and spills onto the continental crust

173
Q

How are shelf seas important in oceanic environments

A

Shelf seas are important for primary production and
carbon storage

174
Q

What can affect ocean circulation

A

Ocean features (seamounts, islands, plateau, trenchs)

175
Q

What is Eckman Transport?

A

Eckman Transport is the deflection of surface waters in the upper 100m of the water column, as a result of the Coriolis Effect.

Surface waters are deflected 90° to the right in the northern hemisphere and 90° to the left in the southern hemisphere.

176
Q

What is Grye circulation

A

Winds create drag on the surface waters, setting them in motion

The Coriolis effect deflects surface waters to the right in the Northern hemisphere, so oceanic gyres rotate in a clockwise direction. The opposite occurs in the Southern hemisphere.

177
Q

The density of surface seawater is sufficient to cause sinking at two general locations:

A

The North Atlantic
The Weddel Sea (Southern Ocean)

Together, temperature and salinity drive the thermohaline circulation of the oceans

178
Q

How can we detect water masses?

A

Depth profiles of temperature and salinity

179
Q

What can drive surface currents?

A

Wind

180
Q

Whare does the Coriolis Effect divert current

A

To the right in the N Hemisphere and the left in the S Hemisphere

181
Q

How do deep ocean waters form?

A

From high density waters

182
Q

Wind generated gravity waves:

A

Wind stress creates small ripples in the water’s surface. Now there is a pressure difference between the front and back of the wave.

The front face is sheltered from the wind and experiences a lower air pressure than the back face, which faces the wind. This pressure difference pushes the wave along.

183
Q

Importance of waves

A

Water mixing (e.g. shelf sea stratificationSustainable energy sourceShipping hazardErosion/deposition of sedimentsSea level changes

184
Q

What is an amphidromic point?

A

Points with no tide

185
Q

What is a Guyot?

A

A flat topped volcanic mountain

186
Q

What is a Seamount?

A

Underwater mountain (usually volcanic)

187
Q

Implications of sea level change

A

Changes in shelf sea area affect primary production, ecosystem distribution, carbon transport etc.

Changes in sea level affect tidal dynamics in shelf seas and the global ocean

188
Q

What is tidal dissipation

A

The loss of the energy of tidal i.e. moon generated, waves

189
Q

How can we reconstruct sea level?

A

Using the and age of fossil coral reefs

190
Q

What are the common marine pollution issues

A

Metals
Organic chemicals
Oil
Contaminants of emerging concern
Nutrients
Plastic

Noise

191
Q

How are PBCs in the Marianas trench?

A

These PCBS are probably incorporated into particulate material at the ocean surface which then sinks to the ocean bottom to deliver the contaminant.

192
Q

What is a Roche Moutonnee

A

Rock formation created by the passing of a glacier.

The passage of glacier ice over underlying bedrock often results in asymmetric erosional forms as a result of abrasion on the “stoss” (upstream) side of the rock and plucking on the “lee” (downstream) side

193
Q

Erosional Glacial features
Striations and chatter marks

A

Striations: Produced by small rock fragments embedded in basal ice that scrape away at the underlying bedrock and produce long parallel scratch marks

Chatter marks: A series of often crescent-shaped gauges chipped out of the bedrock as a glacier drags rock fragments underneath it

194
Q

Corries!!

A

Among the most common and distinctive landforms
produced by glacial erosion

Bowl-shaped valley formed at glacier head

Coire Sgorach on Sgurr a’ Mhaim is a classic northfacingcorrie eroded by a small cirque glacier high on the mountain face during successive glaciations of Scotland

195
Q

U shaped valleys

A

Originates in a corrie, U-shaped (duh)
Higher geo

196
Q

Aretes

A

Sharp-edged, narrow ridge of rock separating two valleys

Formed when two oppositefacing glacial cirques erode headwards towards each other

Also formed when two valley glaciers erode parallel Ushaped valleys

Edge is sharpened by freezethaw weathering, and slope is steepened through mass wasting events and erosion

Svalbard!

197
Q

Glacial horns / pyramidal peaks

A

Pointed pyramidal peaks formed from cirque erosion due to multiple glaciers diverging from a central point

A classic example is the Matterhorn in the Swiss/Italian Alps

A Scottish example is Carn Mor Dearg

198
Q

Hanging valleys

A

Tributary valley well above main valley floor: typically formed when main valley has been widened and deepened by glacial erosion, leaving the side valley
abruptly cut off from main valley

Steep drop-off usually creates dramatic cascading waterfalls

Coire a’ Mhail and Coire Giubhsachanare both hanging valleys, with steep drops at the end into
Glen Nevis below

199
Q

Glacial erosion mechanisms

A

freeze-thaw at base of glacier
abrasion
plucking

200
Q

Till

A

Sediment deposited directly by a glacier is neither sorted nor stratified
Heaps of poorly sorted sediment called till are left as glaciers abate

201
Q

Outwash

A

Till can be then reworked by meltwater streams that
transports it beyond terminus of glacier where it is deposited as outwash

202
Q

Moraines

A

Ridge-like accumulations of till are moraines

Form as sediment is bulldozed by a glacier advancing across the land

End moraines form at the terminus of a glacier, with the terminal moraine marking its furthest advance (Longyear glacier, Svalbard)

Lateral moraines form at the sides (Lars, Svalbard)

Medial moraines form where two glaciers join

Moraines are important tools that scientists use to determine the extent of ice coverage during an
ancient glaciation

203
Q

Drumlins

A

Ice sheets mold oval hills called drumlins

Drumlins are elongated parallel to the direction of
ice flow

Formed by glacial ice acting on underlying unconsolidated till

Streamlined hills shaped beneath the ice

Common in the central lowlands of Scotland, between Glasgow and Edinburgh

204
Q

Eskers

A

Rivers flowing beneath ice (subglacial channels) leave
ridges of wellsortedsand and gravel called eskers

205
Q

Kettles

A

Shallow, sediment-filled body of water formed by retreating glaciers or draining floodwaters

Form as a result of blocks of ice calving from glaciers becoming submerged in the sediment in outwash plain, which then melt to produce a void filled by a
sediment-rich lake

Landscapes marked by kettles, now typically occupied by lakes, ponds, or wetlands are clear evidence of previous glaciation

206
Q

Kames

A

Kames are an irregularly shaped hill or mound
comprised of piles of sand, gravel, and till that
accumulates in a depression on a retreating
glacier and is then deposited on the land
surface with further melting of the glacier

207
Q

Marine ice sheets

A

The Marine Ice Sheet needs to be heavy (thick) enough to displace the water to be grounded.

Ocean warming can melt the ice sheet faster than it moves out to sea thinning the Ice Sheet.

208
Q

Marine ice cliff instability

A

Positive feedback whereby the cliff face can become unstable if not supported by the
buttressing effects of ice shelves

Leads to rapid ice margin retreat

209
Q

Isostatic rebound - mantle movement

A

Viscous mantle flows away from depressed crust under the huge weight of a mountain chain

210
Q

What is a rock?

A

Crystals of one or more minerals bound together in a
mixture

211
Q

Pumicevs pyroclastic

A

pumice –very frothylight-colouredcellular rock, full
of interconnected gas bubbles

pyroclastic rock formed from fragments of chilled
magma pyroclastic = fiery fragments

212
Q

Decompression (adiabatic) melting

A

Mid-ocean ridges
Decompression melting forms
mid-ocean ridge basalt (MORB)

Continental rifts
e.g. East Africa
Over time, will become an ocean

Mantle plumes
e.g. Hawaii
Both increased heat flow and
decompression
Forms ocean-island basalt (OIB)

213
Q

Volatile-assisted melting

A

Changing the chemical composition of the system

If you add volatiles to Earth’s mantle (H2O, CO2) you lower its melting temperature

214
Q

Explain cooling time regarding texture n Grain size

A

More cooling time means:

-coarser
-larger grains

215
Q

What is a porphyritic

A

A fine matrix with larger crystals

216
Q

Batholith

A

Huge mass of intrusive rock made of
numerous plutons

217
Q

Dyke

A

Vertical igneous intrusions to layering

218
Q

Sill

A

Horizontal igneous intrusions to layering

219
Q

What is a felsic rock

A

High silica content

Lighter in colour

220
Q

What is a mafic rock

A

Low silica content

Darker rocks

221
Q

What is bowens reaction

A

Mafic minerals crystallise First
Felsic are last to

Remaining melt becomes more felsic

Yet it can also work in reverse

222
Q

Mid ocean ridges- constructive margin - igneous

A

Melting style

Opening of plate boundary above mantle creates void = mantle moves up to fill void

Melting occurs via decompression

223
Q

Subduction zones- destructive margin- igneous

A

Melting style

Hydration of mantle above subducting plate

Melting occurs via volatile introduction (flux melting)

Mt. Fuji

224
Q

Continent - Continent collision - igneous

A

Source of (original) melt: crust

Sediments, metamorphic rocks, igneous rocks
Often melt is too viscous and deep enough in crust, so it does not escape

Forms granite plutons/batholiths

225
Q

Continental rift - igneous

A

Melting style: decompression

Source of (original) melt: mantle

Majority of melt is mafic
Some remelting of crust produces
felsic volcanoes –BIMODAL volcanism

226
Q

Flood basalts

A

Vast eruptions of basaltic lava

Associated with the initial impingement of a mantle plume under a plate – often continental

Can start the breakup of continents – start rifting by weakening/thinning the plate

HUGE fissure eruptions of basalt

227
Q

What is a lava flow

A

molten rock that moves over the ground

228
Q

What is a pyroclastic debris

A

fragments blown out of a volcano

229
Q

What is volcanic gases

A

Expelled vapor and aerosols

230
Q

What determines magmatic flows

A
  1. Composition of melt
  2. Crystal content
  3. Gas content
  4. Temperature
231
Q

Physical properties of magma

A

Temperature
Increasing temperature decreases the viscosity

Crystal content
The present of crystals in a melt acts to increase the viscosity of a melt

Gas content
If the gases are dissolved, the will act as network modifiers (decrease viscosity)
If the gases exsolve, they will form bubbles which act against the flow

232
Q

Volcanic gas

A

Magma composition often controls gas content.
• Felsic magmas have more gas; mafic magmas less.

• Gases are expelled as magma rises (P drops).

• Style of gas escape controls eruption violence.
• Low viscosity (basalt)—easy escape; effusive eruption
• High viscosity (rhyolite)—difficult escape; explosive release

• Gas bubbles in rock are called vesicles.

233
Q

Lava flow (viscosity) depends on:

A

• Composition, especially silica (SiO2) content.
• Temperature.
• Gas content.
• Crystal content

234
Q

Effusive lava flows

A

Mafic magma – low viscosity, efficient degassing

Andesitic magma – medium viscosity

Rhyolitic magma – high viscosity, does not flow – forms domes

235
Q

Basaltic lava flows

A

Mafic lava—very hot, low silica, and low viscosity

• Basalt flows are often thin and fluid.

• They can flow rapidly (up to 30 km per hour).
• They can flow for long distances (up to several hundred km).

• Most flows measure less than 10 km.
• Long-distance flow facilitated by lava tubes.

236
Q

Andesitic lava flows

A

Higher SiO2content makes andesitic lavas viscous.

• Unlike basalt, they do not flow rapidly.
• Instead, they mound around the vent and flow slowly.

• The crust fractures into rubble, called blocky lava.
• Andesitic lava flows remain close to the vent.

237
Q

Rhyolitic lava flows

A

Rhyolite has the highest SiO2; is the most viscous lava.
• Rhyolitic lava rarely flows.
• Rather, lava plugs the vent as a lava dome.
• Sometimes, lava domes are blown to smithereens.

238
Q

Volcaniclastic deposits

A

Volcanoes often erupt large quantities of fragments.

Volcaniclastic deposits include:
• Pyroclastic debris—lava fragments (of all sizes) that freeze in air.
• Preexisting rock—blasted apart by eruption.
• Landslide debris—blocks that have rolled downslope.
• Lahars—transported as water-rich slurries.

239
Q

Pyroclastic debris

A

Explosive eruption:
Melt, crystals and ‘country’ rock (lithic) fragments are fragmented

fragmented = blasted apart
…and blown from the vent

240
Q

Explosive eruptions - felsic

A

Andesitic or rhyolitic eruptions
• More viscous magmas; more volcanic gases
• Less easy to de-gas = more prone to explode
• Explosive eruptions generate huge volumes of debris.
• Pumice—frothy volcanic glass
• Ash—fragments less than 2 mm in diameter
• Pumice lapilli—angular pumice fragments
• Accretionary lapilli— rounded clumps of ash forming in moist air

241
Q

Pyroclastic eruptions
Different eruptive styles

A

Pyroclastic fall (ash or tephra deposit)
Pyroclastic flows
Pyroclastic surges

242
Q

Pyroclastic eruptions
Fall

A

Fallout from an eruptive column/cloud
Falls like snow – mantles topography

243
Q

Pyroclastic eruptions
Flow

A

Avalanches of hot ash (200oC to 450oC) that race downslope.

Moving up to 300 km per hour, they incinerate all in their path.

Immediately deadly; they kill everything quickly.

Many historic examples: Mt. Vesuvius, Mt. Pelee, Mt. St Helens

Block and ash flows - Ignimbrites welded by heat of flow

244
Q

Pyroclastic eruptions
Surges

A

Like a pyroclastic flow, but denser (wetter)
Very energetic eruptions
Generally colder, lots of water

245
Q

Incoming energy flux

A

Earth receives more energy from sun (electromagnetic waves)

Seasons due to Earth’s xis rotation causing a tilt

30% of solar energy is affected by albedo effect

246
Q

Outgoing energy flux

A

Earh has an approximate energy balance, energy is returned as blackbody radiation

Stefano- Boltzman law:

ōT⁴ W/m²
(ō is a constant)

247
Q

Earth’s energy budget

A

Atmosphere and ocean move because equator receives more energy from sun than it emits

248
Q

Combining incoming and outgoing radiation

A

To close earth’s energy budget, the atmosphere and ocean need to move energy from low latitudes to high lattitudes

249
Q

Energy/heat transport

A

We must transport polewardsas we receive more at equator

250
Q

What does hydrostatic balance tell us

A

Pressure decreases with altitude at a rate dependant on temperature

251
Q

What does geopotential height depend on

A

Depends on the temperature integrated between the surface and that level

252
Q

Air density with temp

A

Warm air is less dense

253
Q

Chemical composition of the atmosphere

A

78% N2, 21% O2, 0.93% Ar and others

254
Q

Ideal gas law

A

p = pRT

255
Q

Water saturation in atmosphere

A

When air cannot hold any more water vapor, its saturated , to get air to condense and firm mist, fog, clods and rain, it must cool to saturation

256
Q

Atmospheric phenomena

A

We want to understand this for fundamental scientific discoveries and practical purposes

257
Q

What is an easterlies wind??

A

Comes from east

258
Q

What is an westerlies wind??

A

Comes from west

259
Q

What is an notherlies wind??

A

Comes from north

260
Q

Volcanic rock types at the rock and spindle

A
  1. Intrusive - igneous, fine grained basalts
  2. Bedded tuffs - pyroclastic deposits, fallen back into vent
  3. Tuffisite, ash rich veins that never got to the surface
261
Q

Sedimentary rocks

A

formed on or near Earth’s surface via erosion, deposition and lithification of sediment transported by water, ice and wind or precipitated out-of-solution by biotic and abiotic processes

262
Q

Classification of sedimentary rocks

A

clastic: composed of fragments (clasts) of pre-existing
minerals/rocks (i.e. a source area or provenance)

non-clastic: (bio)chemically precipitated

clastic rocks and non-clastic rocks commonly occur together

263
Q

Classifying clastic sedimentary rocks

A

conglomerate versus breccia: both consist of gravel-sized sediment but their grain shapes are different, rounded vs angular, respectively

weathering and erosion of ‘parent’ rocks determines
composition of resulting sediment

intensity, duration and ‘style’ of sediment transport
processes determines the texture of the sediment

264
Q

Concept of ‘maturity’

A

As sediment undergoes increasing intensities and durations of weathering and transport, it begins to ‘mature’:

•mafic minerals and feldspars breakdown into finer particles and clays
•quartz becomes more and more enriched
•sediment becomes better sorted and grains more rounded

265
Q

Evolution of sedimentary rocks

A

Source (provenance)

Weathering and transport

Site of deposition

Lithification occurs and the resulting sedimentary rock is classified based on its composition and texture

266
Q

Non clastic sedimentary rocks

A

non-clastic sedimentary rocks are precipitated by organisms or abiotically

temperature, salinity, water chemistry and sediment flux (needs to be low) influence precipitation

chemical sediments are good indicators of environmental conditions

there are numerous types of (bio)chemical sediments:
coal, carbonates, evaporites and siliceous precipitates

267
Q

The order that mineral salts precipitated by (increasing) evaporation

A

Calcite
Gypsum
Halite
Potassium

268
Q

compositional classification of (bio)chemical sedimentary rocks is typically based on the major anion

carbonates (CO3-)

A

CaCO3 – calcite (aragonite polymorph is metastable); forms limestone*^

(Ca)Mg(CO3)2 – dolomite; forms dolostone*

Fe2CO3 – siderite

*can form abiotically or biotically
^fizzes with weak HCl (acid)

269
Q

compositional classification of (bio)chemical sedimentary rocks is typically based on the major anion

sulphates (SO4-2); commonly termed evaporites

A

CaSO4•2(H2O) – gypsum
CaSO4 – anhydrite

270
Q

compositional classification of (bio)chemical sedimentary rocks is typically based on the major anion

Others include:

A

Fe2O3 – ironstone (iron oxide)
SiO2 – chert (flint; opal is SiO2•nH2O)*
NaCl – halite

*can form abiotically or biotically

271
Q

limestones and dolostones: textural classification

A

characterised by their allochems (grains)
• bioclasts (fpieces of fossils)
• ooids – small spheres
• peloids – fecal pellets
• intraclasts – eroded clasts

and their interstitial autochem material (kinda like matrix)
• lime mud or micrite (micro-crystalline
calcite)
• cement as coarse carbonate crystals
(spar)

Ooids are an allochem

272
Q

Graded bedding (sedimentary)

A

deposition due to decreasing flow energy results in graded bedding: coarser grains at the base of beds and finer grains upwards

(Reverse grading is also a thing)

273
Q

Bedding scale (sedimentary)

A

layering <1 cm thick is termed laminated

layering 1 – 10 cm is termed thin bedded

layering 10 – 50 cm thick is termed medium bedded

layering 50 – >100 cm thick is termed thick to very-thick bedded

274
Q

Bedform (sedimentary)

A

a morphological feature formed by the interaction between a flowing fluid (water, air) and sediment on a bed

bedforms inform about flow energy and transport direction

275
Q

Ripples n’ dunes

A

ripples have h <4 cm, dunes have h > 4 cm

ripples and dunes inform on direction of sediment transport

ripples and dunes often occur together

276
Q

Fluid flow and bedforms

A

sediment is carried up the stoss side of a ripple by the flow

at the crest, the flow separates from the bed and grains cascades down the lee side

flow ‘reattaches’ in the trough causing erosion and that sediment is transported up the stoss-side of the next ripple

the progressive cascade and migration of grains forms cross-bedding

277
Q

Bedform stability and flow energy

A

when sediment is transported, it becomes organised into stable bedforms (e.g. ripples, dunes) that reflect flow ‘energy’ (velocity) acting on a particular grain size distribution

generally, as flow velocity increases, the stable bedforms are:
flat beds –> ripples –> dunes –> plane beds –> antidunes

by recognising bedforms, and changes in bedforms through a sedimentary sequence, you can reconstruct past flow conditions and sediment transport direction

278
Q

Types of flow n ripple symmetry

A

unidirectional flow generates asymmetric/current ripples

oscillatory flow generates symmetric/wave ripples

279
Q

Formation of wave ripples

A

wind shear generates waves

waves on the surface generate a circular motion (‘orbitals’) of water molecules

orbitals decrease in size downward; in shallow water these can intersect the seafloor and friction causes the circular motion to become elliptical

the horizontal motion of the ellipse at the bed can move sediment and generate symmetric ripples

280
Q

Imbrication

A

a depositional fabric in which clasts align and overlap one another, much like a run of toppled dominoes

281
Q

Soft sediment deformation

A

these form due to gravitational instabilities via loading and by excessive shear stress

282
Q

sedimentary environments: fluvial

A

characteristic features of fluvial deposits:
• point bars (m-scale lateral accretion surfaces)
• crevasse splay sands (flat, tabular beds)
• overbank or floodplain mud and fine sand
• fining-upward trend from gravel in channel, sand in point bar to mud in floodplain/overbank

283
Q

sedimentary environments: shorelines and deltas

A

• coastal zones are the interface between marine and non-marine settings
• areas where wave, tide and storm energies are dissipated
• sinks for products of physical (sediment) and chemical (ions) weathering
• zones of mixing between fresh and saline waters

284
Q

foreshore or swashface

A

• cm- to dm-thick sets of low-angle laminae
• symmetric (wave) and flat-topped ripples
• bioturbation (burrowing)

285
Q

sedimentary environments: marine settings (focus on carbonates)

A

controls on patterns and characteristics of deposition in marine settings include:
• physical processes such as waves, storms and tides
• oceanic conditions such as bathymetry (shelf, slope, abyssal plain), salinity and water temperature (the latter two are latitudinal or ‘climatic’)
• tectonic setting such as passive vs active margins

286
Q

Carbonate reef distribution

A

low to no siliciclastic flux
• warm temperature (20˚- 30˚ C)
• shallow water depth (<10 - 20 m)
• average to high salinity (34.4 ppm)

287
Q

Components of the climate system

A

The greenhouse effect
The carbon cycle
Forcing mechanisms and feedback
Climate variation

288
Q

The atmosphere is made up of:

A

Troposphere
Stratosphere
Outer atmosphere

289
Q

Drivers of climate change

A

Geological time-scales – millions of years
Movement of the solar system through the galaxy ~ changes in cosmic ray flux and galactic dust
Influence cloud formations

  • Plate tectonics – movement of continental plates
    Affects on ocean currents
  • Mountain building etc etc
    Affects on atmospheric circulation
    Weathering

Presence/absence of sea ice/ice sheets at poles
Albedo affects
Multiple feedbacks in the system

290
Q

The hadean eon

A

Formation of Earth: 4.6 Gya
50-70 Mya later, a Mars-sized object collides with the Earth and the Moon is formed

first 600 My of Earth’s history
Sun was 30% fainter than at present

formed with no “primary” atmosphere, but outgassing resulted in an atmosphere which was likely
water vapour, CO2, ammonia, methane, hydrogen sulphide, sulphur dioxide + others

no O2 at that time
zircons show oceans and continental material had formed by 4.4Gya (0.1Gya after formation)

291
Q

A planet under seige

A

Impacts occurred from formation through until the Late Heavy Bombardment (about 3.9Gya)
Sterilizing impacts probably occurred 6-12 times during the Hadean
No real idea what the “temperature” of the planet was at this time

292
Q

The Archean

A

3.9 to 2.5 Gya

Oldest rocks on Earth from this period

Evidence for lack of Oxygen
Witwatersrand gold ore (~3 Gya)
Detrital Pyrite (FeS2)
Was not oxidized during weathering

Evolution of life: 3.7 – 3.5 Gya
Evolution of methanogens (prokaryotes) [cannot survive with free oxygen]
CO2 + 4 H2 → CH4 + 2 H2O

Archean ends with rise in global oxygen levels
Evolution of cyanobacteria (eukaryotes) – 2.8 Gya (earlier??)

Tectonics different to today
Higher heat flow
Smaller plates (proto-continents) and many hot spots

Temperatures likely warmer than today
Oxygen isotopes in Archean rocks suggest oceans twice as warm as today’s tropical oceans (~50oC).
This is contentious – but climate was WARM
But this is odd as the Sun was less bright!

293
Q

The Faint sun paradox

A

No Atmosphere? - The Earth should have been “frozen” for the first two billion years

3.8 Gya: Sun’s luminosity 75% of present value
Yet – during the Archean liquid water was prevalent on the surface

In fact the geological and palaeoclimatic record strongly suggests Earth has maintained a “moderate” climate throughout its history – BUT WITH WOBBLES

The Greenhouse Effect!!!
CO2 - supplied by volcanoes
CH4 - Also from volcanoes - but also requires life - Methanogens!!

294
Q

Hydrolysis

A

Main chemical weathering mechanism that removes atmospheric CO2
Reaction of silicate minerals (CaSiO3) with carbonic acid (H2CO3) to form clay minerals and dissolved ions

CaSiO3 + H2CO3 –> CaCO3 + SiO2 + H2O
Atmospheric CO2 combines with water = H2CO3

This process accounts for 80% of the CO2 removal
CO2 also dissolves in sea water etc
Later life – photosynthesis etc etc

295
Q

Controls on weathering reactions

A

Chemical weathering influenced by
-Temperature
Weathering rates double / 10oC rise
-Precipitation
H2O – required for hydrolysis
H2O increases as temperature increases

Vegetation [not relevant for Archean]
Respiration in soil increases CO2
CO2 in soils 100-1000x higher than atmospheric CO2

Other factors
land formation, mountain building, latitude location etc

296
Q

Organic haze

A

If CH4 becomes more abundant than CO2, an organic haze begins to form

Haze from UV photolysis (decomposition) of CH4
Creates an anti-greenhouse effect
Haze absorbs sunlight in the stratosphere and radiates energy back to space
E.g. Titan

297
Q

Archean/Proterozoic transition

A

A time of significant change
Change from “small plates” to modern large plate tectonics
Significant rise in O2 due to [evolution] increase of cyanobacteria (blue green algae)
Photosynthesis

Cyanobacteria: 2.8 Gya (possibly evolved 3.8Gya)
Stromatolites
Layered Cyanobacteria accretionary structures

298
Q

Implications of increased oxygen

A

Disrupted the balance
Solar luminosity – low but increasing!
CO2
CH4
+ water vapour

Increased weathering - oxidation
Decrease CO2

Methanogens outcompeted (?) by cyanobacteria – decrease CH4
1st major glaciation 2.3 – 2.2 Gya

It did not take much to shift the planet into a glaciation

299
Q

2.2 Gya to 750 Mya

A

Tectonic style changed
Small to large plates

First supercontinent
Rodinia: 1 Gya – 750 Mya
Bulk of land: mid-latitudes
Related Grenville Orogeny

300
Q

750 - 580 Mya

A

Neoproterozoic Snowball Earth: Cryogenian
Multiple periods of severe “global” glaciation
Lots of geologic evidence of low latitude glaciation

Global temperatures plunged and the whole planet was encased in ice
Or in “Slushball” alternative – tropics were ice free

301
Q

Mechanics to a snowball state

A

Neoproterozoic Snowball Earth: Cryogenian
Multiple periods of severe “global” glaciation
Lots of geologic evidence of low latitude glaciation

Global temperatures plunged and the whole planet was encased in ice
Or in “Slushball” alternative – tropics were ice free

302
Q

How to get out the icehouse

A

It’s the Greenhouse Effect again

Volcanic activity and carbon dioxide release would NOT have ceased during Snowball periods

Due to cold conditions, weathering rates were low so hydrolysis rates low and therefore little “scrubbing” of CO2 from atmosphere

303
Q

Phanerozoic consists of 3 eras

A

Paleeozoic
Mesozoic
Cenozoic

304
Q

Early Phanerozoic

A

Started with the Cambrian Explosion

A direct response to the late Proterozoic Snowball Earth

Quick evolution from “Ediacaran” fauna
Initially marine

Rapid evolution
“empty planet” - many open ecological niches
driven by predation
competition for “food” resources

305
Q

Phanerozoic climate

A

Large swings from “greenhouse” to “icehouse” conditions
Understanding this long-term variability in global temperatures is not straightforward

Underlying hypothesis
CO2 is the main driver of global climate change

Faint sun less of an issue now
Myriad of feedbacks
Presence/absence of continents at poles
Presence/absence of ICE at poles
Hydrolysis: carbonate-silicate cycle

306
Q

Cambrian

A

540 - 490 mya

CO2 ~ 4500 ppm, 16x pre-Industrial
Snowball build up

O2 ~ 63% of present
Temp ~ 21°, 7° above present
Sea level 30-90m above present
No ice cover

No terrestrial life
Trilobites dominant in oceans (became extinct at end of Permian)

Slow removal of CO2 through Hydrolysis

307
Q

Devonian

A

415 - 360 mya

CO2 ~ 2200 ppm, 8x pre-Ind.
O2 ~, 75% of present

Temp ~ 20°, 6° above present
Sea level 180-120m above present

No ice cover
Land has some plants and animals
Continued removal of CO2 through Hydrolysis

308
Q

Carboniferous

A

360 - 300 mya

CO2 ~ 800 ppm, 3x pre-Industrial
O2 ~ 163% of present

Temp ~ 14°, 0° above present
Sea level 80-120m above present

Land is dominated by swamps and forests
Some ice cover – south pole

309
Q

Permo-Carboniferorous glaciation

A

Since the “Snowballs” of the late pre-Cambrian, one of the most extensive glacial periods in earth history until “recent” glaciations of the Cenozoic

Devonian to Carboniferous
Super continent at poles: Pangea/Gondwana
Tropical mountain range
Decreasing CO2

310
Q

Permian

A

300-250 mya

CO2 ~ 900 ppm, 3x pre-Industrial
O2 ~ 115% of present

Temp ~ 16°, 2° above present
Sea level >60m to <20m present

Pangaea diverse climate states
Cold dry at southern polar latitudes
North – intense and great seasonal variation

Worst extinction event in Earth’s history
95% of species disappeared

311
Q

Permian- triassic extinction

A

The boundary of the Permian and Triassic

~90% of all species died out
95% of species in oceans
Marine invertebrates – worst hit!

Took place over a 5-10 million year period
Slow start – rapid by end

Impact event (Nickel-rich Layers
From impact or heavy-metal rich mantle-derived lavas)

Volcanism (Flood basalt events
The Siberian Traps (also another in China) )

Final complete state of Pangaea – extreme climate states
Climate Change – hot or cold (or both?)

312
Q

Mesozoic era

A

The emergence of the dinosaurs
Predatory reptiles
Amphibians living on land and in water
Reef Building corals

Climate and CO2 levels relatively constant

313
Q

Triassic

A

250 - 200 mya

CO2 ~ 1750 ppm, 6x pre-Industrial
O2 ~ 80% of present
Temp ~ 17°, 3° above present
Desert conditions prevail, leads to success of reptiles
Late Triassic – emergence of dinosaurs

314
Q

Jurassic

A

200 - 145 mya

CO2 ~ 1950 ppm, 7x pre-Industrial
O2 ~ 130% of present
Temp ~ 16.5°, 3° above present
High CO2, largest terrestrial animals ever
Landscape dominated by coniferous forests and fern plains

315
Q

Cretaceous

A

145 - 65 mya

CO2 ~ 1700 ppm, 6x pre-Industrial
O2 ~ 150% of present

Temp ~ 18°, 4° above present
By end of Cretaceous CO2 levels are approaching Cenozoic levels

Another extinction event which wiped out the dinosaurs
Emergence of flowers and associated insects
Diversification of mammals

316
Q

Cenozoic era

A

Mammals increased in numbers and diversity
Grasses and flowering plants expanded on land
Ocean life remained relatively unchanged however
The Eocene-Paleocene is the last “warm” period in Earth history

Early Eocene seen as a “worst case” analogue for where today’s change in climate, as influenced by anthropogenic CO2 emissions, could go………….!!

317
Q

Eocene

A

55 - 35 mya

CO2 ~ 385 ppm, 1.5x pre-Industrial
O2 ~ 100% of present
Temp ~ 19°, 5° above present

BUT within this period were some significantly extreme climate states
Paleocene-Eocene Thermal Maximum
End of Eocene marked beginning of current icehouse climate

318
Q

Drivers of climate change

A

External and Internal

External to climate system
Orbital variations, tectonic effects, sun’s variations

Internal to climate system
Feedback mechanisms
Ocean/atmospherics interactions
Ocean conveyor belt
El Nino-southern oscillation, Monsoons etc

319
Q

Milankovitch cycles

A
  • obliquity (tilt)
    It is this tilt that results in the planet having seasons.
    The larger the angle, the larger the difference between summer and winter
  • eccentricity
    How oval it is
  • pressession
    The spinning of the earth its self

All whilst spinning around the sun

320
Q

Ice sheet changes with climate change

A

As ice sheets form, global albedo increases
Results in a further temperature drop and ice expansion

Expanding ice sheets result in a fall in global eustatic sea-level
Makes it easier for ice to flow out from the land
Further increasing albedo

These mechanisms could explain some of the added cooling not explained by Milankovitch theory

But still not enough

321
Q

CO2 and the role of thermohaline circulation

A

Acts as a pump transferring CO2 and nutrients from the surface to the deep ocean
Carbon–plankton relationship
Phytoplankton take up CO2, falls to ocean bottom when dead

Released through oxidation – BUT deep oceans are anoxic
returned to the surface when the thermohaline circulation is on
If circulation slows – carbon is not returned to the surface – global cooling

Changes in strength of circulation would also alter energy transfer from equator to poles – especially in N Atlantic (Gulf Stream looses energy)

322
Q

Self regulating negative feedback loops within climate change

A

Extra ice at poles should cause more downwelling
exclusion of salt from water in ice formation
Increased sea salinity – therefore denser
Causing strong thermohaline circulation

Colder climate means less terrestrial biological activity – therefore more atmospheric CO2

Colder climate means less moisture vapour in atmosphere
less precipitation to feed glaciers
Moisture vapour also a greenhouse gas

323
Q

Ice cores

A

Ice cores
High resolution palaeo archives

Greenland
~130,000 yrs
Antarctic
~800,000 yrs

Greenland data
Shows very rapid
climate change

324
Q

The youngest dryas

A

The last short major cold event
During the transition from the last glacial into the present Holocene
Occurred from 12,800 and 11,500 yrs ago
General warming trend interrupted by cold reversal

325
Q

The late holocene

A

Good quality high resolution proxy data
e.g. tree-rings, ice cores, corals, speleothems, historical archives
“reasonable” knowledge of the climate over this period

Reasonable records of solar and volcanic forcing as input parameters in climate models

Last 150 years – anthropogenic period
So called “Anthropocene”