Equilibrium How Far Flashcards

1
Q

2 features of a system that is in dynamic equilibrium

A

rate of forward reaction = rate of backward reaction

concentrations of reactants and products constantly interchanging

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2
Q

what is Le Chatelier’s principle

A

if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change

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3
Q

what happens if you increase pressure

A

moves position of equilibrium to the side with less moles of gas

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4
Q

what happens if you increase temp

A

moves in endothermic direction

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5
Q

what is homogeneous equilibrium

A

everything present in the same phase/state

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6
Q

how to write Kc

include units or (no units)

A

[C][D]/[A][B]2

only include g compounds

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7
Q

what affects Kc

A

temperature only

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8
Q

if the temp change means more product is formed what does this do to Kc

A

Kc will rise

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9
Q

if the temp change means less product is formed what does this do to Kc

A

Kc will decrease

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10
Q

a Kc of >1 =

A

equilibrium lies towards products

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11
Q

a Kc of <1 =

A

equilibrium lies towards reactants

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12
Q

what is heterogeneous equilibrium

A

not everything is in the same phase

don’t include any term for a solid in the equilibrium equation

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13
Q

equilibrium involving gases uses what

A

Kp

done in terms of partial pressures

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14
Q

how to work out mole fraction of gases

A

number of moles of gas of A/total number of moles of gas

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15
Q

what is partial pressure (Pa)

A

pressure a gas in a mixture would exert if it alone occupied the container

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16
Q

what is the total pressure

A

mixture of gases is equal to the sum of the partial pressures

17
Q

how to work out partial pressures

A

mole fraction x total pressure

18
Q

3 things to remember

A

must be moldm-3- if it says in a 4dm3 vessel, divide by 4 so equals 1dm3
must be concentration, not moles- divide moles by volume (in dm3)
must be same volumes- made up to 250cm3, then 25cm3 sample used, times by 10