Equilibrium constant, Kp Flashcards
the partial pressure of a gas in a mixture of gases is
the pressure that the gas would exert if it alone occupied the volume of the mixture
we use parital pressure for …………………reactions involving gases
homogeneous
the total pressure of the mixture is equal to
the sum of partial pressures of all the gases present in the mixture
the partial pressure of ‘a’ would be
Pa
the partial pressure of an individual gas is calculated by
multiplying its mole fraction by the total pressure where
Pa = XaP
where Xa is the mole fraction of gas ‘a’ in the mixture
we calculate the mole fraction by
dividing the number of moles of ‘a’ by the total number of moles of gas
mole fraction= mols of ‘a’ / total mols
for heterogeneous reaction where there is a solid, we do not
do not include the solid in the Kp expression
the expression for Kp =
[PC]c[PD]d
Kp= ——————
[PA]a [PB]b
From the equation:
aA(g) + bB(g) = cC(g) + dD(g)
because solids are not taken into account when dealing with gas partial pressures, it means that the pressure of the gas involved is …………………at that given temperature regardless of ………………..
because solids are not taken into account when dealing with gas partial pressures, it means that the pressure of the gas involved is CONSTANT at that given temperature regardless of THE MASS OF SOLID PRESENT
for heterogeneous reactions where there is a liquid or aqueous species, we
leave them out of the Kp expression