equillibrium constants kp Flashcards

1
Q

What does the p stand for Kp

A

Pressure

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2
Q

What is the kp calculated from

A

Partial pressure

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3
Q

What are the features of the equilibrium constant

When the kp is greater than 1
When the kp is less than 1
If kp is exactly 1

A

When the kp is greater than 1 - it means the equilibrium is towards the right hand side (more products than reactants)

When the kp is less than 1 - it means the equilibrium is towards the left hand side (more reactants than products)

If kp is exactly 1 - it means that the equilibrium is in the middle (equal amounts of products and reactants)

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4
Q

When writing the kp equation what must you consider in the reactants and products brackets

A

(pp)

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5
Q

How do you work out the units for Kp

A

Can either be KPa or Pa
Add the top powers
At the bottom powers
Take them away from one another

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6
Q

What is kp used for

A

For a reversible reaction in the gas phase

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7
Q

How do you answer an equilibria question for

The position of equilibria
The equilibrium yield of a reagent
They value of Kp

If one of the following conditions are changed
The temperature
The pressure or volume of a container
The concentration of a reagent

A
  1. State the answer
  2. Make a statement considering the condition which has been changed
  3. State the position of equilibrium shifts to the right or left … to oppose the change in condition
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8
Q

N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1

How would an increase in pressure affect the position of equilibrium

A

The equilibrium will shift to the RIGHT
There are fewer gaseous moles on the right hand side
The equilibrium will shift to oppose the increase in pressure

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9
Q

N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1

How would an increase in temperature affect the equilibrium yield of ammonia

A

The equilibrium yield of ammonia will decrease
The forward reaction is exothermic
The equilibrium will shift to oppose the increase in temperature

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10
Q

N2(g) + 3H2 (g) 🔁 2NH3 (g) ΔH = -92 kjmol-1

How would a decrease in temperature affect the value of Kp

A

The value of Kp will increase
The forward reaction is exothermic
The equilibrium will shift to oppose the decrease in temperatures

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