equillibrium constants kp Flashcards
What does the p stand for Kp
Pressure
What is the kp calculated from
Partial pressure
What are the features of the equilibrium constant
When the kp is greater than 1
When the kp is less than 1
If kp is exactly 1
When the kp is greater than 1 - it means the equilibrium is towards the right hand side (more products than reactants)
When the kp is less than 1 - it means the equilibrium is towards the left hand side (more reactants than products)
If kp is exactly 1 - it means that the equilibrium is in the middle (equal amounts of products and reactants)
When writing the kp equation what must you consider in the reactants and products brackets
(pp)
How do you work out the units for Kp
Can either be KPa or Pa
Add the top powers
At the bottom powers
Take them away from one another
What is kp used for
For a reversible reaction in the gas phase
How do you answer an equilibria question for
The position of equilibria
The equilibrium yield of a reagent
They value of Kp
If one of the following conditions are changed
The temperature
The pressure or volume of a container
The concentration of a reagent
- State the answer
- Make a statement considering the condition which has been changed
- State the position of equilibrium shifts to the right or left … to oppose the change in condition
N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1
How would an increase in pressure affect the position of equilibrium
The equilibrium will shift to the RIGHT
There are fewer gaseous moles on the right hand side
The equilibrium will shift to oppose the increase in pressure
N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1
How would an increase in temperature affect the equilibrium yield of ammonia
The equilibrium yield of ammonia will decrease
The forward reaction is exothermic
The equilibrium will shift to oppose the increase in temperature
N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1
How would a decrease in temperature affect the value of Kp
The value of Kp will increase
The forward reaction is exothermic
The equilibrium will shift to oppose the decrease in temperatures